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Experimental and theoretical feasibility study of methanol application for Echium oil-based biodiesel production

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  • Naraki, Mohamad mehdi
  • Parvasi, Payam
  • Jokar, Seyyed Mohammad
  • Iulianelli, Adolfo

Abstract

In this study, the effect of ultrasound waves on biodiesel production from methanol and Echium oil is evaluated experimentally under different operating conditions. A two-step esterification–transesterification process was applied to improve the biodiesel quality, and, in order to optimize the reaction conditions, the effect of variables such as methanol to oil molar ratio, KOH catalyst concentration and temperature were experimentally investigated. The results showed that the optimum biodiesel yield (97.2%) could be obtained at a catalyst concentration of 1.875% w.t, feed molar ratio equal to 9.65, and at 50 °C of operating temperature. The acid value, saponification numbers, iodine value, density, kinematic viscosity, fire point, cloud point and flash point were measured and compared with ASTM D6751 and EN 14214 standards. The results of the analysis showed that the produced biodiesel is a good alternative to fossil fuels. The results demonstrate that methanol and Echium Oil can be used as a proper feedstock for biofuel production. Furthermore, the kinetic study of transesterification is carried out for Echium oil production and the reaction rate constant and activation energy were determined. Finally, the sizing calculations and cost estimation of the Echium oil-based biodiesel production were investigated.

Suggested Citation

  • Naraki, Mohamad mehdi & Parvasi, Payam & Jokar, Seyyed Mohammad & Iulianelli, Adolfo, 2023. "Experimental and theoretical feasibility study of methanol application for Echium oil-based biodiesel production," Renewable Energy, Elsevier, vol. 202(C), pages 1241-1247.
    • Handle: RePEc:eee:renene:v:202:y:2023:i:c:p:1241-1247
    DOI: 10.1016/j.renene.2022.11.118
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    References listed on IDEAS

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    1. Chen, Jiaxin & Li, Ji & Dong, Wenyi & Zhang, Xiaolei & Tyagi, Rajeshwar D. & Drogui, Patrick & Surampalli, Rao Y., 2018. "The potential of microalgae in biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 336-346.
    2. Seyyedeh Faezeh Mirab Haghighi & Payam Parvasi & Seyyed Mohammad Jokar & Angelo Basile, 2021. "Investigating the Effects of Ultrasonic Frequency and Membrane Technology on Biodiesel Production from Chicken Waste," Energies, MDPI, vol. 14(8), pages 1-21, April.
    3. Badday, Ali Sabri & Abdullah, Ahmad Zuhairi & Lee, Keat Teong & Khayoon, Muataz Sh., 2012. "Intensification of biodiesel production via ultrasonic-assisted process: A critical review on fundamentals and recent development," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 4574-4587.
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    1. Moradkhani, Mohammad Amin & Hosseini, Seyyed Hossein & Song, Mengjie & Teimoori, Khalil, 2024. "Comprehensive data-driven methods for estimating the thermal conductivity of biodiesels and their blends with alcohols and fossil diesels," Renewable Energy, Elsevier, vol. 221(C).

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