IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v138y2019icp409-415.html
   My bibliography  Save this article

Vapor-feed low temperature direct methanol fuel cell with Pt and PtRu electrodes: Chemistry insight

Author

Listed:
  • Johánek, Viktor
  • Ostroverkh, Anna
  • Fiala, Roman

Abstract

The performance of a vapor-fed low-temperature direct methanol fuel cell (DMFC) with Nafion proton exchange membrane has been analyzed and compared to identical fuel cell assembly supplied with liquid methanol diluted in water. The cell was subjected to a wide range of methanol concentrations and power loads. The potentiostatic measurements were correlated with the composition of gases released at the anode determined by on-line mass spectroscopy. Both Pt and PtRu catalysts supported on carbon were used at the DMFC anode while cathode comprised pristine Pt on C in all cases. It is demonstrated experimentally that although the vapor-fed system is generally more complex and require an additional source of heat or utilization of the waste reaction heat, it shows its potential to be more efficient and tunable than conventional liquid-fed FCs as well as more resistant to poisoning, even in the absence of ruthenium in the anode catalyst. Energy efficiency of 30% and power density exceeding 70 mW cm−2 were achieved with Pt/C electrodes without any noticeable long-term degradation.

Suggested Citation

  • Johánek, Viktor & Ostroverkh, Anna & Fiala, Roman, 2019. "Vapor-feed low temperature direct methanol fuel cell with Pt and PtRu electrodes: Chemistry insight," Renewable Energy, Elsevier, vol. 138(C), pages 409-415.
    • Handle: RePEc:eee:renene:v:138:y:2019:i:c:p:409-415
    DOI: 10.1016/j.renene.2019.01.109
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148119301211
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2019.01.109?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Mallick, Ranjan K. & Thombre, Shashikant B. & Shrivastava, Naveen K., 2016. "Vapor feed direct methanol fuel cells (DMFCs): A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 56(C), pages 51-74.
    2. Sharaf, Omar Z. & Orhan, Mehmet F., 2014. "An overview of fuel cell technology: Fundamentals and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 32(C), pages 810-853.
    3. Yuan, Wei & Zhang, Zhaochun & Hu, Jinyi & Zhou, Bo & Tang, Yong, 2014. "Passive vapor-feed direct methanol fuel cell using sintered porous metals to realize high-concentration operation," Applied Energy, Elsevier, vol. 136(C), pages 143-149.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Fang, Yuan & Zhang, Tingting & Wang, Yonghui & Chen, Yuanzhen & Liu, Yan & Wu, Wenling & Zhu, Jianfeng, 2020. "The highly efficient cathode of framework structural Fe2O3/Mn2O3 in passive direct methanol fuel cells," Applied Energy, Elsevier, vol. 259(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Abdelkareem, Mohammad Ali & Allagui, Anis & Sayed, Enas Taha & El Haj Assad, M. & Said, Zafar & Elsaid, Khaled, 2019. "Comparative analysis of liquid versus vapor-feed passive direct methanol fuel cells," Renewable Energy, Elsevier, vol. 131(C), pages 563-584.
    2. Pan, Pengcheng & Sun, Yuwei & Yuan, Chengqing & Yan, Xinping & Tang, Xujing, 2021. "Research progress on ship power systems integrated with new energy sources: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 144(C).
    3. Sun, Zuo-Yu & Li, Guo-Xiu, 2015. "On reliability and flexibility of sustainable energy application route for vehicles in China," Renewable and Sustainable Energy Reviews, Elsevier, vol. 51(C), pages 830-846.
    4. Zhao, Chen & Li, Baozhu & Zhang, Lu & Han, Yaru & Wu, Xiaoyu, 2023. "Novel optimal structure design and testing of air-cooled open-cathode proton exchange membrane fuel cell," Renewable Energy, Elsevier, vol. 215(C).
    5. Das, Himadry Shekhar & Tan, Chee Wei & Yatim, A.H.M., 2017. "Fuel cell hybrid electric vehicles: A review on power conditioning units and topologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 76(C), pages 268-291.
