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Surface Assisted Combustion of Hydrogen-Oxygen Mixture in Nanobubbles Produced by Electrolysis

Author

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  • Alexander Prokaznikov

    (Yaroslavl Branch of the Institute of Physics and Technology, Russian Academy of Sciencies, 150007 Yaroslavl, Russia
    P. G. Demidov Yaroslavl State University, Sovetskaya 14, 150000 Yaroslavl, Russia)

  • Niels Tas

    (MESA + Institute for Nanotechnology, University of Twente, PO Box 217, 7500 AE Enschede, The Netherlands)

  • Vitaly Svetovoy

    (Yaroslavl Branch of the Institute of Physics and Technology, Russian Academy of Sciencies, 150007 Yaroslavl, Russia
    Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands)

Abstract

The spontaneous combustion of hydrogen–oxygen mixture observed in nanobubbles at room temperature is a puzzling phenomenon that has no explanation in the standard combustion theory. We suggest that the hydrogen atoms needed to ignite the reaction could be generated on charged sites at the gas–liquid interface. Equations of chemical kinetics augmented by the surface dissociation of hydrogen molecules are solved, keeping the dissociation probability as a parameter. It is predicted that in contrast with the standard combustion, the surface-assisted process can proceed at room temperature, resulting not only in water, but also in a perceptible amount of hydrogen peroxide in the final state. The combustion time for the nanobubbles with a size of about 100 nm is in the range of 1–100 ns, depending on the dissociation probability.

Suggested Citation

  • Alexander Prokaznikov & Niels Tas & Vitaly Svetovoy, 2017. "Surface Assisted Combustion of Hydrogen-Oxygen Mixture in Nanobubbles Produced by Electrolysis," Energies, MDPI, vol. 10(2), pages 1-10, February.
    • Handle: RePEc:gam:jeners:v:10:y:2017:i:2:p:178-:d:89385
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    References listed on IDEAS

    as
    1. Chou, S.K. & Yang, W.M. & Chua, K.J. & Li, J. & Zhang, K.L., 2011. "Development of micro power generators - A review," Applied Energy, Elsevier, vol. 88(1), pages 1-16, January.
    2. Yuri T. Didenko & Kenneth S. Suslick, 2002. "The energy efficiency of formation of photons, radicals and ions during single-bubble cavitation," Nature, Nature, vol. 418(6896), pages 394-397, July.
    3. Vitaly Svetovoy & Alexander Postnikov & Ilia Uvarov & Remco Sanders & Gijs Krijnen, 2016. "Overcoming the Fundamental Limit: Combustion of a Hydrogen-Oxygen Mixture in Micro- and Nano-Bubbles," Energies, MDPI, vol. 9(2), pages 1-17, February.
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    Cited by:

    1. Vitaly B. Svetovoy & Alexander V. Prokaznikov & Alexander V. Postnikov & Ilia V. Uvarov & George Palasantzas, 2019. "Explosion of Microbubbles Generated by the Alternating Polarity Water Electrolysis," Energies, MDPI, vol. 13(1), pages 1-18, December.
    2. Karol Ulatowski & Radosław Jeżak & Paweł Sobieszuk, 2021. "Impact of Process Parameters on the Diameter of Nanobubbles Generated by Electrolysis on Platinum-Coated Titanium Electrodes Using Box–Behnken Experimental Design," Energies, MDPI, vol. 14(9), pages 1-14, April.

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