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Chelating agent assisted heat treatment of carbon supported cobalt oxide nanoparticle for use as cathode catalyst of polymer electrolyte membrane fuel cell (PEMFC)

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  • Huang, Chia-Hung
  • Liu, Shyh-Jiun
  • Hwang, Weng-Sing

Abstract

Cobalt-based catalysts for the oxygen reduction reaction (ORR) in polymer electrolyte membrane fuel cell (PEMFC) have been successfully incorporated cobalt oxide (Co3O4) onto Vulcan XC-72 carbon powder by thermal decomposition of Co–ethylenediamine complex (ethylenediamine, NH2CH2CH2NH2, denoted en) at 850°C. The catalysts were prepared by adsorbing the cobalt complexes [Co(en)(H2O)4]3+, [Co(en)2(H2O)2]3+ and [Co(en)3]3+ on commercial XC-72 carbon black supports, loading amount of Co with respect to carbon black was about 2%, the resulting materials have been pyrolyzed under nitrogen atmosphere to create CoOx/C catalysts, donated as E1, E2, and E3, respectively. The composite materials were characterized using X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM) and X-ray photoelectron spectroscopy (XPS). Chemical compositions of prepared catalysts were determined using inductively-coupled plasma-atomic emission spectroscopy (ICP-AES). The catalytic activities for ORR have been analyzed by cyclic voltammetry (CV) and linear sweep voltammetry (LSV). The electrocatalytic activity for oxygen reduction of E2 is superior to that of E1 and E3. Membrane electrode assemblies (MEAs) containing the synthesized CoOx/C cathode catalysts were fabricated and evaluated by single cell tests. The E2 cathode performed better than that of E1 and E3 cathode. This can be attributed to the enhanced activity for ORR, in agreement with the composition of the catalyst that CoO co-existed with Co3O4. The maximum power density 73mWcm−2 was obtained at 0.3V with a current density of 240mAcm−2 for E2 and the normalized power density of E2 is larger than that that of commercial 20wt.% Pt/C-ETEK.

Suggested Citation

  • Huang, Chia-Hung & Liu, Shyh-Jiun & Hwang, Weng-Sing, 2011. "Chelating agent assisted heat treatment of carbon supported cobalt oxide nanoparticle for use as cathode catalyst of polymer electrolyte membrane fuel cell (PEMFC)," Energy, Elsevier, vol. 36(7), pages 4410-4414.
    • Handle: RePEc:eee:energy:v:36:y:2011:i:7:p:4410-4414
    DOI: 10.1016/j.energy.2011.04.002
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    References listed on IDEAS

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    1. Polterovich, Victor & Popov, Vladimir, 2006. "Эволюционная Теория Экономической Политики: Часть I: Опыт Быстрого Развития [An Evolutionary Theory of Economic Policy: Part I: The Experience of Fast Development]," MPRA Paper 22168, University Library of Munich, Germany.
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    1. Park, Taehyun & Chang, Ikwhang & Lee, Yoon Ho & Ji, Sanghoon & Cha, Suk Won, 2014. "Analysis of operational characteristics of polymer electrolyte fuel cell with expanded graphite flow-field plates via electrochemical impedance investigation," Energy, Elsevier, vol. 66(C), pages 77-81.
    2. Liu, Shengchu & Hua, Shiyang & Lin, Rui & Wang, Hong & Cai, Xin & Ji, Weichen, 2022. "Improving the performance and durability of low Pt-loaded MEAs by adjusting the distribution positions of Pt particles in cathode catalyst layer," Energy, Elsevier, vol. 253(C).
    3. Huang, Yao-Hui & Su, Chia-Chi & Wang, Shu-Ling & Lu, Ming-Chun, 2012. "Development of Al2O3 carrier-Ru composite catalyst for hydrogen generation from alkaline NaBH4 hydrolysis," Energy, Elsevier, vol. 46(1), pages 242-247.
    4. Song, Xingjuan & Zhang, Dongming, 2014. "Bimetallic Ag–Ni/C particles as cathode catalyst in AFCs (alkaline fuel cells)," Energy, Elsevier, vol. 70(C), pages 223-230.
    5. Huang, Zhen-Ming & Su, Ay & Liu, Ying-Chieh, 2013. "Hydrogen generator system using Ru catalyst for PEMFC (proton exchange membrane fuel cell) applications," Energy, Elsevier, vol. 51(C), pages 230-236.

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