    6. Peng, Fei & Zhao, Yuanzhe & Li, Xiaopeng & Liu, Zhixiang & Chen, Weirong & Liu, Yang & Zhou, Donghua, 2017. "Development of master-slave energy management strategy based on fuzzy logic hysteresis state machine and differential power processing compensation for a PEMFC-LIB-SC hybrid tramway," Applied Energy, Elsevier, vol. 206(C), pages 346-363.
    7. Jae Yun Jeong & Inje Kang & Ki Seok Choi & Byeong-Hee Lee, 2018. "Network Analysis on Green Technology in National Research and Development Projects in Korea," Sustainability, MDPI, vol. 10(4), pages 1-12, April.
    8. Liao, Shuxin & Qiu, Diankai & Yi, Peiyun & Peng, Linfa & Lai, Xinmin, 2022. "Modeling of a novel cathode flow field design with optimized sub-channels to improve drainage for proton exchange membrane fuel cells," Energy, Elsevier, vol. 261(PB).
    9. Liu, Guicheng & Li, Xinyang & Wang, Hui & Liu, Xiuying & Chen, Ming & Woo, Jae Young & Kim, Ji Young & Wang, Xindong & Lee, Joong Kee, 2017. "Design of 3-electrode system for in situ monitoring direct methanol fuel cells during long-time running test at high temperature," Applied Energy, Elsevier, vol. 197(C), pages 163-168.
    10. Lv, Xiuqing & Chen, Huili & Zhou, Wei & Li, Si-Dian & Cheng, Fangqin & Shao, Zongping, 2022. "SrCo0.4Fe0.4Zr0.1Y0.1O3-δ, A new CO2 tolerant cathode for proton-conducting solid oxide fuel cells," Renewable Energy, Elsevier, vol. 185(C), pages 8-16.
    11. Kinnon, Michael Mac & Razeghi, Ghazal & Samuelsen, Scott, 2021. "The role of fuel cells in port microgrids to support sustainable goods movement," Renewable and Sustainable Energy Reviews, Elsevier, vol. 147(C).
    12. Mehrpooya, Mehdi & Ansarinasab, Hojat & Mousavi, Seyed Ali, 2021. "Life cycle assessment and exergoeconomic analysis of the multi-generation system based on fuel cell for methanol, power, and heat production," Renewable Energy, Elsevier, vol. 172(C), pages 1314-1332.
    13. Lin, Jui-Yen & Shih, Yu-Jen & Chen, Po-Yen & Huang, Yao-Hui, 2016. "Precipitation recovery of boron from aqueous solution by chemical oxo-precipitation at room temperature," Applied Energy, Elsevier, vol. 164(C), pages 1052-1058.
    14. Wang, Chu & Li, Zhongliang & Outbib, Rachid & Dou, Manfeng & Zhao, Dongdong, 2022. "Symbolic deep learning based prognostics for dynamic operating proton exchange membrane fuel cells," Applied Energy, Elsevier, vol. 305(C).
    15. Wang, Aoyu & Yuan, Wei & Huang, Shimin & Tang, Yong & Chen, Yu, 2017. "Structural effects of expanded metal mesh used as a flow field for a passive direct methanol fuel cell," Applied Energy, Elsevier, vol. 208(C), pages 184-194.
    16. Wang, Junye, 2015. "Theory and practice of flow field designs for fuel cell scaling-up: A critical review," Applied Energy, Elsevier, vol. 157(C), pages 640-663.
    17. Xuexia Zhang & Zixuan Yu & Weirong Chen, 2019. "Life Prediction Based on D-S ELM for PEMFC," Energies, MDPI, vol. 12(19), pages 1-15, September.
    18. Bao, Zhiming & Niu, Zhiqiang & Jiao, Kui, 2020. "Gas distribution and droplet removal of metal foam flow field for proton exchange membrane fuel cells," Applied Energy, Elsevier, vol. 280(C).
    19. Jiang, Hongliang & Xu, Liangfei & Li, Jianqiu & Hu, Zunyan & Ouyang, Minggao, 2019. "Energy management and component sizing for a fuel cell/battery/supercapacitor hybrid powertrain based on two-dimensional optimization algorithms," Energy, Elsevier, vol. 177(C), pages 386-396.
    20. Wilberforce, Tabbi & El Hassan, Zaki & Ogungbemi, Emmanuel & Ijaodola, O. & Khatib, F.N. & Durrant, A. & Thompson, J. & Baroutaji, A. & Olabi, A.G., 2019. "A comprehensive study of the effect of bipolar plate (BP) geometry design on the performance of proton exchange membrane (PEM) fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 111(C), pages 236-260.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:138:y:2019:i:c:p:409-415. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.