IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v153y2020icp998-1004.html
   My bibliography  Save this article

Unveiling one-pot scalable fabrication of reusable carboxylated heterogeneous carbon-based catalysts from eucalyptus plant with the assistance of dry ice for selective hydrolysis of eucalyptus biomass

Author

Listed:
  • Abdu, Hassan Idris
  • Eid, Kamel
  • Abdullah, Aboubakr M.
  • Han, Zhengang
  • Ibrahim, Mohammed Hassan
  • Shan, Duoliang
  • Chen, Jing
  • Elzatahry, Ahmed A.
  • Lu, Xiaoquan

Abstract

Biomass is the most abundant source for organic carbon-based substances on the earth; however, its utilization as sources for heterogeneous catalysts for biorefineries is rarely reported. Herein, a simple approach was developed for tailoring one-pot fabrication of carboxylate heterogeneous catalysts from woody biomass eucalyptus denoted as (ECS) via the ball-milling in the presence of dry ice as an oxidant followed by protonation. The ECS catalyst was obtained in a high yield of (100%) without any waste, organic solvents, and multistep reactions. The resultant ECS is composed of an aromatic skeleton enriched with a carboxylic group (COOH) of (2.4 mmol g−1) as well as some aliphatic moieties (CH0.44O0.42). The COOH content in the ECS was a function of the ball-milling time. The newly designed ECS catalyst allowed the successful hydrolysis of eucalyptus biomass to xylose (95.1%) and glucose (81%) at 180 °C within only 17 min in the presence of 120 ppm of HCl. Intriguingly, the obtained solid residuals of both catalysts and unhydrolyzed eucalyptus could be milled again to form a fresh ECS catalyst. The presented approach opens new avenues for the fabrication of scalable heterogeneous-carbon catalysts for biorefineries applications.

