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Thermal Degradation Kinetics and FT-IR Analysis on the Pyrolysis of Pinus pseudostrobus , Pinus leiophylla and Pinus montezumae as Forest Waste in Western Mexico

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  • José Juan Alvarado Flores

    (Faculty of Wood Engineering and Technology, University Michoacana of San Nicolas of Hidalgo, Edif. D, University Cd, Morelia C.P. 58060, Michoacán, Mexico)

  • José Guadalupe Rutiaga Quiñones

    (Faculty of Wood Engineering and Technology, University Michoacana of San Nicolas of Hidalgo, Edif. D, University Cd, Morelia C.P. 58060, Michoacán, Mexico)

  • María Liliana Ávalos Rodríguez

    (Center for Research in Environmental Geography, National Autonomous University of Mexico, Morelia C.P. 58190, Michoacán, Mexico)

  • Jorge Víctor Alcaraz Vera

    (Institute of Economic and Business Research, University Michoacana of San Nicolas of Hidalgo, University Cd, Morelia C.P. 58060, Michoacán, Mexico)

  • Jaime Espino Valencia

    (Faculty of Chemical Engineering, University Michoacana of San Nicolas of Hidalgo, Edif. V-1, University Cd, Morelia C.P. 58060, Michoacán, Mexico)

  • Santiago José Guevara Martínez

    (Faculty of Chemical Engineering, University Michoacana of San Nicolas of Hidalgo, Edif. V-1, University Cd, Morelia C.P. 58060, Michoacán, Mexico)

  • Francisco Márquez Montesino

    (Centre for the Study of Energy and Sustainable Technologies, University of Pinar del Rio, Martí 270 Final, C.P. Pinar del Rio 20100, Cuba)

  • Antonio Alfaro Rosas

    (Faculty of Wood Engineering and Technology, University Michoacana of San Nicolas of Hidalgo, Edif. D, University Cd, Morelia C.P. 58060, Michoacán, Mexico)

Abstract

For the first time, a study has been carried out on the pyrolysis of wood residues from Pinus pseudostrobus , Pinus leiophylla and Pinus montezumae , from an area in Western México using TGA analysis to determine the main kinetic parameters ( Ea and Z ) at different heating rates in a N 2 atmosphere. The samples were heated from 25 °C to 800 °C with six different heating rates 5–30 °C min −1 . The Ea , was calculated using different widely known mathematical models such as Friedman, Flynn-Wall-Ozawa and Kissinger-Akahira-Sunose. The Ea value of 126.58, 123.22 and 112.72 kJ/mol ( P. pseudostrobus ), 146.15, 143.24 and 132.76 kJ/mol ( P. leiophylla ) and 148.12, 151.8 and 141.25 kJ/mol ( P. montezumae ) respectively, was found for each method. A variation in Ea with respect to conversion was observed with the three models used, revealing that pyrolysis of pines progresses through more complex, multi-stage kinetics. FT-IR spectroscopy was conducted to determine the functional groups present in the three species of conifers. This research will allow future decisions to be made, and possibly, to carry out this process in a biomass reactor and therefore the production of H 2 for the generation of energy through a fuel cell.

Suggested Citation

  • José Juan Alvarado Flores & José Guadalupe Rutiaga Quiñones & María Liliana Ávalos Rodríguez & Jorge Víctor Alcaraz Vera & Jaime Espino Valencia & Santiago José Guevara Martínez & Francisco Márquez Mo, 2020. "Thermal Degradation Kinetics and FT-IR Analysis on the Pyrolysis of Pinus pseudostrobus , Pinus leiophylla and Pinus montezumae as Forest Waste in Western Mexico," Energies, MDPI, vol. 13(4), pages 1-25, February.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:4:p:969-:d:323510
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    References listed on IDEAS

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    1. Jing Sun & Wenlong Wang & Zhen Liu & Qingluan Ma & Chao Zhao & Chunyuan Ma, 2012. "Kinetic Study of the Pyrolysis of Waste Printed Circuit Boards Subject to Conventional and Microwave Heating," Energies, MDPI, vol. 5(9), pages 1-12, August.
    2. Manzano-Agugliaro, F. & Alcayde, A. & Montoya, F.G. & Zapata-Sierra, A. & Gil, C., 2013. "Scientific production of renewable energies worldwide: An overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 134-143.
    3. Kantarelis, E. & Yang, W. & Blasiak, W. & Forsgren, C. & Zabaniotou, A., 2011. "Thermochemical treatment of E-waste from small household appliances using highly pre-heated nitrogen-thermogravimetric investigation and pyrolysis kinetics," Applied Energy, Elsevier, vol. 88(3), pages 922-929, March.
    4. A.V. Bridgwater, 2007. "The production of biofuels and renewable chemicals by fast pyrolysis of biomass," International Journal of Global Energy Issues, Inderscience Enterprises Ltd, vol. 27(2), pages 160-203.
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    Cited by:

    1. José Alberto Soria-González & Raúl Tauro & José Juan Alvarado-Flores & Víctor Manuel Berrueta-Soriano & José Guadalupe Rutiaga-Quiñones, 2022. "Avocado Tree Pruning Pellets ( Persea americana Mill.) for Energy Purposes: Characterization and Quality Evaluation," Energies, MDPI, vol. 15(20), pages 1-18, October.
    2. José Juan Alvarado Flores & Jorge Víctor Alcaraz Vera & María Liliana Ávalos Rodríguez & Luis Bernardo López Sosa & José Guadalupe Rutiaga Quiñones & Luís Fernando Pintor Ibarra & Francisco Márquez Mo, 2022. "Analysis of Pyrolysis Kinetic Parameters Based on Various Mathematical Models for More than Twenty Different Biomasses: A Review," Energies, MDPI, vol. 15(18), pages 1-19, September.
    3. João Silva & Senhorinha Teixeira & José Teixeira, 2023. "A Review of Biomass Thermal Analysis, Kinetics and Product Distribution for Combustion Modeling: From the Micro to Macro Perspective," Energies, MDPI, vol. 16(18), pages 1-23, September.

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