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Catalytic pyrolysis of biomass: Effects of pyrolysis temperature, sweeping gas flow rate and MgO catalyst

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  • Pütün, Ersan

Abstract

Cotton seed, as a biomass source, is pyrolysed in a tubular fixed-bed reactor under various sweeping gas (N2) flow rates at different pyrolysis temperatures. In the non-catalytic work, the maximum bio-oil yield was attained as 48.30% at 550°C with a sweeping gas flow rate of 200mLmin−1. At the optimum conditions, catalytic pyrolysis of biomass samples was performed with various amounts of MgO catalyst (5, 10, 15, and 20wt.% of raw material). Catalyst addition decreased the quantity of bio-oil yet increased the quality of bio-oil in terms of calorific value, hydrocarbon distribution and removal of oxygenated groups. It was observed that increasing the amount of catalyst used, decreased the oil yields while increased the gas and char yields. Bio-oils obtained at the optimum conditions were separated into aliphatic, aromatic and polar sub-fractions. After the application of column chromatography, bio-oils were subjected into elemental, FT-IR and 1H NMR analyses. Aliphatic sub-fractions of bio-oils were analyzed by GC–MS. It was deduced that the fuel obtained via catalytic pyrolysis mainly consisted of lower weight hydrocarbons in the diesel range. Finally, obtained results were compared with petroleum fractions and evaluated as a potential source for liquid fuels.

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  • Pütün, Ersan, 2010. "Catalytic pyrolysis of biomass: Effects of pyrolysis temperature, sweeping gas flow rate and MgO catalyst," Energy, Elsevier, vol. 35(7), pages 2761-2766.
    • Handle: RePEc:eee:energy:v:35:y:2010:i:7:p:2761-2766
    DOI: 10.1016/j.energy.2010.02.024
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    1. Ioannidou, O. & Zabaniotou, A. & Antonakou, E.V. & Papazisi, K.M. & Lappas, A.A. & Athanassiou, C., 2009. "Investigating the potential for energy, fuel, materials and chemicals production from corn residues (cobs and stalks) by non-catalytic and catalytic pyrolysis in two reactor configurations," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(4), pages 750-762, May.
    2. Özbay, N & Pütün, A.E & Uzun, B.B & Pütün, E, 2001. "Biocrude from biomass: pyrolysis of cottonseed cake," Renewable Energy, Elsevier, vol. 24(3), pages 615-625.
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    1. Sonil Nanda & Pravakar Mohanty & Janusz Kozinski & Ajay Dalai, 2014. "Physico-Chemical Properties of Bio-Oils from Pyrolysis of Lignocellulosic Biomass with High and Slow Heating Rate," Energy and Environment Research, Canadian Center of Science and Education, vol. 4(3), pages 1-21, December.
    2. Theodore Dickerson & Juan Soria, 2013. "Catalytic Fast Pyrolysis: A Review," Energies, MDPI, vol. 6(1), pages 1-25, January.
    3. Xing, Shiyou & Yuan, Haoran & Huhetaoli, & Qi, Yujie & Lv, Pengmei & Yuan, Zhenhong & Chen, Yong, 2016. "Characterization of the decomposition behaviors of catalytic pyrolysis of wood using copper and potassium over thermogravimetric and Py-GC/MS analysis," Energy, Elsevier, vol. 114(C), pages 634-646.

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