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Mitigating crystallization of saturated FAMES (fatty acid methyl esters) in biodiesel: 4. The phase behavior of 1,3-dioleoyl-2-palmitoyl glycerol – Methyl stearate binary system

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  • Mohanan, Athira
  • Bouzidi, Laziz
  • Narine, Suresh S.

Abstract

The present study examines the phase behavior of a model binary system made of OPO (1,3-dioleoyl-2-palmitoyl glycerol); a TAG (triacylglycerol) highly effective in depressing onset of crystallization of biodiesel, and MeS (methyl stearate); a prevalent saturated FAMEs (fatty acid methyl esters) in biodiesel. The thermal behavior, crystal structure and microstructure of the OPO/MeS mixtures were investigated with DSC (differential scanning calorimetry), XRD (X-ray diffraction) and PLM (polarized light microscope). The OPO/MeS system presented a phase diagram with peritectic and eutectic transitions. A simple thermodynamic modeling of the liquidus line indicated a relatively complex mixing behavior, and highlighted the prevailing effect of the peritectic compound on solubility. Different types of microstructures that were more or less influenced by MeS, OPO or/and compound microstructures were observed in the mixtures. They are associated with the crystal phases and the thermal transitions. Furthermore, MeS, OPO and compound crystal structures (monoclinic, orthorhombic and triclinic, respectively) served as templates for the crystal forms of the coexisting phases. The singularities in the liquidus line are attributed to chain length mismatch between the palmitic acid and the FAME (fatty acid methyl ester). The phase diagram achieved for OPO/MeS system is complete and can help in designing additive formulations to improve the cold flow behavior of biodiesel.

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  • Mohanan, Athira & Bouzidi, Laziz & Narine, Suresh S., 2016. "Mitigating crystallization of saturated FAMES (fatty acid methyl esters) in biodiesel: 4. The phase behavior of 1,3-dioleoyl-2-palmitoyl glycerol – Methyl stearate binary system," Energy, Elsevier, vol. 96(C), pages 242-252.
    • Handle: RePEc:eee:energy:v:96:y:2016:i:c:p:242-252
    DOI: 10.1016/j.energy.2015.11.080
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    References listed on IDEAS

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    1. Misra, R.D. & Murthy, M.S., 2011. "Blending of additives with biodiesels to improve the cold flow properties, combustion and emission performance in a compression ignition engine--A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(5), pages 2413-2422, June.
    2. Fazal, M.A. & Haseeb, A.S.M.A. & Masjuki, H.H., 2011. "Biodiesel feasibility study: An evaluation of material compatibility; performance; emission and engine durability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(2), pages 1314-1324, February.
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    1. Mohanan, Athira & Bouzidi, Laziz & Narine, Suresh S., 2017. "Harnessing the synergies between lipid-based crystallization modifiers and a polymer pour point depressant to improve pour point of biodiesel," Energy, Elsevier, vol. 120(C), pages 895-906.
    2. Mohanan, Athira & Bouzidi, Laziz & Narine, Suresh S., 2016. "Mitigating crystallization of saturated FAMEs in biodiesel 6: The binary phase behavior of 1, 2-dioleoyl-3-stearoyl sn-glycerol – Methyl stearate," Energy, Elsevier, vol. 100(C), pages 273-284.

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