IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v235y2021ics0360544221015127.html
   My bibliography  Save this article

Pyrolysis of waste activated sludge from food manufacturing industry: Thermal degradation, kinetics and thermodynamics analysis

Author

Listed:
  • Mong, Guo Ren
  • Chong, William Woei Fong
  • Nor, Siti Aminah Mohd
  • Ng, Jo-Han
  • Chong, Cheng Tung
  • Idris, Rubia
  • Too, Jingwei
  • Chiong, Meng Choung
  • Abas, Mohd Azman

Abstract

Rising environmental concern on industrial waste disposal drives the exploration of alternative managing methods. The route of waste-to-energy sparks interest as the uncontrollable amount of waste can be potentially transformed into energy-rich by-products. Waste activated sludge (WAS) from the food-manufacturing industry is a novel feedstock in pyrolysis and is investigated through a thermogravimetric analyser coupled with FTIR. During pyrolysis, a large composition of WAS is degraded within 190–550 °C, which is due to the breaking down of carbohydrates, protein and fats components. Phenols, alkanes, aromatics, acids, aldehydes, ketones and carbonyl are volatile chemicals, whereas light gases, such as CH4, CO and CO2, are produced. The kinetic analysis through model-free methods shows that the activation energy of WAS during pyrolysis increase with conversional level (Eα = 68.9–693.1 kJ mol-1 for α = 0.15–0.7). Polyacrylamide addition during wastewater treatment complicates the decomposition process, potentially imposing a higher Eα and consume more energy. The thermodynamic analysis of WAS demonstrated an endothermic and endergonic condition during pyrolysis where these are important information required for the designing of pyrolysis rig. From the large portion and valuable volatile composition with average activation energy, pyrolysis is found to be a feasible pathway for the management and transformation of WAS into bio-products.