Suggested Citation

  • Abdu, Hassan Idris & Eid, Kamel & Abdullah, Aboubakr M. & Han, Zhengang & Ibrahim, Mohammed Hassan & Shan, Duoliang & Chen, Jing & Elzatahry, Ahmed A. & Lu, Xiaoquan, 2020. "Unveiling one-pot scalable fabrication of reusable carboxylated heterogeneous carbon-based catalysts from eucalyptus plant with the assistance of dry ice for selective hydrolysis of eucalyptus biomass," Renewable Energy, Elsevier, vol. 153(C), pages 998-1004.
    • Handle: RePEc:eee:renene:v:153:y:2020:i:c:p:998-1004
    DOI: 10.1016/j.renene.2020.02.034
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148120302202
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2020.02.034?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Gibbins, Jon & Chalmers, Hannah, 2008. "Carbon capture and storage," Energy Policy, Elsevier, vol. 36(12), pages 4317-4322, December.
    2. Masakazu Toda & Atsushi Takagaki & Mai Okamura & Junko N. Kondo & Shigenobu Hayashi & Kazunari Domen & Michikazu Hara, 2005. "Biodiesel made with sugar catalyst," Nature, Nature, vol. 438(7065), pages 178-178, November.
    3. Rode, Rafael & Leite, Helio Garcia & Silva, Márcio Lopes da & Ribeiro, Carlos Antonio Álvares Soares & Binoti, Daniel Henrique Breda, 2014. "The economics and optimal management regimes of eucalyptus plantations: A case study of forestry outgrower schemes in Brazil," Forest Policy and Economics, Elsevier, vol. 44(C), pages 26-33.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Setiawan, Andri D. & Cuppen, Eefje, 2013. "Stakeholder perspectives on carbon capture and storage in Indonesia," Energy Policy, Elsevier, vol. 61(C), pages 1188-1199.
    2. Barelli, L. & Ottaviano, A., 2014. "Solid oxide fuel cell technology coupled with methane dry reforming: A viable option for high efficiency plant with reduced CO2 emissions," Energy, Elsevier, vol. 71(C), pages 118-129.
    3. Christian Leßmann & Arne Steinkraus, 2016. "Kurz zum Klima: »Carbon Capture and Storage« – was kostet die Emissionsvermeidung?," ifo Schnelldienst, ifo Institute - Leibniz Institute for Economic Research at the University of Munich, vol. 69(05), pages 51-54, March.
    4. Giwa, Adewale & Alabi, Adetunji & Yusuf, Ahmed & Olukan, Tuza, 2017. "A comprehensive review on biomass and solar energy for sustainable energy generation in Nigeria," Renewable and Sustainable Energy Reviews, Elsevier, vol. 69(C), pages 620-641.
    5. Aydin, Gokhan & Karakurt, Izzet & Aydiner, Kerim, 2010. "Evaluation of geologic storage options of CO2: Applicability, cost, storage capacity and safety," Energy Policy, Elsevier, vol. 38(9), pages 5072-5080, September.
    6. Stewart Russell & Nils Markusson & Vivian Scott, 2012. "What will CCS demonstrations demonstrate?," Mitigation and Adaptation Strategies for Global Change, Springer, vol. 17(6), pages 651-668, August.
    7. Shu, Qing & Tang, Guoqiang & Lesmana, Herry & Zou, Laixi & Xiong, Daolin, 2018. "Preparation, characterization and application of a novel solid Brönsted acid catalyst SO42−/La3+/C for biodiesel production via esterification of oleic acid and methanol," Renewable Energy, Elsevier, vol. 119(C), pages 253-261.
    8. Ezebor, Francis & Khairuddean, Melati & Abdullah, Ahmad Zuhairi & Boey, Peng Lim, 2014. "Oil palm trunk and sugarcane bagasse derived heterogeneous acid catalysts for production of fatty acid methyl esters," Energy, Elsevier, vol. 70(C), pages 493-503.
    9. Lin, Chih-Wei & Nazeri, Mahmoud & Bhattacharji, Ayan & Spicer, George & Maroto-Valer, M. Mercedes, 2016. "Apparatus and method for calibrating a Coriolis mass flow meter for carbon dioxide at pressure and temperature conditions represented to CCS pipeline operations," Applied Energy, Elsevier, vol. 165(C), pages 759-764.
    10. Cavalcanti, Eduardo J.C. & Lima, Matheus S.R. & de Souza, Gabriel F., 2020. "Comparison of carbon capture system and concentrated solar power in natural gas combined cycle: Exergetic and exergoenvironmental analyses," Renewable Energy, Elsevier, vol. 156(C), pages 1336-1347.
    11. Kemp, Alexander G. & Sola Kasim, A., 2010. "A futuristic least-cost optimisation model of CO2 transportation and storage in the UK/UK Continental Shelf," Energy Policy, Elsevier, vol. 38(7), pages 3652-3667, July.
    12. Maitri Verma & Alok Kumar Verma & A. K. Misra, 2021. "Mathematical modeling and optimal control of carbon dioxide emissions from energy sector," Environment, Development and Sustainability: A Multidisciplinary Approach to the Theory and Practice of Sustainable Development, Springer, vol. 23(9), pages 13919-13944, September.
    13. Konwar, Lakhya Jyoti & Boro, Jutika & Deka, Dhanapati, 2014. "Review on latest developments in biodiesel production using carbon-based catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 546-564.
    14. Afonso, Roberta & Miller, Daniel C., 2021. "Forest plantations and local economic development: Evidence from Minas Gerais, Brazil," Forest Policy and Economics, Elsevier, vol. 133(C).
    15. Saman Hasan & Abubakar Jibrin Abbas & Ghasem Ghavami Nasr, 2020. "Improving the Carbon Capture Efficiency for Gas Power Plants through Amine-Based Absorbents," Sustainability, MDPI, vol. 13(1), pages 1-27, December.
    16. Bora, Akash Pratim & Dhawane, Sumit H. & Anupam, Kumar & Halder, Gopinath, 2018. "Biodiesel synthesis from Mesua ferrea oil using waste shell derived carbon catalyst," Renewable Energy, Elsevier, vol. 121(C), pages 195-204.
    17. Widuramina Sameendranath Amarasinghe & Ingebret Fjelde & Anna Maija Nørstebø Flaata, 2021. "Visual investigation of CO2 dissolution and convection in heterogeneous porous media at reservoir temperature and pressure conditions," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 11(2), pages 342-359, April.
    18. Iyer, Gokul & Hultman, Nathan & Eom, Jiyong & McJeon, Haewon & Patel, Pralit & Clarke, Leon, 2015. "Diffusion of low-carbon technologies and the feasibility of long-term climate targets," Technological Forecasting and Social Change, Elsevier, vol. 90(PA), pages 103-118.
    19. Marshall, Jonathan Paul, 2016. "Disordering fantasies of coal and technology: Carbon capture and storage in Australia," Energy Policy, Elsevier, vol. 99(C), pages 288-298.
    20. Yang Teng & Lijiao Li & Gang Xu & Kai Zhang & Kaixi Li, 2016. "Promoting Effect of Inorganic Alkali on Carbon Dioxide Adsorption in Amine-Modified MCM-41," Energies, MDPI, vol. 9(9), pages 1-11, August.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:153:y:2020:i:c:p:998-1004. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.