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A novel structured PdZnAl/Cu fiber catalyst for methanol steam reforming in microreactor

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  • Tian, Jinshu
  • Ke, Yuzhi
  • Kong, Guoguo
  • Tan, Mingwu
  • Wang, Yong
  • Lin, Jingdong
  • Zhou, Wei
  • Wan, Shaolong

Abstract

Structured PdZnAl/Cu fiber catalyst prepared by a PVA(Polyvinyl Alcohol)-assisted coating method, was integrated in the micro-reactor for methanol steam reforming (MSR), which could be used to efficiently produce hydrogen in situ for a coupled fuel cell. XRD, SEM-EDX and HRTEM etc. were employed to characterize both the fresh and spent powder and structured catalysts. A variety of reaction conditions were tested to achieve the optimized reaction condition, where the H2 productivity and the product distribution especially CO selectivity were carefully examined. Compared to the structured CuZnAlZr/Cu fiber catalyst, the PdZnAl/Cu counterpart exhibits superior stability in MSR process, and its spent catalyst could be readily regenerated just by oxidation in air at 420 °C for 4 h.

Suggested Citation

  • Tian, Jinshu & Ke, Yuzhi & Kong, Guoguo & Tan, Mingwu & Wang, Yong & Lin, Jingdong & Zhou, Wei & Wan, Shaolong, 2017. "A novel structured PdZnAl/Cu fiber catalyst for methanol steam reforming in microreactor," Renewable Energy, Elsevier, vol. 113(C), pages 30-42.
    • Handle: RePEc:eee:renene:v:113:y:2017:i:c:p:30-42
    DOI: 10.1016/j.renene.2017.04.070
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    References listed on IDEAS

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    1. Wu, Horng-Wen, 2016. "A review of recent development: Transport and performance modeling of PEM fuel cells," Applied Energy, Elsevier, vol. 165(C), pages 81-106.
    2. Pan, Minqiang & Wu, Qiuyu & Jiang, Lianbo & Zeng, Dehuai, 2015. "Effect of microchannel structure on the reaction performance of methanol steam reforming," Applied Energy, Elsevier, vol. 154(C), pages 416-427.
    3. Li, Yanxia & Luo, Chaoming & Liu, Zhongliang & Sang, Lixia, 2015. "Catalytic oxidation characteristics of CH4–air mixtures over metal foam monoliths," Applied Energy, Elsevier, vol. 156(C), pages 756-761.
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    Cited by:

    1. Fajín, José L.C. & Cordeiro, M. Natália D.S., 2024. "Renewable hydrogen production from biomass derivatives or water on trimetallic based catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PA).
    2. Liu, Yangxu & Zhou, Wei & Lin, Yu & Chen, Lu & Chu, Xuyang & Zheng, Tianqing & Wan, Shaolong & Lin, Jingdong, 2019. "Novel copper foam with ordered hole arrays as catalyst support for methanol steam reforming microreactor," Applied Energy, Elsevier, vol. 246(C), pages 24-37.
    3. Tang, Xincheng & Wu, Yanxiao & Fang, Zhenchang & Dong, Xinyu & Du, Zhongxuan & Deng, Bicai & Sun, Chunhua & Zhou, Feng & Qiao, Xinqi & Li, Xinling, 2024. "Syntheses, catalytic performances and DFT investigations: A recent review of copper-based catalysts of methanol steam reforming for hydrogen production," Energy, Elsevier, vol. 295(C).

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