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Evaluation of Low-GWP fluids for power generation with Organic Rankine Cycle

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  • Luo, Dong
  • Mahmoud, Ahmad
  • Cogswell, Frederick

Abstract

A systematic approach has been developed for fast evaluation of large sets of fluids and mixtures for power generation using ORC (Organic Rankine Cycle) to identify the best refrigerants with low GWP (global warming potentials). A model has been created to calculate performance of a basic cycle for pure fluids as well as mixtures based on heat balance and pinch point analysis using the property package of RefProp 9.0. Processes in both heat exchangers and turbine are discretized to compute key design and operating parameters. With any given resource temperature, cycle performance are optimized on both heating and cooling sides of the cycle for maximum power generation or maximum efficiency. Case studies have been performed for analysis of fluids pre-screened with EHS (environment, health and safety) criteria, including toxicity, ODP (ozone depletion potential) and GWP. Major design and operating constraints have been evaluated through simulation and applied for fluid selection, such as dry expansion in turbine. Candidate pure fluids and binary mixtures with low GWP and high performance have been identified at different resource temperatures for further detailed design evaluation. This approach has been demonstrated for efficient evaluation of large sets of pure fluids and mixtures for any given resource temperature.

Suggested Citation

  • Luo, Dong & Mahmoud, Ahmad & Cogswell, Frederick, 2015. "Evaluation of Low-GWP fluids for power generation with Organic Rankine Cycle," Energy, Elsevier, vol. 85(C), pages 481-488.
    • Handle: RePEc:eee:energy:v:85:y:2015:i:c:p:481-488
    DOI: 10.1016/j.energy.2015.03.109
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    6. Juan J. García-Pabón & Dario Méndez-Méndez & Juan M. Belman-Flores & Juan M. Barroso-Maldonado & Ali Khosravi, 2021. "A Review of Recent Research on the Use of R1234yf as an Environmentally Friendly Fluid in the Organic Rankine Cycle," Sustainability, MDPI, vol. 13(11), pages 1-21, May.
    7. Yang, Jingye & Ye, Zhenhong & Yu, Binbin & Ouyang, Hongsheng & Chen, Jiangping, 2019. "Simultaneous experimental comparison of low-GWP refrigerants as drop-in replacements to R245fa for Organic Rankine cycle application: R1234ze(Z), R1233zd(E), and R1336mzz(E)," Energy, Elsevier, vol. 173(C), pages 721-731.
    8. Frutiger, Jérôme & Andreasen, Jesper & Liu, Wei & Spliethoff, Hartmut & Haglind, Fredrik & Abildskov, Jens & Sin, Gürkan, 2016. "Working fluid selection for organic Rankine cycles – Impact of uncertainty of fluid properties," Energy, Elsevier, vol. 109(C), pages 987-997.
    9. Liu, Wei & Meinel, Dominik & Gleinser, Moritz & Wieland, Christoph & Spliethoff, Hartmut, 2015. "Optimal Heat Source Temperature for thermodynamic optimization of sub-critical Organic Rankine Cycles," Energy, Elsevier, vol. 88(C), pages 897-906.
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    11. Bartosz Gil & Jacek Kasperski, 2018. "Efficiency Evaluation of the Ejector Cooling Cycle using a New Generation of HFO/HCFO Refrigerant as a R134a Replacement," Energies, MDPI, vol. 11(8), pages 1-17, August.
    12. Györke, Gábor & Deiters, Ulrich K. & Groniewsky, Axel & Lassu, Imre & Imre, Attila R., 2018. "Novel classification of pure working fluids for Organic Rankine Cycle," Energy, Elsevier, vol. 145(C), pages 288-300.
    13. Xu, Weicong & Zhao, Ruikai & Deng, Shuai & Zhao, Li & Mao, Samuel S., 2021. "Is zeotropic working fluid a promising option for organic Rankine cycle: A quantitative evaluation based on literature data," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    14. Zhai, Rui & Yang, Zhao & Chen, Yubo & Feng, Biao & Lv, Zijian & Zhao, Wenzhong, 2019. "Theoretical and experimental studies on the combustion mechanism of Trans-1, 3, 3, 3-tetrafluoroprop-1-ene," Energy, Elsevier, vol. 189(C).
    15. González, Johan & Llovell, Fèlix & Garrido, José Matías & Quinteros-Lama, Héctor, 2022. "A rigorous approach for characterising the limiting optimal efficiency of working fluids in organic Rankine cycles," Energy, Elsevier, vol. 254(PA).

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