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Biodiesel production from waste frying oils: Optimization of reaction parameters and determination of fuel properties

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  • Uzun, Başak Burcu
  • Kılıç, Murat
  • Özbay, Nurgül
  • Pütün, Ayşe E.
  • Pütün, Ersan

Abstract

Alkali-catalyzed transesterification of waste frying oils (WFO) was carried out in various conditions to investigate the effects of catalyst concentration, reaction time, methanol/oil molar ratio, reaction temperature, catalyst type (hydroxides, methoxides and ethoxides), and purification type (such as washing with hot water, purification with silica gel and dowex) on the biodiesel yields. The optimum conditions were 0.5%wt. of NaOH, 30min reaction time, 50°C reaction temperature, 7.5 methanol to oil ratio and purification with hot distilled water. 96% biodiesel yield with ∼97% ester content was obtained within in these conditions, and the activation energy was found to be as 11741Jmol−1. The determined specifications of obtained biodiesel according to ASTM D 6751 and EN 14214 standards were in accordance with the required limits. As a conclusion, the present study indicates that WFO derived fuel promises being an alternative for petrodiesel, and could be used in engines without a major modification due to its qualifications.

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  • Uzun, Başak Burcu & Kılıç, Murat & Özbay, Nurgül & Pütün, Ayşe E. & Pütün, Ersan, 2012. "Biodiesel production from waste frying oils: Optimization of reaction parameters and determination of fuel properties," Energy, Elsevier, vol. 44(1), pages 347-351.
    • Handle: RePEc:eee:energy:v:44:y:2012:i:1:p:347-351
    DOI: 10.1016/j.energy.2012.06.024
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    14. Richard Ochieng & Alemayehu Gebremedhin & Shiplu Sarker, 2022. "Integration of Waste to Bioenergy Conversion Systems: A Critical Review," Energies, MDPI, vol. 15(7), pages 1-22, April.
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    16. Badday, Ali Sabri & Abdullah, Ahmad Zuhairi & Lee, Keat-Teong, 2013. "Ultrasound-assisted transesterification of crude Jatropha oil using cesium doped heteropolyacid catalyst: Interactions between process variables," Energy, Elsevier, vol. 60(C), pages 283-291.
    17. Behçet, Rasim & Yumrutaş, Recep & Oktay, Hasan, 2014. "Effects of fuels produced from fish and cooking oils on performance and emissions of a diesel engine," Energy, Elsevier, vol. 71(C), pages 645-655.
    18. Tooba Touqeer & Muhammad Waseem Mumtaz & Hamid Mukhtar & Ahmad Irfan & Sadia Akram & Aroosh Shabbir & Umer Rashid & Imededdine Arbi Nehdi & Thomas Shean Yaw Choong, 2019. "Fe 3 O 4 -PDA-Lipase as Surface Functionalized Nano Biocatalyst for the Production of Biodiesel Using Waste Cooking Oil as Feedstock: Characterization and Process Optimization," Energies, MDPI, vol. 13(1), pages 1-19, December.
    19. Hüseyin Çamur & Ebaa Alassi, 2021. "Physicochemical Properties Enhancement of Biodiesel Synthesis from Various Feedstocks of Waste/Residential Vegetable Oils and Palm Oil," Energies, MDPI, vol. 14(16), pages 1-29, August.
    20. Dinesha, P. & Kumar, Shiva & Rosen, Marc A., 2019. "Combined effects of water emulsion and diethyl ether additive on combustion performance and emissions of a compression ignition engine using biodiesel blends," Energy, Elsevier, vol. 179(C), pages 928-937.
    21. Serrano, Marta & Oliveros, Rubén & Sánchez, Marcos & Moraschini, Andrea & Martínez, Mercedes & Aracil, José, 2014. "Influence of blending vegetable oil methyl esters on biodiesel fuel properties: Oxidative stability and cold flow properties," Energy, Elsevier, vol. 65(C), pages 109-115.

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