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Multiproduct biorefinery from vine shoots: Bio-ethanol and lignin production

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  • Dávila, Izaskun
  • Gullón, Beatriz
  • Labidi, Jalel
  • Gullón, Patricia

Abstract

Vine shoots were hydrothermally processed and the effect of the different assayed severities on the subsequent enzymatic saccharification of the remaining solids was evaluated. The solid obtained at a severity of 4.47 showed the highest yield on glucose (74.01%) and therefore, it was used as the substrate for the obtaining of bio-ethanol through a SSF process. Under the evaluated conditions (LSR 10 g/g, 20 FPU/g and 10 IU/FPU) 13.3 g/L of bio-ethanol were produced (corresponding to 67.4% of ethanol conversion). Moreover, lignin has been extracted by an alkali delignification treatment from the vine shoots unprocessing and from the solids resulting from the stages of the proposed biorefinery scheme, which were the autohydrolysed vine shoots and the bio-ethanol residue. The isolated lignins were characterized by HPLC, total phenolic content, FTIR, HPSEC, Py-GC/MS and TGA and it was observed that the successive stages of processing to which the vine shoots were submitted provoked chemical and structural changes in the extracted lignins. The knowledge of the structural modifications that the lignin present in the vine shoots during the autohydrolysis and the SSF process could help determining at which stage of the bio-ethanol production would be suitable to recover the lignin for value-added applications.

Suggested Citation

  • Dávila, Izaskun & Gullón, Beatriz & Labidi, Jalel & Gullón, Patricia, 2019. "Multiproduct biorefinery from vine shoots: Bio-ethanol and lignin production," Renewable Energy, Elsevier, vol. 142(C), pages 612-623.
    • Handle: RePEc:eee:renene:v:142:y:2019:i:c:p:612-623
    DOI: 10.1016/j.renene.2019.04.131
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    References listed on IDEAS

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    1. Sarkar, Nibedita & Ghosh, Sumanta Kumar & Bannerjee, Satarupa & Aikat, Kaustav, 2012. "Bioethanol production from agricultural wastes: An overview," Renewable Energy, Elsevier, vol. 37(1), pages 19-27.
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    4. Domínguez, Elena & Romaní, Aloia & Domingues, Lucília & Garrote, Gil, 2017. "Evaluation of strategies for second generation bioethanol production from fast growing biomass Paulownia within a biorefinery scheme," Applied Energy, Elsevier, vol. 187(C), pages 777-789.
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    1. Dominik Anđelini & Danko Cvitan & Melissa Prelac & Igor Pasković & Marko Černe & Ivan Nemet & Nikola Major & Smiljana Goreta Ban & Zoran Užila & Tea Zubin Ferri & Branka Njegić Džakula & Marko Petek &, 2023. "Biochar from Grapevine-Pruning Residues Is Affected by Grapevine Rootstock and Pyrolysis Temperature," Sustainability, MDPI, vol. 15(6), pages 1-17, March.
    2. Hashemi, Seyed Sajad & Mirmohamadsadeghi, Safoora & Karimi, Keikhosro, 2020. "Biorefinery development based on whole safflower plant," Renewable Energy, Elsevier, vol. 152(C), pages 399-408.
    3. Sebastián Serna-Loaiza & Angela Miltner & Martin Miltner & Anton Friedl, 2019. "A Review on the Feedstocks for the Sustainable Production of Bioactive Compounds in Biorefineries," Sustainability, MDPI, vol. 11(23), pages 1-24, November.
    4. Garita-Cambronero, Jerson & Paniagua-García, Ana I. & Hijosa-Valsero, María & Díez-Antolínez, Rebeca, 2021. "Biobutanol production from pruned vine shoots," Renewable Energy, Elsevier, vol. 177(C), pages 124-133.
    5. Radhakrishnan, Rokesh & Manna, Bharat & Ghosh, Amit, 2023. "Molecular insights into dissolution of lignin bunch in ionic liquid-water mixture for enhanced biomass conversion," Renewable Energy, Elsevier, vol. 206(C), pages 47-59.

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