IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v15y2022i15p5430-d873081.html
   My bibliography  Save this article

Biomass Behavior upon Fast Pyrolysis in Inert and in CO 2 -Rich Atmospheres: Role of Lignin, Hemicellulose and Cellulose Content

Author

Listed:
  • Osvalda Senneca

    (Istituto di Scienze e Tecnologia per l’Energia e la Mobilità Sostenibili (STEMS)-CNR, 80125 Napoli, Italy)

  • Barbara Apicella

    (Istituto di Scienze e Tecnologia per l’Energia e la Mobilità Sostenibili (STEMS)-CNR, 80125 Napoli, Italy)

  • Carmela Russo

    (Istituto di Scienze e Tecnologia per l’Energia e la Mobilità Sostenibili (STEMS)-CNR, 80125 Napoli, Italy)

  • Francesca Cerciello

    (Laboratory of Industrial Chemistry, Ruhr University Bochum, 44801 Bochum, Germany)

Abstract

The present work focuses on the quality of char and primary tar produced from fast pyrolysis in N 2 and CO 2 of lignocellulosic biomasses: walnut shells (lignin-rich), straw (hemicellulose-rich) and pinewood (cellulose-rich). Heat treatments are carried out in a heated strip reactor (HSR) at 1573 and 2073 K for 3 s, with a heating rate of 10 4 K/s. The equipment allows for quenching the volatiles as soon as they are emitted. Chars are analyzed by thermogravimetric analysis in air. Results are compared with the products obtained from raw lignin, pure cellulose and pure hemicellulose. Cellulose and hemicellulose tars are dominated by anhydrous monosaccharides, which are scarce in straw tar and abundant in walnut shells tar. Polycyclic aromatic hydrocarbons PAHs are present in the primary products, in particular for walnut shells. The most reactive char is the one obtained from straw and the least reactive is the walnut shells char. Severe heat treatment and a CO 2 atmosphere generate additional char components with higher and lower reactivity. The more reactive char component may arise from cross-linking reactions involving the monosaccharides (for which the result decreased in tar), whereas the less reactive component arises from thermal annealing and graphitization. Thus, the pyrolytic behavior of biomasses cannot be reconstructed with a mere addition of the lignin/cellulose/hemicellulose contribution, taking into account their content in the biomass.

Suggested Citation

  • Osvalda Senneca & Barbara Apicella & Carmela Russo & Francesca Cerciello, 2022. "Biomass Behavior upon Fast Pyrolysis in Inert and in CO 2 -Rich Atmospheres: Role of Lignin, Hemicellulose and Cellulose Content," Energies, MDPI, vol. 15(15), pages 1-13, July.
  • Handle: RePEc:gam:jeners:v:15:y:2022:i:15:p:5430-:d:873081
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/15/15/5430/pdf
    Download Restriction: no