Suggested Citation

  • Mong, Guo Ren & Chong, William Woei Fong & Nor, Siti Aminah Mohd & Ng, Jo-Han & Chong, Cheng Tung & Idris, Rubia & Too, Jingwei & Chiong, Meng Choung & Abas, Mohd Azman, 2021. "Pyrolysis of waste activated sludge from food manufacturing industry: Thermal degradation, kinetics and thermodynamics analysis," Energy, Elsevier, vol. 235(C).
    • Handle: RePEc:eee:energy:v:235:y:2021:i:c:s0360544221015127
    DOI: 10.1016/j.energy.2021.121264
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544221015127
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2021.121264?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Chen, Renjie & Yu, Xiaoqing & Dong, Bin & Dai, Xiaohu, 2020. "Sludge-to-energy approaches based on pathways that couple pyrolysis with anaerobic digestion (thermal hydrolysis pre/post-treatment): Energy efficiency assessment and pyrolysis kinetics analysis," Energy, Elsevier, vol. 190(C).
    2. Naqvi, Salman Raza & Tariq, Rumaisa & Hameed, Zeeshan & Ali, Imtiaz & Naqvi, Muhammad & Chen, Wei-Hsin & Ceylan, Selim & Rashid, Harith & Ahmad, Junaid & Taqvi, Syed A. & Shahbaz, Muhammad, 2019. "Pyrolysis of high ash sewage sludge: Kinetics and thermodynamic analysis using Coats-Redfern method," Renewable Energy, Elsevier, vol. 131(C), pages 854-860.
    3. Yurdakul, Sema, 2016. "Determination of co-combustion properties and thermal kinetics of poultry litter/coal blends using thermogravimetry," Renewable Energy, Elsevier, vol. 89(C), pages 215-223.
    4. Fonts, Isabel & Gea, Gloria & Azuara, Manuel & Ábrego, Javier & Arauzo, Jesús, 2012. "Sewage sludge pyrolysis for liquid production: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 2781-2805.
    5. Sobek, Szymon & Werle, Sebastian, 2020. "Solar pyrolysis of waste biomass: Part 2 kinetic modeling and methodology of the determination of the kinetic parameters for solar pyrolysis of sewage sludge," Renewable Energy, Elsevier, vol. 153(C), pages 962-974.
    6. Tang, Siqi & Zheng, Chunmiao & Yan, Feng & Shao, Ningning & Tang, Yuanyuan & Zhang, Zuotai, 2018. "Product characteristics and kinetics of sewage sludge pyrolysis driven by alkaline earth metals," Energy, Elsevier, vol. 153(C), pages 921-932.
    7. Lu, Yang & Wang, Ying & Zhang, Jing & Wang, Qi & Zhao, Yuqiong & Zhang, Yongfa, 2020. "Investigation on the characteristics of pyrolysates during co-pyrolysis of Zhundong coal and Changji oil shale and its kinetics," Energy, Elsevier, vol. 200(C).
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Chong, Cheng Tung & Fan, Yee Van & Lee, Chew Tin & Klemeš, Jiří Jaromír, 2022. "Post COVID-19 ENERGY sustainability and carbon emissions neutrality," Energy, Elsevier, vol. 241(C).
    2. Abdelrahman K. A. Khalil & Fikri Dweiri & Ismail W. Almanassra & Anjaneyulu Chatla & Muataz Ali Atieh, 2022. "Mg-Al Layered Double Hydroxide Doped Activated Carbon Composites for Phosphate Removal from Synthetic Water: Adsorption and Thermodynamics Studies," Sustainability, MDPI, vol. 14(12), pages 1-23, June.
    3. Jiang, Chunlong & Zhou, Wenliang & Bi, Haobo & Ni, Zhanshi & Sun, Hao & Lin, Qizhao, 2022. "Co-pyrolysis of coal slime and cattle manure by TG–FTIR–MS and artificial neural network modeling: Pyrolysis behavior, kinetics, gas emission characteristics," Energy, Elsevier, vol. 247(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Wang, Chengxin & Bi, Haobo & Lin, Qizhao & Jiang, Xuedan & Jiang, Chunlong, 2020. "Co-pyrolysis of sewage sludge and rice husk by TG–FTIR–MS: Pyrolysis behavior, kinetics, and condensable/non-condensable gases characteristics," Renewable Energy, Elsevier, vol. 160(C), pages 1048-1066.
    2. Liu, Huidong & Xu, Guoren & Li, Guibai, 2021. "Autocatalytic sludge pyrolysis by biochar derived from pharmaceutical sludge for biogas upgrading," Energy, Elsevier, vol. 229(C).
    3. Patel, Savankumar & Kundu, Sazal & Halder, Pobitra & Rickards, Lauren & Paz-Ferreiro, Jorge & Surapaneni, Aravind & Madapusi, Srinivasan & Shah, Kalpit, 2019. "Thermogravimetric Analysis of biosolids pyrolysis in the presence of mineral oxides," Renewable Energy, Elsevier, vol. 141(C), pages 707-716.
    4. Sobek, Szymon & Werle, Sebastian, 2020. "Isoconversional determination of the apparent reaction models governing pyrolysis of wood, straw and sewage sludge, with an approach to rate modelling," Renewable Energy, Elsevier, vol. 161(C), pages 972-987.
