IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v160y2020icp707-720.html
   My bibliography  Save this article

Pyrolysis of sewage sludge in a benchtop fluidized bed reactor: Characteristics of condensates and non-condensable gases

Author

Listed:
  • Liu, Yang
  • Ran, Chunmei
  • Siddiqui, Azka Rizwana
  • Chtaeva, Polina
  • Siyal, Asif Ali
  • Song, Yongmeng
  • Dai, Jianjun
  • Deng, Zeyu
  • Fu, Jie
  • Ao, Wenya
  • Jiang, Zhihui
  • Zhang, Tianhao

Abstract

This paper studied influences of temperature and additives on sewage sludge (SS) pyrolysis in a fluidized bed. The maximum condensate yield (17.07 wt%) was observed with Ca-bentonite at 650 °C. The yields of non-condensable gases rose significantly with addition of catalysts (e.g. kaolin). Fourier transform infra-red (FTIR) spectra indicated catalysts led to the appearance of some compounds (e.g. alkanes, ketones, amines) in the pyrolysis oil (PO). Gas chromatography mass spectrometry (GC-MS) revealed that PO mainly contained organo-oxygen species, nitrogen-containing heterocyclic compounds, hydrocarbons and antibiotics. With catalysts addition, the main components in the organo-oxygen species were phenols (1.59%–13.78%) and ketones (1.15%–5.12%). The highest CO2 and CO yields were obtained with kaolin addition, while the lowest CO2 yield was reached by CaO. Nitrogen (N) and chlorine (Cl) mainly existed in char and liquid phase, whereas sulfur (S) was dominated in char, indicating that the existence form of S was stable. CaO had certain N retention ability and S retention capability was up to 99.64%. Ca-bentonite and CaO reduced the release of Cl and all catalysts contributed to reduction of HCN emission.

