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Effect of lignin, cellulose and hemicellulose from biomass on sulfur release behavior from dyeing sludge combustion

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  • Liu, Bo
  • Wan, Sha
  • Ye, Jianran
  • Zhao, Hui
  • Xue, Yongjie
  • Wang, Teng

Abstract

Co-combustion with biomass is recommended for treating dyeing sludge (DS) from the view of minimizing sulfur emissions. However, the sulfur emission from DS combustion depends on the lignin (L)/cellulose (C)/hemicellulose (H) ratio in the biomass, which is frequently overlooked. This study reveals the effect of biomass on the combustion characteristics and sulfur evolutions of DS combustion using triphenylmethyl mercaptan (TM) and L/C/H as model representative compounds of DS and biomass, respectively. Results indicated that the combustion behavior of the TM–biomass mixture was dominated by TM and secondarily by L/C/H. Although L/C/H brought forward the TM combustion, these biomass components (especially L) deteriorated the combustibility and burnout performances of the combustion. L/C/H promoted CH3SH and SO2 release at low temperatures but inhibited these emissions at high temperatures. The sulfur retention ratios of L, C, and H were 7.53 %, −5.75 %, and 0.17 %. TM–L interaction initially promoted and later inhibited the co-combustion process and the CH3SH and SO2 release. L/C/H addition reduced the E values of the mixtures and the co-combustion kinetics were dominated by Dn models. Residue analysis also indicated a dominant role of L in sulfur fixation, mainly because L additive created abundant adsorption sites in the co-combustion residue.

Suggested Citation

  • Liu, Bo & Wan, Sha & Ye, Jianran & Zhao, Hui & Xue, Yongjie & Wang, Teng, 2024. "Effect of lignin, cellulose and hemicellulose from biomass on sulfur release behavior from dyeing sludge combustion," Renewable Energy, Elsevier, vol. 228(C).
    • Handle: RePEc:eee:renene:v:228:y:2024:i:c:s0960148124007468
    DOI: 10.1016/j.renene.2024.120678
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    References listed on IDEAS

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    1. Zacharczuk, Wojciech & Andruszkiewicz, Artur & Tatarek, Andrzej & Alahmer, Ali & Alsaqoor, Sameh, 2021. "Effect of Ca-based additives on the capture of SO2 during combustion of pulverized lignite," Energy, Elsevier, vol. 231(C).
    2. Huang, Hongyi & Liu, Jingyong & Liu, Hui & Evrendilek, Fatih & Zhang, Gang & He, Yao, 2022. "Turning the co-combustion synergy of textile dyeing sludge and waste biochar into emission-to-bottom slag pollution controls toward a circular economy," Renewable Energy, Elsevier, vol. 194(C), pages 760-777.
    3. Yao, Xiwen & Zhou, Haodong & Xu, Kaili & Xu, Qingwei & Li, Li, 2020. "Investigation on the fusion characterization and melting kinetics of ashes from co-firing of anthracite and pine sawdust," Renewable Energy, Elsevier, vol. 145(C), pages 835-846.
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