    5. Liu, Yang & Ran, Chunmei & Siddiqui, Azka R. & Siyal, Asif Ali & Song, Yongmeng & Dai, Jianjun & Chtaeva, Polina & Fu, Jie & Ao, Wenya & Deng, Zeyu & Jiang, Zhihui & Zhang, Tianhao, 2020. "Characterization and analysis of sludge char prepared from bench-scale fluidized bed pyrolysis of sewage sludge," Energy, Elsevier, vol. 200(C).
    6. Zheng, Anqing & Li, Luwei & Tippayawong, Nakorn & Huang, Zhen & Zhao, Kun & Wei, Guoqiang & Zhao, Zengli & Li, Haibin, 2020. "Reducing emission of NOx and SOx precursors while enhancing char production from pyrolysis of sewage sludge by torrefaction pretreatment," Energy, Elsevier, vol. 192(C).
    7. Gürel, Barış & Kurtuluş, Karani & Yurdakul, Sema & Karaca Dolgun, Gülşah & Akman, Remzi & Önür, Muhammet Enes & Varol, Murat & Keçebaş, Ali & Gürbüz, Habib, 2024. "Combustion of chicken manure and Turkish lignite mixtures in a circulating fluidized bed," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PA).
    8. Kaczor, Zuzanna & Buliński, Zbigniew & Werle, Sebastian, 2020. "Modelling approaches to waste biomass pyrolysis: a review," Renewable Energy, Elsevier, vol. 159(C), pages 427-443.
    9. Mushtaq, Faisal & Mat, Ramli & Ani, Farid Nasir, 2014. "A review on microwave assisted pyrolysis of coal and biomass for fuel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 39(C), pages 555-574.
    10. Marzena Smol, 2020. "Inventory of Wastes Generated in Polish Sewage Sludge Incineration Plants and Their Possible Circular Management Directions," Resources, MDPI, vol. 9(8), pages 1-24, July.
    11. Meng, Xiangmei & de Jong, Wiebren & Kudra, Tadeusz, 2016. "A state-of-the-art review of pulse combustion: Principles, modeling, applications and R&D issues," Renewable and Sustainable Energy Reviews, Elsevier, vol. 55(C), pages 73-114.
    12. Shahbeig, Hossein & Nosrati, Mohsen, 2020. "Pyrolysis of municipal sewage sludge for bioenergy production: Thermo-kinetic studies, evolved gas analysis, and techno-socio-economic assessment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    13. Alam, Mahboob & Bhavanam, Anjireddy & Jana, Ashirbad & Viroja, Jaimin kumar S. & Peela, Nageswara Rao, 2020. "Co-pyrolysis of bamboo sawdust and plastic: Synergistic effects and kinetics," Renewable Energy, Elsevier, vol. 149(C), pages 1133-1145.
    14. Nawaz, Ahmad & Kumar, Pradeep, 2022. "Elucidating the bioenergy potential of raw, hydrothermally carbonized and torrefied waste Arundo donax biomass in terms of physicochemical characterization, kinetic and thermodynamic parameters," Renewable Energy, Elsevier, vol. 187(C), pages 844-856.
    15. Salvilla, John Nikko V. & Ofrasio, Bjorn Ivan G. & Rollon, Analiza P. & Manegdeg, Ferdinand G. & Abarca, Ralf Ruffel M. & de Luna, Mark Daniel G., 2020. "Synergistic co-pyrolysıs of polyolefin plastics with wood and agricultural wastes for biofuel production," Applied Energy, Elsevier, vol. 279(C).
    16. Zhang, He, 2024. "Study on microscale stress sensitivity of CO2 foam fracturing in tight reservoirs," Energy, Elsevier, vol. 294(C).
    17. Liu, Xiaoguang & Wang, Qian & Tang, Yuanzhi & Pavlostathis, Spyros G., 2021. "A comparative study on biogas production, energy balance, and nutrients conversion with inter-stage hydrothermal treatment of sewage sludge," Applied Energy, Elsevier, vol. 288(C).
    18. Juan Félix González & Carmen María Álvez-Medina & Sergio Nogales-Delgado, 2023. "Biogas Steam Reforming in Wastewater Treatment Plants: Opportunities and Challenges," Energies, MDPI, vol. 16(17), pages 1-35, September.
    19. Duan, Zhonghui & Zhang, Yongmin & Yang, Fu & Liu, Meijuan & Wang, Zhendong & Zhao, Youzhi & Ma, Li, 2024. "Research on controllable shock wave technology for in-situ development of tar-rich coal," Energy, Elsevier, vol. 288(C).
    20. Li, Jiawei & Fan, Subo & Zhang, Xuyang & Chen, Zhichao & Qiao, Yanyu & Yuan, Zhenhua & Zeng, Lingyan & Li, Zhengqi, 2022. "Physicochemical structure, combustion characteristics and SiO2 properties of entrained flow gasification ash," Energy, Elsevier, vol. 251(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:235:y:2021:i:c:s0360544221015127. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.