IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v297y2024ics0360544224009745.html
   My bibliography  Save this article

Inner-particle reaction mechanism of cellulose, hemicellulose and lignin during photo-thermal pyrolysis process: Evolution characteristics of free radicals

Author

Listed:
  • Song, Gongxiang
  • Huang, Dexin
  • Ren, Qiangqiang
  • Hu, Song
  • Xu, Jun
  • Xu, Kai
  • Jiang, Long
  • Wang, Yi
  • Su, Sheng
  • Xiang, Jun

Abstract

Based on the concentrated photo-thermal thermogravimetry analyzer (PT-TGA) reactor, the pyrolysis of the cellulose, hemicellulose and lignin with different ratios at 100 °C/min and 550–850 °C was performed. The interaction among the three components significantly reduced the reaction temperatures and increased the maximum weight loss rate. The cellulose/lignin interactions were the main reason for the increase of gas production, especially for the H2 production which reached 128.13 mL/g biomass, much higher than the calculated value of 75.35 mL/g biomass without considering the interactions. What occurred during the co-pyrolysis of cellulose/lignin was the combination of free radicals without consuming the hydrogen radicals, while the formation of chemicals in others’ interactions integrated with the hydrogen radicals inhibited the production of H2 at high temperatures. For full-component pyrolysis, the yield of C-containing gas can be calculated by adding a coefficient of interaction between two components, indicating that the effect of the three-component interaction was much lower than that of the two-component. This study established the interaction mechanism for the three components of biomass during photo-thermal pyrolysis based on free radicals.

