IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v293y2024ics0360544224004791.html
   My bibliography  Save this article

Effect of inorganic salts / lignin on the combustion performance of torrefied biochar

Author

Listed:
  • Zhang, Yan
  • Zhao, Zhihong
  • Xing, Dong
  • Hu, Jianpeng
  • Liu, Wenjing
  • Wang, Xue
  • Yao, Lihong

Abstract

In this study, inorganic salts (KMnO4, Ba(NO3)2) and enzymolysis lignin were added into torrefied biochar to improve the drawback of high ignition temperature during combustion when biomass underwent torrefaction. Weight loss characteristics, gas products, combustion kinetics of torrefied biochar with different additives were investigated. The addition of KMnO4, Ba(NO3)2, enzymolysis lignin, and their blends can reduce the ignition point of torrefied biochar, and the addition of Ba(NO3)2 can also extent the burnout time. When KMnO4, Ba(NO3)2 and lignin were added at the same time, the first weight loss peak temperature was reduced, and the reaction rate was accelerated. The combustion kinetics of torrefied biochar with different inorganic salts/lignin can be described by a simple first-order reaction. The addition of different inorganic salts/lignin additives is beneficial to reduce the activation energy of the low temperature reaction stage, and the activation energy of torrefied biochar with lignin addition decreases the most.

