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The Effect of Solvents on the Performance of CH 3 NH 3 PbI 3 Perovskite Solar Cells

Author

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  • Pao-Hsun Huang

    (Institute of Microelectronics, Department of Electrical Engineering, National Cheng Kung University, Tainan 70101, Taiwan)

  • Yeong-Her Wang

    (Institute of Microelectronics, Department of Electrical Engineering, National Cheng Kung University, Tainan 70101, Taiwan)

  • Jhong-Ciao Ke

    (Institute of Microelectronics, Department of Electrical Engineering, National Cheng Kung University, Tainan 70101, Taiwan)

  • Chien-Jung Huang

    (Department of Applied Physics, National University of Kaohsiung, Nanzih, Kaohsiung 81148, Taiwan)

Abstract

The properties of perovskite solar cells (PSCs) fabricated using various solvents was studied. The devices had an indium tin oxide (ITO)/poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOT:PSS)/CH 3 NH 3 PbI 3 (fabricated by using various solvents)/fullerene (C 60 )/bathocuproine (BCP)/silver (Ag) structure. The solvents used were dimethylformamide (DMF), γ-butyrolactone (GBL), dimethyl sulfoxide (DMSO), a mixture of DMSO and DMF (1:1 v / v ), and a mixture of DMSO and GBL (DMSO: GBL, 1:1 v / v ), respectively. The power conversion efficiency (PCE) of the device fabricated using DMF is zero, which is attributed to the poor coverage of CH 3 NH 3 PbI 3 film on the substrate. In addition, the PCE of the device made using GBL is only 1.74% due to the low solubility of PbI 2 and CH 3 NH 3 I. In contrast, the PCE of the device fabricated using the solvents containing DMSO showed better performance. This is ascribed to the high solubilization properties and strong coordination of DMSO. As a result, a PCE of 9.77% was obtained using a mixed DMSO:GBL solvent due to the smooth surface, uniform film coverage on the substrate and the high crystallization of the perovskite structure. Finally, a mixed DMSO: DMF:GBL (5:2:3 v / v / v ) solvent that combined the advantages of each solvent was used to fabricate a device, leading to a further improvement of the PCE of the resulting PSC to 10.84%.

Suggested Citation

  • Pao-Hsun Huang & Yeong-Her Wang & Jhong-Ciao Ke & Chien-Jung Huang, 2017. "The Effect of Solvents on the Performance of CH 3 NH 3 PbI 3 Perovskite Solar Cells," Energies, MDPI, vol. 10(5), pages 1-8, April.
    • Handle: RePEc:gam:jeners:v:10:y:2017:i:5:p:599-:d:97227
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    References listed on IDEAS

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    1. Julian Burschka & Norman Pellet & Soo-Jin Moon & Robin Humphry-Baker & Peng Gao & Mohammad K. Nazeeruddin & Michael Grätzel, 2013. "Sequential deposition as a route to high-performance perovskite-sensitized solar cells," Nature, Nature, vol. 499(7458), pages 316-319, July.
    2. Yicheng Zhao & Jing Wei & Heng Li & Yin Yan & Wenke Zhou & Dapeng Yu & Qing Zhao, 2016. "A polymer scaffold for self-healing perovskite solar cells," Nature Communications, Nature, vol. 7(1), pages 1-9, April.
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