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High performance FeTi – 3.1 mass % V alloy for on board hydrogen storage solution

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  • Kumar, Sanjay
  • Tiwari, G.P.
  • Sonak, Sagar
  • Jain, Uttam
  • Krishnamurthy, Nagaiyar

Abstract

Single phase FeTi intermetallic and FeTi-3.1 mass % V alloy were synthesized by vacuum arc melting using high purity elemental constituents. The crystal structure of both, FeTi intermetallic and FeTi-3.1 mass % V alloy was found to be of CsCl-type. Under similar annealing conditions, crystallite size of FeTi-3.1 mass % V alloy was markedly smaller than that of FeTi intermetallic. Hydrogen absorption in FeTi intermetallic and FeTi-3.1 mass % V alloy was studied in a thermobalance attached to a Sieverts apparatus at a temperature of 327 K under 0.2 MPa hydrogen pressure. The hydrogen absorption in vanadium alloyed FeTi matrix was significantly faster than in the pure intermetallic. The maximum amount of hydrogen absorbed in the FeTi intermetallic and FeTi-3.1 mass % V alloy was of 1.2 and 1.1 mass % respectively.

Suggested Citation

  • Kumar, Sanjay & Tiwari, G.P. & Sonak, Sagar & Jain, Uttam & Krishnamurthy, Nagaiyar, 2014. "High performance FeTi – 3.1 mass % V alloy for on board hydrogen storage solution," Energy, Elsevier, vol. 75(C), pages 520-524.
    • Handle: RePEc:eee:energy:v:75:y:2014:i:c:p:520-524
    DOI: 10.1016/j.energy.2014.08.011
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    References listed on IDEAS

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    1. Rovira, Antonio & Rubbia, Carlo & Valdés, Manuel & Martínez-Val, José M., 2014. "Thermodynamic cycles optimised for medium enthalpy units of concentrating solar power," Energy, Elsevier, vol. 67(C), pages 176-185.
    2. Zhou, Li, 2005. "Progress and problems in hydrogen storage methods," Renewable and Sustainable Energy Reviews, Elsevier, vol. 9(4), pages 395-408, August.
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    2. Chen, X.Y. & Chen, R.R. & Ding, X. & Fang, H.Z. & Li, X.Z. & Ding, H.S. & Su, Y.Q. & Guo, J.J. & Fu, H.Z., 2019. "Effect of phase formation on hydrogen storage properties in Ti-V-Mn alloys by zirconium substitution," Energy, Elsevier, vol. 166(C), pages 587-597.
    3. Kou, Huaqin & Luo, Wenhua & Huang, Zhiyong & Sang, Ge & Meng, Daqiao & Zhang, Guanghui & Chen, Changan & Luo, Deli & Hu, Changwen, 2015. "Fabrication and experimental validation of a full-scale depleted uranium bed with thin double-layered annulus configuration for hydrogen isotopes recovery and delivery," Energy, Elsevier, vol. 90(P1), pages 588-594.
    4. Liu, Jingjing & Cheng, Honghui & Han, Shumin & Liu, Hongfei & Huot, Jacques, 2020. "Hydrogen storage properties and cycling degradation of single-phase La0.60R0.15Mg0·25Ni3.45 alloys with A2B7-type superlattice structure," Energy, Elsevier, vol. 192(C).

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