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In Situ Catalytic Methanation of Real Steelworks Gases

Author

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  • Philipp Wolf-Zoellner

    (Chair of Process Technology and Industrial Environmental Protection, Montanuniversität Leoben, Franz-Josef-Strasse 18, 8700 Leoben, Austria)

  • Ana Roza Medved

    (Chair of Process Technology and Industrial Environmental Protection, Montanuniversität Leoben, Franz-Josef-Strasse 18, 8700 Leoben, Austria)

  • Markus Lehner

    (Chair of Process Technology and Industrial Environmental Protection, Montanuniversität Leoben, Franz-Josef-Strasse 18, 8700 Leoben, Austria)

  • Nina Kieberger

    (Voestalpine Stahl GmbH, Research and Development Ironmaking, Voestalpine Straße 3, 4020 Linz, Austria)

  • Katharina Rechberger

    (K1-MET GmbH, Stahlstraße 14, 4020 Linz, Austria)

Abstract

The by-product gases from the blast furnace and converter of an integrated steelworks highly contribute to today’s global CO 2 emissions. Therefore, the steel industry is working on solutions to utilise these gases as a carbon source for product synthesis in order to reduce the amount of CO 2 that is released into the environment. One possibility is the conversion of CO 2 and CO to synthetic natural gas through methanation. This process is currently extensively researched, as the synthetic natural gas can be directly utilised in the integrated steelworks again, substituting for natural gas. This work addresses the in situ methanation of real steelworks gases in a lab-scaled, three-stage reactor setup, whereby the by-product gases are directly bottled at an integrated steel plant during normal operation, and are not further treated, i.e., by a CO 2 separation step. Therefore, high shares of nitrogen are present in the feed gas for the methanation. Furthermore, due to the catalyst poisons present in the only pre-cleaned steelworks gases, an additional gas-cleaning step based on CuO-coated activated carbon is implemented to prevent an instant catalyst deactivation. Results show that, with the filter included, the steady state methanation of real blast furnace and converter gases can be performed without any noticeable deactivation in the catalyst performance.

Suggested Citation

  • Philipp Wolf-Zoellner & Ana Roza Medved & Markus Lehner & Nina Kieberger & Katharina Rechberger, 2021. "In Situ Catalytic Methanation of Real Steelworks Gases," Energies, MDPI, vol. 14(23), pages 1-22, December.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:23:p:8131-:d:694841
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    References listed on IDEAS

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    1. Uribe-Soto, Wilmar & Portha, Jean-François & Commenge, Jean-Marc & Falk, Laurent, 2017. "A review of thermochemical processes and technologies to use steelworks off-gases," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 809-823.
    2. Philipp Biegger & Florian Kirchbacher & Ana Roza Medved & Martin Miltner & Markus Lehner & Michael Harasek, 2018. "Development of Honeycomb Methanation Catalyst and Its Application in Power to Gas Systems," Energies, MDPI, vol. 11(7), pages 1-17, June.
    3. Witte, Julia & Calbry-Muzyka, Adelaide & Wieseler, Tanja & Hottinger, Peter & Biollaz, Serge M.A. & Schildhauer, Tilman J., 2019. "Demonstrating direct methanation of real biogas in a fluidised bed reactor," Applied Energy, Elsevier, vol. 240(C), pages 359-371.
    4. Serge Roudier & Luis Delgado Sancho & Rainer Remus & Miguel Aguado-Monsonet, 2013. "Best Available Techniques (BAT) Reference Document for Iron and Steel Production: Industrial Emissions Directive 2010/75/EU: Integrated Pollution Prevention and Control," JRC Research Reports JRC69967, Joint Research Centre.
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    Cited by:

    1. Alexander Hauser & Alexander Feldner & Peter Treiber & Fabian Grimm & Jürgen Karl, 2023. "Utilization of Synthetic Steel Gases in an Additively Manufactured Reactor for Catalytic Methanation," Sustainability, MDPI, vol. 15(9), pages 1-24, May.
    2. Michael Bampaou & Kyriakos Panopoulos & Panos Seferlis & Amaia Sasiain & Stephane Haag & Philipp Wolf-Zoellner & Markus Lehner & Leokadia Rog & Przemyslaw Rompalski & Sebastian Kolb & Nina Kieberger &, 2022. "Economic Evaluation of Renewable Hydrogen Integration into Steelworks for the Production of Methanol and Methane," Energies, MDPI, vol. 15(13), pages 1-26, June.

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