IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v195y2022icp1300-1309.html
   My bibliography  Save this article

The reaction characteristics and mechanism of pine sawdust chemical-looping gasification based on CoFe2O4 oxygen carrier

Author

Listed:
  • Liu, Feng
  • Fang, Ruixue
  • Wang, Xufeng
  • Liu, Jing
  • Li, Yu

Abstract

Biomass chemical-looping gasification (BCLG) is a promising technology for high quality syngas production. CoFe2O4 with good redox stability and synergistically enhanced performance is considered as a better oxygen carrier. Herein, the gasification characteristic and mechanism between pine sawdust and CoFe2O4 were studied by using the thermodynamic calculation, thermogravimetric analysis (TGA) and fixed bed reactor experiments. Thermodynamic calculation reveals that the oxygen carrier to pine sawdust ratio, H2O volume fraction and reaction temperature of 0.08, 50%, and 900 °C, respectively, could be optimal for obtaining syngas with high quality and biomass conversion efficiency. CoFe2O4 can provide lattice oxygen for pine sawdust gasification and accelerate the carbon conversion rate of pine sawdust. The existence of Co in CoFe2O4 can synergistically improve the activity of Fe3+ and promote the further reduction of Fe3+ to Fe0. Experimental results verify that pine sawdust gasification process with an oxygen carrier to pine sawdust ratio of 0.08, reaction temperature of 900 °C, and H2O volume fraction of 50% has the highest syngas quality and biomass conversion. After five redox cycles, CoFe2O4 still maintains good reactivity and redox stability. These results can offer useful information for the utilization of biomass energy and can be used to improve the BCLG process.