    File URL: https://www.mdpi.com/1996-1073/15/15/5430/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Biswas, Bijoy & Singh, Rawel & Kumar, Jitendra & Singh, Raghuvir & Gupta, Piyush & Krishna, Bhavya B. & Bhaskar, Thallada, 2018. "Pyrolysis behavior of rice straw under carbon dioxide for production of bio-oil," Renewable Energy, Elsevier, vol. 129(PB), pages 686-694.
    2. Lee, Jechan & Oh, Jeong-Ik & Ok, Yong Sik & Kwon, Eilhann E., 2017. "Study on susceptibility of CO2-assisted pyrolysis of various biomass to CO2," Energy, Elsevier, vol. 137(C), pages 510-517.
    3. Shirkavand, Ehsan & Baroutian, Saeid & Gapes, Daniel J. & Young, Brent R., 2016. "Combination of fungal and physicochemical processes for lignocellulosic biomass pretreatment – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 217-234.
    4. Lee, Jechan & Yang, Xiao & Cho, Seong-Heon & Kim, Jae-Kon & Lee, Sang Soo & Tsang, Daniel C.W. & Ok, Yong Sik & Kwon, Eilhann E., 2017. "Pyrolysis process of agricultural waste using CO2 for waste management, energy recovery, and biochar fabrication," Applied Energy, Elsevier, vol. 185(P1), pages 214-222.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Shen, Feng & Xiong, Xinni & Fu, Junyan & Yang, Jirui & Qiu, Mo & Qi, Xinhua & Tsang, Daniel C.W., 2020. "Recent advances in mechanochemical production of chemicals and carbon materials from sustainable biomass resources," Renewable and Sustainable Energy Reviews, Elsevier, vol. 130(C).
    2. Zhang, Yu & Jiang, Haifeng & Li, Yuhang & Jia, Wei & Song, Meng & Hong, Wenpeng, 2024. "Efficient production of furans by CO2-assisted pyrolysis of cellulose with carbon-supported Ni/Co catalysts," Energy, Elsevier, vol. 294(C).
    3. Ma, Chunyan & Wang, Nan & Chen, Yifeng & Khokarale, Santosh Govind & Bui, Thai Q. & Weiland, Fredrik & Lestander, Torbjörn A. & Rudolfsson, Magnus & Mikkola, Jyri-Pekka & Ji, Xiaoyan, 2020. "Towards negative carbon emissions: Carbon capture in bio-syngas from gasification by aqueous pentaethylenehexamine," Applied Energy, Elsevier, vol. 279(C).
    4. Zhao, Ming & Memon, Muhammad Zaki & Ji, Guozhao & Yang, Xiaoxiao & Vuppaladadiyam, Arun K. & Song, Yinqiang & Raheem, Abdul & Li, Jinhui & Wang, Wei & Zhou, Hui, 2020. "Alkali metal bifunctional catalyst-sorbents enabled biomass pyrolysis for enhanced hydrogen production," Renewable Energy, Elsevier, vol. 148(C), pages 168-175.
    5. Yoon, Kwangsuk & Lee, Sang Soo & Ok, Yong Sik & Kwon, Eilhann E. & Song, Hocheol, 2019. "Enhancement of syngas for H2 production via catalytic pyrolysis of orange peel using CO2 and bauxite residue," Applied Energy, Elsevier, vol. 254(C).
    6. Zhang, Huaiwen & Yao, Yiqing & Deng, Jun & Zhang, Jian-Li & Qiu, Yaojing & Li, Guofu & Liu, Jian, 2022. "Hydrogen production via anaerobic digestion of coal modified by white-rot fungi and its application benefits analysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 157(C).
    7. Khushbu Kumari & Raushan Kumar & Nirmali Bordoloi & Tatiana Minkina & Chetan Keswani & Kuldeep Bauddh, 2023. "Unravelling the Recent Developments in the Production Technology and Efficient Applications of Biochar for Agro-Ecosystems," Agriculture, MDPI, vol. 13(3), pages 1-26, February.
    8. Struhs, Ethan & Mirkouei, Amin & You, Yaqi & Mohajeri, Amir, 2020. "Techno-economic and environmental assessments for nutrient-rich biochar production from cattle manure: A case study in Idaho, USA," Applied Energy, Elsevier, vol. 279(C).
    9. Wei, Maogui & Xiong, Shaojun & Chen, Feng & Geladi, Paul & Eilertsen, Lill & Myronycheva, Olena & Lestander, Torbjörn A. & Thyrel, Mikael, 2020. "Energy smart hot-air pasteurisation as effective as energy intense autoclaving for fungal preprocessing of lignocellulose feedstock for bioethanol fuel production," Renewable Energy, Elsevier, vol. 155(C), pages 237-247.
    10. Maria Alexandropoulou & Georgia Antonopoulou & Ioanna Ntaikou & Gerasimos Lyberatos, 2017. "Fungal Pretreatment of Willow Sawdust with Abortiporus biennis for Anaerobic Digestion: Impact of an External Nitrogen Source," Sustainability, MDPI, vol. 9(1), pages 1-14, January.
    11. Brillard, A. & Brilhac, J.F., 2020. "Improvements of global models for the determination of the kinetic parameters associated to the thermal degradation of lignocellulosic materials under low heating rates," Renewable Energy, Elsevier, vol. 146(C), pages 1498-1509.
    12. Feng, Qunjie & Lin, Yunqin, 2017. "Integrated processes of anaerobic digestion and pyrolysis for higher bioenergy recovery from lignocellulosic biomass: A brief review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 1272-1287.
    13. Angelika Gryta & Kamil Skic & Agnieszka Adamczuk & Anna Skic & Magdalena Marciniak & Grzegorz Józefaciuk & Patrycja Boguta, 2023. "The Importance of the Targeted Design of Biochar Physicochemical Properties in Microbial Inoculation for Improved Agricultural Productivity—A Review," Agriculture, MDPI, vol. 14(1), pages 1-43, December.
    14. Park, Jonghyun & Yim, Jun Ho & Cho, Seong-Heon & Jung, Sungyup & Tsang, Yiu Fai & Chen, Wei-Hsin & Jeon, Young Jae & Kwon, Eilhann E., 2024. "A virtuous cycle for thermal treatment of polyvinyl chloride and fermentation of lignocellulosic biomass," Applied Energy, Elsevier, vol. 362(C).
    15. Shen, Ye & Li, Xian & Yao, Zhiyi & Cui, Xiaoqiang & Wang, Chi-Hwa, 2019. "CO2 gasification of woody biomass: Experimental study from a lab-scale reactor to a small-scale autothermal gasifier," Energy, Elsevier, vol. 170(C), pages 497-506.
    16. Ghosh, Shiladitya & Chowdhury, Ranjana & Bhattacharya, Pinaki, 2017. "Sustainability of cereal straws for the fermentative production of second generation biofuels: A review of the efficiency and economics of biochemical pretreatment processes," Applied Energy, Elsevier, vol. 198(C), pages 284-298.
    17. Jiang, Haifeng & Liu, Haipeng & Dong, Jiaxin & Song, Jiaxing & Deng, Sunhua & Chen, Jie & Zhang, Yu & Hong, Wenpeng, 2022. "Enhancing ketones and syngas production by CO2-assisted catalytic pyrolysis of cellulose with the Ce–Co–Na ternary catalyst," Energy, Elsevier, vol. 250(C).
    18. Hassan, Shady S. & Williams, Gwilym A. & Jaiswal, Amit K., 2019. "Moving towards the second generation of lignocellulosic biorefineries in the EU: Drivers, challenges, and opportunities," Renewable and Sustainable Energy Reviews, Elsevier, vol. 101(C), pages 590-599.
    19. Wei, Yimeng & Zhuang, Zitong & Shi, Jinwen & Jin, Hui, 2024. "Thermochemical conversion of guaiacol with supercritical CO2: Experimental insights," Energy, Elsevier, vol. 299(C).
    20. Riva, Lorenzo & Nielsen, Henrik Kofoed & Skreiberg, Øyvind & Wang, Liang & Bartocci, Pietro & Barbanera, Marco & Bidini, Gianni & Fantozzi, Francesco, 2019. "Analysis of optimal temperature, pressure and binder quantity for the production of biocarbon pellet to be used as a substitute for coke," Applied Energy, Elsevier, vol. 256(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:15:y:2022:i:15:p:5430-:d:873081. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.