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Biomass Potential for Producing Power via Green Hydrogen

Author

Listed:
  • Nestor Sanchez

    (Group of Energy, Materials, and Environment, Department of Chemical and Biochemical Processes, Faculty of Engineering, Universidad de La Sabana, Chia 250001, Colombia)

  • David Rodríguez-Fontalvo

    (Group of Energy, Materials, and Environment, Department of Chemical and Biochemical Processes, Faculty of Engineering, Universidad de La Sabana, Chia 250001, Colombia)

  • Bernay Cifuentes

    (Faculty of Engineering, Chemical Engineering, Universidad de La Salle, Bogotá 111711, Colombia)

  • Nelly M. Cantillo

    (Group of Energy, Materials, and Environment, Department of Chemical and Biochemical Processes, Faculty of Engineering, Universidad de La Sabana, Chia 250001, Colombia)

  • Miguel Ángel Uribe Laverde

    (Group of Energy, Materials, and Environment, Department of Chemical and Biochemical Processes, Faculty of Engineering, Universidad de La Sabana, Chia 250001, Colombia)

  • Martha Cobo

    (Group of Energy, Materials, and Environment, Department of Chemical and Biochemical Processes, Faculty of Engineering, Universidad de La Sabana, Chia 250001, Colombia)

Abstract

Hydrogen (H 2 ) has become an important energy vector for mitigating the effects of climate change since it can be obtained from renewable sources and can be fed to fuel cells for producing power. Bioethanol can become a green H 2 source via Ethanol Steam Reforming (ESR) but several variables influence the power production in the fuel cell. Herein, we explored and optimized the main variables that affect this power production. The process includes biomass fermentation, bioethanol purification, H 2 production via ESR, syngas cleaning by a CO-removal reactor, and power production in a high temperature proton exchange membrane fuel cell (HT-PEMFC). Among the explored variables, the steam-to-ethanol molar ratio (S/E) employed in the ESR has the strongest influence on power production, process efficiency, and energy consumption. This effect is followed by other variables such as the inlet ethanol concentration and the ESR temperature. Although the CO-removal reactor did not show a significant effect on power production, it is key to increase the voltage on the fuel cell and consequently the power production. Optimization was carried out by the response surface methodology (RSM) and showed a maximum power of 0.07 kWh kg −1 of bioethanol with an efficiency of 17%, when ESR temperature is 700 °C. These values can be reached from different bioethanol sources as the S/E and CO-removal temperature are changed accordingly with the inlet ethanol concentration. Because there is a linear correlation between S/E and ethanol concentration, it is possible to select a proper S/E and CO-removal temperature to maximize the power generation in the HT-PEMFC via ESR. This study serves as a starting point to diversify the sources for producing H 2 and moving towards a H 2 -economy.

Suggested Citation

  • Nestor Sanchez & David Rodríguez-Fontalvo & Bernay Cifuentes & Nelly M. Cantillo & Miguel Ángel Uribe Laverde & Martha Cobo, 2021. "Biomass Potential for Producing Power via Green Hydrogen," Energies, MDPI, vol. 14(24), pages 1-18, December.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:24:p:8366-:d:700474
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    References listed on IDEAS

    as
    1. Jin, Xianchun & Ma, Jiangshan & Song, Jianing & Liu, Gao-Qiang, 2021. "Promoted bioethanol production through fed-batch semisimultaneous saccharification and fermentation at a high biomass load of sodium carbonate-pretreated rice straw," Energy, Elsevier, vol. 226(C).
    2. Sanchez, Nestor & Ruiz, Ruth & Rödl, Anne & Cobo, Martha, 2021. "Technical and environmental analysis on the power production from residual biomass using hydrogen as energy vector," Renewable Energy, Elsevier, vol. 175(C), pages 825-839.
    3. Jeffrey D. Sachs & Guido Schmidt-Traub & Mariana Mazzucato & Dirk Messner & Nebojsa Nakicenovic & Johan Rockström, 2019. "Six Transformations to achieve the Sustainable Development Goals," Nature Sustainability, Nature, vol. 2(9), pages 805-814, September.
    4. Sharma, Yogesh Chandra & Kumar, Ashutosh & Prasad, Ram & Upadhyay, Siddh Nath, 2017. "Ethanol steam reforming for hydrogen production: Latest and effective catalyst modification strategies to minimize carbonaceous deactivation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 89-103.
    5. Geonhui Gwak & Minwoo Kim & Dohwan Kim & Muhammad Faizan & Kyeongmin Oh & Jaeseung Lee & Jaeyoo Choi & Nammin Lee & Kisung Lim & Hyunchul Ju, 2019. "Performance and Efficiency Analysis of an HT-PEMFC System with an Absorption Chiller for Tri-Generation Applications," Energies, MDPI, vol. 12(5), pages 1-21, March.
    6. Tahereh Soleymani Angili & Katarzyna Grzesik & Anne Rödl & Martin Kaltschmitt, 2021. "Life Cycle Assessment of Bioethanol Production: A Review of Feedstock, Technology and Methodology," Energies, MDPI, vol. 14(10), pages 1-18, May.
    7. Lu, Jie & Song, Fuyu & Liu, Hao & Chang, Chengcheng & Cheng, Yi & Wang, Haisong, 2021. "Production of high concentration bioethanol from reed by combined liquid hot water and sodium carbonate-oxygen pretreatment," Energy, Elsevier, vol. 217(C).
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    Cited by:

    1. Sara Domínguez & Bernay Cifuentes & Felipe Bustamante & Nelly M. Cantillo & César L. Barraza-Botet & Martha Cobo, 2022. "On the Potential of Blue Hydrogen Production in Colombia: A Fossil Resource-Based Assessment for Low-Emission Hydrogen," Sustainability, MDPI, vol. 14(18), pages 1-18, September.
    2. Sebastián Mantilla & Diogo M. F. Santos, 2022. "Green and Blue Hydrogen Production: An Overview in Colombia," Energies, MDPI, vol. 15(23), pages 1-21, November.
    3. Juan Félix González & Carmen María Álvez-Medina & Sergio Nogales-Delgado, 2023. "Biogas Steam Reforming in Wastewater Treatment Plants: Opportunities and Challenges," Energies, MDPI, vol. 16(17), pages 1-35, September.

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