Suggested Citation

  • Liu, Feng & Fang, Ruixue & Wang, Xufeng & Liu, Jing & Li, Yu, 2022. "The reaction characteristics and mechanism of pine sawdust chemical-looping gasification based on CoFe2O4 oxygen carrier," Renewable Energy, Elsevier, vol. 195(C), pages 1300-1309.
    • Handle: RePEc:eee:renene:v:195:y:2022:i:c:p:1300-1309
    DOI: 10.1016/j.renene.2022.06.134
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148122009752
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2022.06.134?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Huang, Zhen & He, Fang & Zhu, Huangqing & Chen, Dezhen & Zhao, Kun & Wei, Guoqiang & Feng, Yipeng & Zheng, Anqing & Zhao, Zengli & Li, Haibin, 2015. "Thermodynamic analysis and thermogravimetric investigation on chemical looping gasification of biomass char under different atmospheres with Fe2O3 oxygen carrier," Applied Energy, Elsevier, vol. 157(C), pages 546-553.
    2. Li, Jian & Tao, Junyu & Yan, Beibei & Jiao, Liguo & Chen, Guanyi & Hu, Jianli, 2021. "Review of microwave-based treatments of biomass gasification tar," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    3. Parthasarathy, Prakash & Narayanan, K. Sheeba, 2014. "Hydrogen production from steam gasification of biomass: Influence of process parameters on hydrogen yield – A review," Renewable Energy, Elsevier, vol. 66(C), pages 570-579.
    4. Huang, Zhen & Deng, Zhengbing & Chen, Dezhen & He, Fang & Liu, Shuai & Zhao, Kun & Wei, Guoqiang & Zheng, Anqing & Zhao, Zengli & Li, Haibin, 2017. "Thermodynamic analysis and kinetic investigations on biomass char chemical looping gasification using Fe-Ni bimetallic oxygen carrier," Energy, Elsevier, vol. 141(C), pages 1836-1844.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ren, Yi & Wang, Zhiyong & Chen, Jianbiao & Gao, Haojie & Guo, Kai & Wang, Xu & Wang, Xiaoyuan & Wang, Yinfeng & Chen, Haijun & Zhu, Jinjiao & Zhu, Yuezhao, 2023. "Effect of water/acetic acid washing pretreatment on biomass chemical looping gasification (BCLG) using cost-effective oxygen carrier from iron-rich sludge ash," Energy, Elsevier, vol. 272(C).
    2. Zeng, Jimin & Hu, Jiawei & Qiu, Yu & Zhang, Shuai & Zeng, Dewang & Xiao, Rui, 2019. "Multi-function of oxygen carrier for in-situ tar removal in chemical looping gasification: Naphthalene as a model compound," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    3. Nguyen, Nhut M. & Alobaid, Falah & Epple, Bernd, 2021. "Chemical looping gasification of torrefied woodchips in a bubbling fluidized bed test rig using iron-based oxygen carriers," Renewable Energy, Elsevier, vol. 172(C), pages 34-45.
    4. Samprón, Iván & de Diego, Luis F. & García-Labiano, Francisco & Izquierdo, María T., 2021. "Optimization of synthesis gas production in the biomass chemical looping gasification process operating under auto-thermal conditions," Energy, Elsevier, vol. 226(C).
    5. Zeng, Jimin & Xiao, Rui & Zhang, Shuai & Zhang, Huiyan & Zeng, Dewang & Qiu, Yu & Ma, Zhong, 2018. "Identifying iron-based oxygen carrier reduction during biomass chemical looping gasification on a thermogravimetric fixed-bed reactor," Applied Energy, Elsevier, vol. 229(C), pages 404-412.
    6. Ramos, Ana & Monteiro, Eliseu & Rouboa, Abel, 2019. "Numerical approaches and comprehensive models for gasification process: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 110(C), pages 188-206.
    7. Andrea Di Giuliano & Stefania Lucantonio & Katia Gallucci, 2021. "Devolatilization of Residual Biomasses for Chemical Looping Gasification in Fluidized Beds Made Up of Oxygen-Carriers," Energies, MDPI, vol. 14(2), pages 1-16, January.
    8. Song, Weiming & Zhou, Jianan & Li, Yujie & Yang, Jian & Cheng, Rijin, 2021. "New technology for producing high-quality combustible gas by high-temperature reaction of dust-removal coke powder in mixed atmosphere," Energy, Elsevier, vol. 233(C).
    9. Burra, K.G. & Hussein, M.S. & Amano, R.S. & Gupta, A.K., 2016. "Syngas evolutionary behavior during chicken manure pyrolysis and air gasification," Applied Energy, Elsevier, vol. 181(C), pages 408-415.
    10. Banerjee, Debarun & Kushwaha, Nidhi & Shetti, Nagaraj P. & Aminabhavi, Tejraj M. & Ahmad, Ejaz, 2022. "Green hydrogen production via photo-reforming of bio-renewable resources," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    11. Owen Sedej & Eric Mbonimpa & Trevor Sleight & Jeremy Slagley, 2022. "Application of Machine Learning to Predict the Performance of an EMIPG Reactor Using Data from Numerical Simulations," Energies, MDPI, vol. 15(7), pages 1-22, March.
    12. Ansari, Khursheed B. & Gaikar, Vilas G., 2019. "Investigating production of hydrocarbon rich bio-oil from grassy biomass using vacuum pyrolysis coupled with online deoxygenation of volatile products over metallic iron," Renewable Energy, Elsevier, vol. 130(C), pages 305-318.
    13. Hafizi, A. & Rahimpour, M.R. & Hassanajili, Sh., 2016. "Hydrogen production via chemical looping steam methane reforming process: Effect of cerium and calcium promoters on the performance of Fe2O3/Al2O3 oxygen carrier," Applied Energy, Elsevier, vol. 165(C), pages 685-694.
    14. Jiao, Liguo & Li, Jian & Yan, Beibei & Chen, Guanyi & Ahmed, Sarwaich, 2022. "Microwave torrefaction integrated with gasification: Energy and exergy analyses based on Aspen Plus modeling," Applied Energy, Elsevier, vol. 319(C).
    15. Arnob Das & Susmita Datta Peu, 2022. "A Comprehensive Review on Recent Advancements in Thermochemical Processes for Clean Hydrogen Production to Decarbonize the Energy Sector," Sustainability, MDPI, vol. 14(18), pages 1-42, September.
    16. Wang, Dechao & Jin, Lijun & Li, Yang & Yao, Demeng & Wang, Jiaofei & Hu, Haoquan, 2018. "Upgrading of vacuum residue with chemical looping partial oxidation over Ce doped Fe2O3," Energy, Elsevier, vol. 162(C), pages 542-553.
    17. Zhang, Guozhao & Liu, Hao & Wang, Jia & Wu, Baojia, 2018. "Catalytic gasification characteristics of rice husk with calcined dolomite," Energy, Elsevier, vol. 165(PB), pages 1173-1177.
    18. Xiang, Dong & Jin, Tong & Lei, Xinru & Liu, Shuai & Jiang, Yong & Dong, Zhongbing & Tao, Quanbao & Cao, Yan, 2018. "The high efficient synthesis of natural gas from a joint-feedstock of coke-oven gas and pulverized coke via a chemical looping combustion scheme," Applied Energy, Elsevier, vol. 212(C), pages 944-954.
    19. Fugang Zhu & Laihong Shen & Pengcheng Xu & Haoran Yuan & Ming Hu & Jingwei Qi & Yong Chen, 2022. "Numerical Simulation of an Improved Updraft Biomass Gasifier Based on Aspen Plus," IJERPH, MDPI, vol. 19(24), pages 1-11, December.
    20. Detchusananard, Thanaphorn & Im-orb, Karittha & Maréchal, François & Arpornwichanop, Amornchai, 2020. "Analysis of the sorption-enhanced chemical looping biomass gasification process: Performance assessment and optimization through design of experiment approach," Energy, Elsevier, vol. 207(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:195:y:2022:i:c:p:1300-1309. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.