Suggested Citation

  • Song, Gongxiang & Huang, Dexin & Ren, Qiangqiang & Hu, Song & Xu, Jun & Xu, Kai & Jiang, Long & Wang, Yi & Su, Sheng & Xiang, Jun, 2024. "Inner-particle reaction mechanism of cellulose, hemicellulose and lignin during photo-thermal pyrolysis process: Evolution characteristics of free radicals," Energy, Elsevier, vol. 297(C).
    • Handle: RePEc:eee:energy:v:297:y:2024:i:c:s0360544224009745
    DOI: 10.1016/j.energy.2024.131201
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544224009745
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2024.131201?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Tamer Y. A. Fahmy & Yehia Fahmy & Fardous Mobarak & Mohamed El-Sakhawy & Ragab E. Abou-Zeid, 2020. "Biomass pyrolysis: past, present, and future," Environment, Development and Sustainability: A Multidisciplinary Approach to the Theory and Practice of Sustainable Development, Springer, vol. 22(1), pages 17-32, January.
    2. Taylor Uekert & Christian M. Pichler & Teresa Schubert & Erwin Reisner, 2021. "Solar-driven reforming of solid waste for a sustainable future," Nature Sustainability, Nature, vol. 4(5), pages 383-391, May.
    3. Huang, Xiankun & Yin, Hongchao & Zhang, Hu & Mei, Ning & Mu, Lin, 2022. "Pyrolysis characteristics, gas products, volatiles, and thermo–kinetics of industrial lignin via TG/DTG–FTIR/MS and in–situ Py–PI–TOF/MS," Energy, Elsevier, vol. 259(C).
    4. Li, Chao & Sun, Yifan & Dong, Dehua & Gao, Guanggang & Zhang, Shu & Wang, Yi & Xiang, Jun & Hu, Song & Mortaza, Gholizadeh & Hu, Xun, 2021. "Co-pyrolysis of cellulose/lignin and sawdust: Influence of secondary condensation of the volatiles on characteristics of biochar," Energy, Elsevier, vol. 226(C).
    5. Tian Li & Chaoji Chen & Alexandra H. Brozena & J. Y. Zhu & Lixian Xu & Carlos Driemeier & Jiaqi Dai & Orlando J. Rojas & Akira Isogai & Lars Wågberg & Liangbing Hu, 2021. "Developing fibrillated cellulose as a sustainable technological material," Nature, Nature, vol. 590(7844), pages 47-56, February.
    6. Font Palma, Carolina, 2013. "Modelling of tar formation and evolution for biomass gasification: A review," Applied Energy, Elsevier, vol. 111(C), pages 129-141.
    7. Song, Gongxiang & Huang, Dexin & Li, Hanjian & Wang, Xuepeng & Ren, Qiangqiang & Jiang, Long & Wang, Yi & Su, Sheng & Hu, Song & Xiang, Jun, 2022. "Pyrolysis reaction mechanism of typical Chinese agriculture and forest waste pellets at high heating rates based on the photo-thermal TGA," Energy, Elsevier, vol. 244(PB).
    8. Xiao, Ruirui & Yang, Wei & Cong, Xingshun & Dong, Kai & Xu, Jie & Wang, Dengfeng & Yang, Xin, 2020. "Thermogravimetric analysis and reaction kinetics of lignocellulosic biomass pyrolysis," Energy, Elsevier, vol. 201(C).
    9. Ding, Yanming & Huang, Biqing & Li, Kaiyuan & Du, Wenzhou & Lu, Kaihua & Zhang, Yansong, 2020. "Thermal interaction analysis of isolated hemicellulose and cellulose by kinetic parameters during biomass pyrolysis," Energy, Elsevier, vol. 195(C).
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Escalante, Jamin & Chen, Wei-Hsin & Tabatabaei, Meisam & Hoang, Anh Tuan & Kwon, Eilhann E. & Andrew Lin, Kun-Yi & Saravanakumar, Ayyadurai, 2022. "Pyrolysis of lignocellulosic, algal, plastic, and other biomass wastes for biofuel production and circular bioeconomy: A review of thermogravimetric analysis (TGA) approach," Renewable and Sustainable Energy Reviews, Elsevier, vol. 169(C).
    2. Ahmed, A.M.A & Salmiaton, A. & Choong, T.S.Y & Wan Azlina, W.A.K.G., 2015. "Review of kinetic and equilibrium concepts for biomass tar modeling by using Aspen Plus," Renewable and Sustainable Energy Reviews, Elsevier, vol. 52(C), pages 1623-1644.
    3. Jiadong Tang & Yun Wang & Hongyang Yang & Qianqian Zhang & Ce Wang & Leyuan Li & Zilong Zheng & Yuhong Jin & Hao Wang & Yifan Gu & Tieyong Zuo, 2024. "All-natural 2D nanofluidics as highly-efficient osmotic energy generators," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    4. Hu, Lin & Xu, Mei-Ling & Wei, Xian-Yong & Yu, Changlin & Wu, Jingcheng & Wang, Haiyong & Liu, Tianlong, 2024. "Effect of ethanolysis on the structure evolution, pyrolysis kinetics, and volatile products of waste poplar sawdust," Energy, Elsevier, vol. 305(C).
