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PVT properties of sulfur-hexafluoride in the gas-liquid critical region

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  • Biswas, S.N.
  • Trappeniers, N.J.
  • Hoogland, J.H.B.

Abstract

The PVT properties of sulfur hexafluoride in the critical region have been measured by using a combination of the Burnett and the isochoric methods. The measurement of one reference PV-isotherm at about 333 K was performed by the Burnett method of repeated expansions; the measurement of a large number of PT quasi-isochores between 313 and 333 K relied on the so-called isochoric method. An important feature of the data analysis is the application of several consistency criteria to the least-squares analysis for polynomial representation which made it possible to determine reliable values of the Burnett constants and the virial coefficients. The reference isotherm with 105 data points covers a pressure range between 1 and 100 bar and a density range up to 1.2 g cm−3. The 21 isochoric runs with densities between 0.1 and 1.2 g cm−3 contain 220 data points. Except for the region very close to the critical point, the accuracy of the measurements is estimated to be better than 0.01% in the pressure, 0.02% in the density and 1 mK in the temperature.

Suggested Citation

  • Biswas, S.N. & Trappeniers, N.J. & Hoogland, J.H.B., 1984. "PVT properties of sulfur-hexafluoride in the gas-liquid critical region," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 126(3), pages 384-415.
    • Handle: RePEc:eee:phsmap:v:126:y:1984:i:3:p:384-415
    DOI: 10.1016/0378-4371(84)90208-5
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    References listed on IDEAS

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    1. Henry S. Schneider, 1951. "Two Formula Methods For Choosing Common Stocks," Journal of Finance, American Finance Association, vol. 6(2), pages 229-237, June.
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    1. Hoogland, J.H.B. & Van Den Berg, H.R. & Trappeniers, N.J., 1985. "Measurements of the viscosity of sulfur hexaflouride up to 100 bar by a capillary-flow viscometer," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 134(1), pages 169-192.

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