Suggested Citation

  • Liu, Yang & Ran, Chunmei & Siddiqui, Azka Rizwana & Chtaeva, Polina & Siyal, Asif Ali & Song, Yongmeng & Dai, Jianjun & Deng, Zeyu & Fu, Jie & Ao, Wenya & Jiang, Zhihui & Zhang, Tianhao, 2020. "Pyrolysis of sewage sludge in a benchtop fluidized bed reactor: Characteristics of condensates and non-condensable gases," Renewable Energy, Elsevier, vol. 160(C), pages 707-720.
    • Handle: RePEc:eee:renene:v:160:y:2020:i:c:p:707-720
    DOI: 10.1016/j.renene.2020.06.137
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148120310594
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2020.06.137?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Fonts, Isabel & Gea, Gloria & Azuara, Manuel & Ábrego, Javier & Arauzo, Jesús, 2012. "Sewage sludge pyrolysis for liquid production: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 2781-2805.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Zhang, Yingwen & Zhou, Chunbao & Liu, Yang & Zhang, Tianhao & Li, Xiangtong & Wang, Long & Dai, Jianjun & Qu, Junshen & Zhang, Changfa & Yu, Mengyan & Yuan, Yanxin & Jin, Yajie & Yu, Hejie & Fu, Jie, 2022. "Product characteristics and potential energy recovery for microwave assisted pyrolysis of waste printed circuit boards in a continuously operated auger pyrolyser," Energy, Elsevier, vol. 239(PD).
    2. Chen, Minzi & Zhang, Shuping & Su, Yinhai & Niu, Xin & Zhu, Shuguang & Liu, Xinzhi, 2022. "Catalytic co-pyrolysis of food waste digestate and corn husk with CaO catalyst for upgrading bio-oil," Renewable Energy, Elsevier, vol. 186(C), pages 105-114.
    3. Jerzak, Wojciech & Wądrzyk, Mariusz & Kalemba-Rec, Izabela & Bieniek, Artur & Magdziarz, Aneta, 2023. "Release of chlorine during oat straw pyrolysis doped with char and ammonium chloride," Renewable Energy, Elsevier, vol. 215(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Mushtaq, Faisal & Mat, Ramli & Ani, Farid Nasir, 2014. "A review on microwave assisted pyrolysis of coal and biomass for fuel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 39(C), pages 555-574.
    2. Meng, Xiangmei & de Jong, Wiebren & Kudra, Tadeusz, 2016. "A state-of-the-art review of pulse combustion: Principles, modeling, applications and R&D issues," Renewable and Sustainable Energy Reviews, Elsevier, vol. 55(C), pages 73-114.
    3. Shahbeig, Hossein & Nosrati, Mohsen, 2020. "Pyrolysis of municipal sewage sludge for bioenergy production: Thermo-kinetic studies, evolved gas analysis, and techno-socio-economic assessment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    4. Salvilla, John Nikko V. & Ofrasio, Bjorn Ivan G. & Rollon, Analiza P. & Manegdeg, Ferdinand G. & Abarca, Ralf Ruffel M. & de Luna, Mark Daniel G., 2020. "Synergistic co-pyrolysıs of polyolefin plastics with wood and agricultural wastes for biofuel production," Applied Energy, Elsevier, vol. 279(C).
    5. Juan Félix González & Carmen María Álvez-Medina & Sergio Nogales-Delgado, 2023. "Biogas Steam Reforming in Wastewater Treatment Plants: Opportunities and Challenges," Energies, MDPI, vol. 16(17), pages 1-35, September.
    6. Farhad Beik & Leon Williams & Tim Brown & Stuart T. Wagland, 2021. "Managing Non-Sewered Human Waste Using Thermochemical Waste Treatment Technologies: A Review," Energies, MDPI, vol. 14(22), pages 1-22, November.
    7. Praspaliauskas, M. & Pedišius, N., 2017. "A review of sludge characteristics in Lithuania's wastewater treatment plants and perspectives of its usage in thermal processes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 899-907.
    8. Syed-Hassan, Syed Shatir A. & Wang, Yi & Hu, Song & Su, Sheng & Xiang, Jun, 2017. "Thermochemical processing of sewage sludge to energy and fuel: Fundamentals, challenges and considerations," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 888-913.
    9. Motasemi, F. & Afzal, Muhammad T., 2013. "A review on the microwave-assisted pyrolysis technique," Renewable and Sustainable Energy Reviews, Elsevier, vol. 28(C), pages 317-330.
    10. Liu, Huidong & Xu, Guoren & Li, Guibai, 2021. "Autocatalytic sludge pyrolysis by biochar derived from pharmaceutical sludge for biogas upgrading," Energy, Elsevier, vol. 229(C).
    11. Leng, Lijian & Li, Hui & Yuan, Xingzhong & Zhou, Wenguang & Huang, Huajun, 2018. "Bio-oil upgrading by emulsification/microemulsification: A review," Energy, Elsevier, vol. 161(C), pages 214-232.
    12. Zhang, Jifu & Cui, Peizhe & Yang, Sheng & Zhou, Yaru & Du, Wei & Wang, Yinglong & Deng, Chengwei & Wang, Shuai, 2023. "Thermodynamic analysis of SOFC–CCHP system based on municipal sludge plasma gasification with carbon capture," Applied Energy, Elsevier, vol. 336(C).
    13. Luo, Juan & Ma, Rui & Lin, Junhao & Sun, Shichang & Gong, Guojin & Sun, Jiaman & Chen, Yi & Ma, Ning, 2023. "Review of microwave pyrolysis of sludge to produce high quality biogas: Multi-perspectives process optimization and critical issues proposal," Renewable and Sustainable Energy Reviews, Elsevier, vol. 173(C).
    14. He, Chao & Chen, Chia-Lung & Giannis, Apostolos & Yang, Yanhui & Wang, Jing-Yuan, 2014. "Hydrothermal gasification of sewage sludge and model compounds for renewable hydrogen production: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 39(C), pages 1127-1142.
    15. Chakraborty, Sourabh & Dunford, Nurhan Turgut & Goad, Carla, 2021. "A kinetic study of microalgae, municipal sludge and cedar wood co-pyrolysis," Renewable Energy, Elsevier, vol. 165(P1), pages 514-524.
    16. Xu, Donghai & Lin, Guike & Liu, Liang & Wang, Yang & Jing, Zefeng & Wang, Shuzhong, 2018. "Comprehensive evaluation on product characteristics of fast hydrothermal liquefaction of sewage sludge at different temperatures," Energy, Elsevier, vol. 159(C), pages 686-695.
    17. Chen, Renjie & Yu, Xiaoqing & Dong, Bin & Dai, Xiaohu, 2020. "Sludge-to-energy approaches based on pathways that couple pyrolysis with anaerobic digestion (thermal hydrolysis pre/post-treatment): Energy efficiency assessment and pyrolysis kinetics analysis," Energy, Elsevier, vol. 190(C).
    18. Sharifzadeh, Mahdi & Wang, Lei & Shah, Nilay, 2015. "Integrated biorefineries: CO2 utilization for maximum biomass conversion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 47(C), pages 151-161.
    19. Zuo, Zongliang & Feng, Yan & Li, Xiaoteng & Luo, Siyi & Ma, Jinshuang & Sun, Huiping & Bi, Xuejun & Yu, Qingbo & Zhou, Enze & Zhang, Jingkui & Guo, Jianxiang & Lin, Huan, 2021. "Thermal-chemical conversion of sewage sludge based on waste heat cascade recovery of copper slag: Mass and energy analysis," Energy, Elsevier, vol. 235(C).
    20. Naqvi, Salman Raza & Tariq, Rumaisa & Hameed, Zeeshan & Ali, Imtiaz & Naqvi, Muhammad & Chen, Wei-Hsin & Ceylan, Selim & Rashid, Harith & Ahmad, Junaid & Taqvi, Syed A. & Shahbaz, Muhammad, 2019. "Pyrolysis of high ash sewage sludge: Kinetics and thermodynamic analysis using Coats-Redfern method," Renewable Energy, Elsevier, vol. 131(C), pages 854-860.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:160:y:2020:i:c:p:707-720. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.