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Comparison of Pyrolysis Liquids from Continuous and Batch Biochar Production—Influence of Feedstock Evidenced by FTICR MS

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  • Wolfram Buss

    (UK Biochar Research Centre, School of GeoSciences, University of Edinburgh, Crew Building, Alexander Crum, Brown Road, Edinburgh EH9 3FF, UK
    Research School of Biology, Australian National University, 134 Linnaeus Way, Canberra 2601, Australia
    Equal contributing authors.)

  • Jasmine Hertzog

    (LCP-A2MC, FR 2843 Institut Jean Barriol de Chimie et Physique Moléculaires et Biomoléculaires, FR 3624 Réseau National de Spectrométrie de Masse FT-ICR à très Haut Champ, Université de Lorraine, ICPM, 1 Boulevard Arago, CEDEX 03, 57078 Metz, France
    Equal contributing authors.)

  • Julian Pietrzyk

    (UK Biochar Research Centre, School of GeoSciences, University of Edinburgh, Crew Building, Alexander Crum, Brown Road, Edinburgh EH9 3FF, UK)

  • Vincent Carré

    (LCP-A2MC, FR 2843 Institut Jean Barriol de Chimie et Physique Moléculaires et Biomoléculaires, FR 3624 Réseau National de Spectrométrie de Masse FT-ICR à très Haut Champ, Université de Lorraine, ICPM, 1 Boulevard Arago, CEDEX 03, 57078 Metz, France)

  • C. Logan Mackay

    (SIRCAMS, School of Chemistry, University of Edinburgh, Edinburgh EH9 3FJ, UK)

  • Frédéric Aubriet

    (LCP-A2MC, FR 2843 Institut Jean Barriol de Chimie et Physique Moléculaires et Biomoléculaires, FR 3624 Réseau National de Spectrométrie de Masse FT-ICR à très Haut Champ, Université de Lorraine, ICPM, 1 Boulevard Arago, CEDEX 03, 57078 Metz, France)

  • Ondřej Mašek

    (UK Biochar Research Centre, School of GeoSciences, University of Edinburgh, Crew Building, Alexander Crum, Brown Road, Edinburgh EH9 3FF, UK)

Abstract

Bio-oils from biomass pyrolysis can be a resource for upgrading to chemicals or fuels. Here, for the first time, we compare the composition of bio-oils produced from two feedstocks (wheat straw, softwood) in pyrolysis units of different mode of operation (continuous—rotary kiln vs. batch) using Fourier transform ion cyclotron resonance mass spectrometry (FTICR MS) in different ionization modes (APPI (+), ESI (+/−)). Our results demonstrate that the pyrolysis unit design had only a minor influence on the composition of bio-oils produced from low-mineral containing wood biomass. Yet, the wheat straw-derived bio-oil produced in the continuous unit comprised lower molecular weight compounds with fewer oxygen-containing functional groups and lower O/C and H/C ratios, compared to bio-oils from batch pyrolysis. Longer residence time of vapours in the heated zone in the rotary kiln and a higher mineral content in wheat straw resulted in increased catalytically-mediated secondary reactions that favoured further bio-oil decomposition. This work shows for the first time that it is possible to produce distinct bio-oils without the need for external catalyst addition, by matching reactor type/design and feedstock.

Suggested Citation

  • Wolfram Buss & Jasmine Hertzog & Julian Pietrzyk & Vincent Carré & C. Logan Mackay & Frédéric Aubriet & Ondřej Mašek, 2020. "Comparison of Pyrolysis Liquids from Continuous and Batch Biochar Production—Influence of Feedstock Evidenced by FTICR MS," Energies, MDPI, vol. 14(1), pages 1-14, December.
    • Handle: RePEc:gam:jeners:v:14:y:2020:i:1:p:9-:d:466337
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    References listed on IDEAS

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    1. Junming Zhu & Chengming Fan & Haijia Shi & Lei Shi, 2019. "Efforts for a Circular Economy in China: A Comprehensive Review of Policies," Journal of Industrial Ecology, Yale University, vol. 23(1), pages 110-118, February.
    2. Bridgwater, A. V. & Peacocke, G. V. C., 2000. "Fast pyrolysis processes for biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 4(1), pages 1-73, March.
    3. Eleni F. Iliopoulou & Kostas S. Triantafyllidis & Angelos A. Lappas, 2019. "Overview of catalytic upgrading of biomass pyrolysis vapors toward the production of fuels and high‐value chemicals," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 8(1), January.
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    1. Shi, Ziyi & Jin, Yanghao & Svanberg, Rikard & Han, Tong & Minidis, Alexander B.E. & Ann-Sofi, Kindstedt Danielsson & Kjeldsen, Christian & Jönsson, Pär G. & Yang, Weihong, 2023. "Continuous catalytic pyrolysis of biomass using a fluidized bed with commercial-ready catalysts for scale-up," Energy, Elsevier, vol. 273(C).

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