    5. Huang, Shengxiong & Lei, Can & Qin, Jie & Yi, Cheng & Chen, Tao & Yao, Lingling & Li, Bo & Wen, Yujiao & Zhou, Zhi & Xia, Mao, 2022. "Properties, kinetics and pyrolysis products distribution of oxidative torrefied camellia shell in different oxygen concentration," Energy, Elsevier, vol. 251(C).
    6. Neves, Daniel & Thunman, Henrik & Tarelho, Luís & Larsson, Anton & Seemann, Martin & Matos, Arlindo, 2014. "Method for online measurement of the CHON composition of raw gas from biomass gasifier," Applied Energy, Elsevier, vol. 113(C), pages 932-945.
    7. Elhambakhsh, Abbas & Van Duc Long, Nguyen & Lamichhane, Pradeep & Hessel, Volker, 2023. "Recent progress and future directions in plasma-assisted biomass conversion to hydrogen," Renewable Energy, Elsevier, vol. 218(C).
    8. Katarzyna Kocur-Bera & Anna Lyjak, 2021. "Analysis of Changes in Agricultural Use of Land After Poland’s Accession to the EU," European Research Studies Journal, European Research Studies Journal, vol. 0(4), pages 517-533.
    9. Itxaso Anso & Samira Zouhir & Thibault Géry Sana & Petya Violinova Krasteva, 2024. "Structural basis for synthase activation and cellulose modification in the E. coli Type II Bcs secretion system," Nature Communications, Nature, vol. 15(1), pages 1-15, December.
    10. Kuo, Po-Chih & Illathukandy, Biju & Wu, Wei & Chang, Jo-Shu, 2021. "Energy, exergy, and environmental analyses of renewable hydrogen production through plasma gasification of microalgal biomass," Energy, Elsevier, vol. 223(C).
    11. Ma, Junfang & Liu, Jiaxun & Jiang, Xiumin & Zhang, Hai, 2021. "A two-dimensional distributed activation energy model for pyrolysis of solid fuels," Energy, Elsevier, vol. 230(C).
    12. Monteiro, Eliseu & Ismail, Tamer M. & Ramos, Ana & Abd El-Salam, M. & Brito, Paulo & Rouboa, Abel, 2018. "Experimental and modeling studies of Portuguese peach stone gasification on an autothermal bubbling fluidized bed pilot plant," Energy, Elsevier, vol. 142(C), pages 862-877.
    13. Michela Costa & Maurizio La Villetta & Daniele Piazzullo & Domenico Cirillo, 2021. "A Phenomenological Model of a Downdraft Biomass Gasifier Flexible to the Feedstock Composition and the Reactor Design," Energies, MDPI, vol. 14(14), pages 1-29, July.
    14. Niu, Miaomiao & Sun, Rongyue & Ding, Kuan & Gu, Haiming & Cui, Xiaobo & Wang, Liang & Hu, Jichu, 2022. "Synergistic effect on thermal behavior and product characteristics during co-pyrolysis of biomass and waste tire: Influence of biomass species and waste blending ratios," Energy, Elsevier, vol. 240(C).
    15. Pere Ariza-Montobbio & Susana Herrero Olarte, 2021. "Socio-metabolic profiles of electricity consumption along the rural–urban continuum of Ecuador: Whose energy sovereignty?," Environment, Development and Sustainability: A Multidisciplinary Approach to the Theory and Practice of Sustainable Development, Springer, vol. 23(5), pages 7961-7995, May.
    16. Buentello-Montoya, David & Zhang, Xiaolei & Li, Jun & Ranade, Vivek & Marques, Simão & Geron, Marco, 2020. "Performance of biochar as a catalyst for tar steam reforming: Effect of the porous structure," Applied Energy, Elsevier, vol. 259(C).
    17. Ruivo, Luís & Silva, Tiago & Neves, Daniel & Tarelho, Luís & Frade, Jorge, 2023. "Thermodynamic guidelines for improved operation of iron-based catalysts in gasification of biomass," Energy, Elsevier, vol. 268(C).
    18. Singh, Piyush Pratap & Jaswal, Anurag & Nirmalkar, Neelkanth & Mondal, Tarak, 2023. "Synergistic effect of transition metals substitution on the catalytic activity of LaNi0.5M0.5O3 (M = Co, Cu, and Fe) perovskite catalyst for steam reforming of simulated bio-oil for green hydrogen pro," Renewable Energy, Elsevier, vol. 207(C), pages 575-587.
    19. Chen, Yuxiang & Li, Chao & Zhang, Lijun & Zhang, Shu & Xiang, Jun & Hu, Song & Wang, Yi & Hu, Xun, 2024. "Varied directions of heat flow and emission of volatiles impact evolution of products in pyrolysis of wet and dry pine needles," Renewable Energy, Elsevier, vol. 226(C).
    20. Audronė Minelgaitė & Genovaitė Liobikienė, 2021. "Changes in pro-environmental behaviour and its determinants during long-term period in a transition country as Lithuania," Environment, Development and Sustainability: A Multidisciplinary Approach to the Theory and Practice of Sustainable Development, Springer, vol. 23(11), pages 16083-16099, November.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:297:y:2024:i:c:s0360544224009745. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.