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Solid-state D102 dye sensitized/poly(3-hexylthiophene) hybrid solar cells on flexible Ti substrate

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  • Xue, Zhaosheng
  • Wang, Long
  • Liu, Wei
  • Liu, Bin

Abstract

Flexible solid-state dye sensitized solar cell is an important milestone for low-cost, large scale fabrication of dye-sensitized solar cells. Flexible solid-state dye-sensitized solar cell is fabricated for the first time on titanium substrates using D102 sensitizer and a sputtered platinum semi-transparent cathode. Devices are illuminated from the cathode side since titanium substrates are non-transparent. Due to rear-side illumination, significant proportion of radiation is absorbed and scattered by poly(3-hexylthiophene) and platinum, respectively. Limiting the amount of platinum and poly(3-hexylthiophene), up to a point, is found to enhance device efficiency. The amount of platinum and poly(3-hexylthiophene) is optimized on glass substrates before fabrication of flexible devices on titanium substrates. The rough surface of titanium substrates is smoothened until a mirror finish and the growth of a thin layer of native oxide enhanced the device efficiency. Under optimized conditions, an efficiency of 1.20% is obtained for devices fabricated on titanium foil substrates. The lower efficiency as compared to conventional devices is mainly due to light absorption/scattering from the poly(3-hexylthiophene) and platinum layers.

Suggested Citation

  • Xue, Zhaosheng & Wang, Long & Liu, Wei & Liu, Bin, 2014. "Solid-state D102 dye sensitized/poly(3-hexylthiophene) hybrid solar cells on flexible Ti substrate," Renewable Energy, Elsevier, vol. 72(C), pages 22-28.
    • Handle: RePEc:eee:renene:v:72:y:2014:i:c:p:22-28
    DOI: 10.1016/j.renene.2014.06.043
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    References listed on IDEAS

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    1. Edward J. W. Crossland & Nakita Noel & Varun Sivaram & Tomas Leijtens & Jack A. Alexander-Webber & Henry J. Snaith, 2013. "Mesoporous TiO2 single crystals delivering enhanced mobility and optoelectronic device performance," Nature, Nature, vol. 495(7440), pages 215-219, March.
    2. U. Bach & D. Lupo & P. Comte & J. E. Moser & F. Weissörtel & J. Salbeck & H. Spreitzer & M. Grätzel, 1998. "Solid-state dye-sensitized mesoporous TiO2 solar cells with high photon-to-electron conversion efficiencies," Nature, Nature, vol. 395(6702), pages 583-585, October.
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    1. Ali, N. & Hussain, A. & Ahmed, R. & Wang, M.K. & Zhao, C. & Haq, B. Ul & Fu, Y.Q., 2016. "Advances in nanostructured thin film materials for solar cell applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 59(C), pages 726-737.

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