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Hydrogen generation by aluminum alloy corrosion in aqueous acid solutions promoted by nanometal: Kinetics study

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  • Martínez-Salazar, A.L.
  • Melo-Banda, J.A.
  • Coronel-García, M.A.
  • González-Barbosa, J.J.
  • Domínguez-Esquivel, J.M.

Abstract

A novel process to obtain H2 from flat plate aluminum corrosion in aqueous acid solutions is described. A modified traditional shrinking core model has been developed to analyze kinetics behavior by including the effect of growing and textural changes of hydroxide layer during reaction. Modified model is fitted to experimental data. Initial diffusion coefficient, magnitude of the change in its value and the ratio of volume of the produced shell to volume of consumed core during reaction were determined by parameters obtained from fitting the proposed model to experimental data.

Suggested Citation

  • Martínez-Salazar, A.L. & Melo-Banda, J.A. & Coronel-García, M.A. & González-Barbosa, J.J. & Domínguez-Esquivel, J.M., 2020. "Hydrogen generation by aluminum alloy corrosion in aqueous acid solutions promoted by nanometal: Kinetics study," Renewable Energy, Elsevier, vol. 146(C), pages 2517-2523.
    • Handle: RePEc:eee:renene:v:146:y:2020:i:c:p:2517-2523
    DOI: 10.1016/j.renene.2019.08.103
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    References listed on IDEAS

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    1. Fan, Mei-Qiang & Mei, De-Sheng & Chen, Da & Lv, Chun-Ju & Shu, Kang-ying, 2011. "Portable hydrogen generation from activated Al–Li–Bi alloys in water," Renewable Energy, Elsevier, vol. 36(11), pages 3061-3067.
    2. Fan, Mei Qiang & Sun, Li Xian & Xu, Fen, 2011. "Hydrogen production for micro-fuel-cell from activated Al–Sn–Zn–X (X: hydride or halide) mixture in water," Renewable Energy, Elsevier, vol. 36(2), pages 519-524.
    3. Solé, Aran & Miró, Laia & Barreneche, Camila & Martorell, Ingrid & Cabeza, Luisa F., 2015. "Corrosion of metals and salt hydrates used for thermochemical energy storage," Renewable Energy, Elsevier, vol. 75(C), pages 519-523.
    4. Wang, Hongqi & Wang, Zhi & Shi, Zhihao & Gong, Xuzhong & Cao, Jianwei & Wang, Mingyong, 2017. "Facile hydrogen production from Al-water reaction promoted by choline hydroxide," Energy, Elsevier, vol. 131(C), pages 98-105.
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    1. Gai, Wei-Zhuo & Deng, Zhen-Yan, 2024. "Enhanced hydrogen production from Al-water reaction: Strategies, performances, mechanisms and applications," Renewable Energy, Elsevier, vol. 226(C).

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