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Dimensional effects of nanostructured Mg/MgH2 for hydrogen storage applications: A review

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  • Sadhasivam, T.
  • Kim, Hee-Tak
  • Jung, Seunghun
  • Roh, Sung-Hee
  • Park, Jeong-Hun
  • Jung, Ho-Young

Abstract

Hydrogen is regarded as an ideal fuel for vehicle applications owing to its high chemical energy. However, for on-board energy storage, fuel cell electric vehicles need compact, light, and affordable hydrogen storage system to replace the pressurized hydrogen tanks. In this regard, various materials and composites have been developed for denser and safer hydrogen storage. Among them, Mg is considered as a highly promising material to store the hydrogen in terms of gravimetric and volumetric capacity. However, because of its higher thermodynamic stability and sluggish hydrogen sorption kinetics, the sorption temperature is high and the sorption time is long, limiting for practical usage. Nanoscale material designs with various dimensionalities that have been extensively studied and used in countless research and development sectors, which can provide new strategies to tackle the limitations of Mg based hydrogen storage system. This review describes the fundamental properties, preparation, activation kinetics and thermodynamic stability of various nanostructured Mg/MgH2 materials (including bulk particles, nanofilms, nanowires and nanoparticles confined in nanoporous carbon structures and encapsulated by polymers) for feasible hydrogen storage applications, and summarizes their dimensional effects.

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  • Sadhasivam, T. & Kim, Hee-Tak & Jung, Seunghun & Roh, Sung-Hee & Park, Jeong-Hun & Jung, Ho-Young, 2017. "Dimensional effects of nanostructured Mg/MgH2 for hydrogen storage applications: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 523-534.
    • Handle: RePEc:eee:rensus:v:72:y:2017:i:c:p:523-534
    DOI: 10.1016/j.rser.2017.01.107
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    1. Ding, Xin & Chen, Ruirun & Chen, Xiaoyu & Cao, Wenchao & Su, Yanqing & Ding, Hongsheng & Guo, Jingjie, 2020. "Formation of Mg2Ni/Cu phase and de-/hydrogenation behavior of Mg91Ni9-xCux alloy at moderate temperatures," Renewable Energy, Elsevier, vol. 166(C), pages 81-90.
    2. Wang, Peng & Wang, Zexuan & Tian, Zhihui & Xia, Chaoqun & Yang, Tai & Liang, Chunyong & Li, Qiang, 2020. "Enhanced hydrogen absorption and desorption properties of MgH2 with NiS2: The catalytic effect of in-situ formed MgS and Mg2NiH4 phases," Renewable Energy, Elsevier, vol. 160(C), pages 409-417.
    3. Muntasir Shovon, Shaik & Ahamed Akash, Faysal & Abdur Rahman, Md & Rahman, Wahida & Chakraborty, Prosenjeet & Monir, Minhaj Uddin & Sarkar, Shaheen M. & Abd Aziz, Azrina & Chowdhury, Shahariar, 2024. "Advancements in hydrogen generation, storage, and utilizations: A comprehensive review of current trends in Bangladesh," Energy, Elsevier, vol. 292(C).
    4. Lutz, Michael & Linder, Marc & Bürger, Inga, 2020. "High capacity, low pressure hydrogen storage based on magnesium hydride and thermochemical heat storage: Experimental proof of concept," Applied Energy, Elsevier, vol. 271(C).
    5. Montazerinejad, H. & Eicker, U., 2022. "Recent development of heat and power generation using renewable fuels: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 165(C).
    6. Omar Mounkachi & Asmae Akrouchi & Ghassane Tiouitchi & Marwan Lakhal & Elmehdi Salmani & Abdelilah Benyoussef & Abdelkader Kara & Abdellah El Kenz & Hamid Ez-Zahraouy & Amine El Moutaouakil, 2021. "Stability, Electronic Structure and Thermodynamic Properties of Nanostructured MgH 2 Thin Films," Energies, MDPI, vol. 14(22), pages 1-10, November.
    7. Huaiyu Shao, 2017. "Heat Modeling and Material Development of Mg-Based Nanomaterials Combined with Solid Oxide Fuel Cell for Stationary Energy Storage," Energies, MDPI, vol. 10(11), pages 1-11, November.
    8. Yang, Tai & Wang, Peng & Li, Qiang & Xia, Chaoqun & Yin, Fuxing & Liang, Chunyong & Zhang, Yanghuan, 2018. "Hydrogen absorption and desorption behavior of Ni catalyzed Mg–Y–C–Ni nanocomposites," Energy, Elsevier, vol. 165(PA), pages 709-719.
    9. Hoang, Anh Tuan & Pandey, Ashok & Martinez De Osés, Francisco Javier & Chen, Wei-Hsin & Said, Zafar & Ng, Kim Hoong & Ağbulut, Ümit & Tarełko, Wiesław & Ölçer, Aykut I. & Nguyen, Xuan Phuong, 2023. "Technological solutions for boosting hydrogen role in decarbonization strategies and net-zero goals of world shipping: Challenges and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 188(C).
    10. Baldi, Francesco & Coraddu, Andrea & Kalikatzarakis, Miltiadis & Jeleňová, Diana & Collu, Maurizio & Race, Julia & Maréchal, François, 2022. "Optimisation-based system designs for deep offshore wind farms including power to gas technologies," Applied Energy, Elsevier, vol. 310(C).
    11. Wang, Zexuan & Tian, Zhihui & Yao, Pufan & Zhao, Huimin & Xia, Chaoqun & Yang, Tai, 2022. "Improved hydrogen storage kinetic properties of magnesium-based materials by adding Ni2P," Renewable Energy, Elsevier, vol. 189(C), pages 559-569.
    12. Kannaiyan, Kumaran & Lekshmi, G.S. & Ramakrishna, Seeram & Kang, Misook & Kumaravel, Vignesh, 2023. "Perspectives for the green hydrogen energy-based economy," Energy, Elsevier, vol. 284(C).

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