Suggested Citation

  • Zhang, Yan & Zhao, Zhihong & Xing, Dong & Hu, Jianpeng & Liu, Wenjing & Wang, Xue & Yao, Lihong, 2024. "Effect of inorganic salts / lignin on the combustion performance of torrefied biochar," Energy, Elsevier, vol. 293(C).
  • Handle: RePEc:eee:energy:v:293:y:2024:i:c:s0360544224004791
    DOI: 10.1016/j.energy.2024.130707
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544224004791
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.energy.2024.130707?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Chen, Wei-Hsin & Peng, Jianghong & Bi, Xiaotao T., 2015. "A state-of-the-art review of biomass torrefaction, densification and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 44(C), pages 847-866.
    2. Park, Sang-Woo & Jang, Cheol-Hyeon, 2012. "Effects of pyrolysis temperature on changes in fuel characteristics of biomass char," Energy, Elsevier, vol. 39(1), pages 187-195.
    3. Peng, Jianghong & Bi, Xiaotao T. & Lim, C. Jim & Peng, Hanchao & Kim, Chang Soo & Jia, Dening & Zuo, Haibin, 2015. "Sawdust as an effective binder for making torrefied pellets," Applied Energy, Elsevier, vol. 157(C), pages 491-498.
    4. Hu, Qiang & Shao, Jingai & Yang, Haiping & Yao, Dingding & Wang, Xianhua & Chen, Hanping, 2015. "Effects of binders on the properties of bio-char pellets," Applied Energy, Elsevier, vol. 157(C), pages 508-516.
    5. Kong, Lingjun & Tian, ShuangHong & Li, Zhaohui & Luo, Rongshu & Chen, Dingsheng & Tu, YuTing & Xiong, Ya, 2013. "Conversion of recycled sawdust into high HHV and low NOx emission bio-char pellets using lignin and calcium hydroxide blended binders," Renewable Energy, Elsevier, vol. 60(C), pages 559-565.
    6. Zhang, Yan & Song, Kuiyan, 2018. "Thermal and chemical characteristics of torrefied biomass derived from a generated volatile atmosphere," Energy, Elsevier, vol. 165(PB), pages 235-245.
    7. Backer, Michael & Gladen, Adam, 2023. "Impact of salt composition and temperature on low-temperature torrefaction of pine in molten nitrate salts," Energy, Elsevier, vol. 263(PE).
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Riva, Lorenzo & Nielsen, Henrik Kofoed & Skreiberg, Øyvind & Wang, Liang & Bartocci, Pietro & Barbanera, Marco & Bidini, Gianni & Fantozzi, Francesco, 2019. "Analysis of optimal temperature, pressure and binder quantity for the production of biocarbon pellet to be used as a substitute for coke," Applied Energy, Elsevier, vol. 256(C).
    2. Mostafa, Mohamed E. & Hu, Song & Wang, Yi & Su, Sheng & Hu, Xun & Elsayed, Saad A. & Xiang, Jun, 2019. "The significance of pelletization operating conditions: An analysis of physical and mechanical characteristics as well as energy consumption of biomass pellets," Renewable and Sustainable Energy Reviews, Elsevier, vol. 105(C), pages 332-348.
    3. Yang, Wei & Zhu, Youjian & Cheng, Wei & Sang, Huiying & Xu, Hanshen & Yang, Haiping & Chen, Hanping, 2018. "Effect of minerals and binders on particulate matter emission from biomass pellets combustion," Applied Energy, Elsevier, vol. 215(C), pages 106-115.
    4. Shui, Tao & Khatri, Vinay & Chae, Michael & Sokhansanj, Shahabaddine & Choi, Phillip & Bressler, David C., 2020. "Development of a torrefied wood pellet binder from the cross-linking between specified risk materials-derived peptides and epoxidized poly (vinyl alcohol)," Renewable Energy, Elsevier, vol. 162(C), pages 71-80.
    5. James W. Butler & William Skrivan & Samira Lotfi, 2023. "Identification of Optimal Binders for Torrefied Biomass Pellets," Energies, MDPI, vol. 16(8), pages 1-23, April.
    6. Safa Arous & Ahmed Koubaa & Hassine Bouafif & Besma Bouslimi & Flavia Lega Braghiroli & Chedly Bradai, 2021. "Effect of Pyrolysis Temperature and Wood Species on the Properties of Biochar Pellets," Energies, MDPI, vol. 14(20), pages 1-15, October.
    7. Riva, Lorenzo & Surup, Gerrit Ralf & Buø, Therese Videm & Nielsen, Henrik Kofoed, 2019. "A study of densified biochar as carbon source in the silicon and ferrosilicon production," Energy, Elsevier, vol. 181(C), pages 985-996.
    8. Ong, Hwai Chyuan & Yu, Kai Ling & Chen, Wei-Hsin & Pillejera, Ma Katreena & Bi, Xiaotao & Tran, Khanh-Quang & Pétrissans, Anelie & Pétrissans, Mathieu, 2021. "Variation of lignocellulosic biomass structure from torrefaction: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 152(C).
    9. Zhu, Youjian & Yang, Wei & Fan, Jiyuan & Kan, Tao & Zhang, Wennan & Liu, Heng & Cheng, Wei & Yang, Haiping & Wu, Xuehong & Chen, Hanping, 2018. "Effect of sodium carboxymethyl cellulose addition on particulate matter emissions during biomass pellet combustion," Applied Energy, Elsevier, vol. 230(C), pages 925-934.
    10. Arkadiusz Dyjakon & Tomasz Noszczyk, 2020. "Alternative Fuels from Forestry Biomass Residue: Torrefaction Process of Horse Chestnuts, Oak Acorns, and Spruce Cones," Energies, MDPI, vol. 13(10), pages 1-19, May.
    11. Yun, Huimin & Clift, Roland & Bi, Xiaotao, 2020. "Process simulation, techno-economic evaluation and market analysis of supply chains for torrefied wood pellets from British Columbia: Impacts of plant configuration and distance to market," Renewable and Sustainable Energy Reviews, Elsevier, vol. 127(C).
    12. Ashokkumar, Veeramuthu & Chen, Wei-Hsin & Kamyab, Hesam & Kumar, Gopalakrishnan & Al-Muhtaseb, Ala'a H. & Ngamcharussrivichai, Chawalit, 2019. "Cultivation of microalgae Chlorella sp. in municipal sewage for biofuel production and utilization of biochar derived from residue for the conversion of hematite iron ore (Fe2O3) to iron (Fe) – Integr," Energy, Elsevier, vol. 189(C).
    13. Manouchehrinejad, Maryam & Bilek, E.M. Ted & Mani, Sudhagar, 2021. "Techno-economic analysis of integrated torrefaction and pelletization systems to produce torrefied wood pellets," Renewable Energy, Elsevier, vol. 178(C), pages 483-493.
    14. Surup, Gerrit & Vehus, Tore & Eidem, Per-Anders & Trubetskaya, Anna & Nielsen, Henrik Kofoed, 2019. "Characterization of renewable reductants and charcoal-based pellets for the use in ferroalloy industries," Energy, Elsevier, vol. 167(C), pages 337-345.
    15. Korshunov, Alexey & Kichatov, Boris & Melnikova, Ksenia & Gubernov, Vladimir & Yakovenko, Ivan & Kiverin, Alexey & Golubkov, Alexandr, 2019. "Pyrolysis characteristics of biomass torrefied in a quiescent mineral layer," Energy, Elsevier, vol. 187(C).
    16. Yek, Peter Nai Yuh & Cheng, Yoke Wang & Liew, Rock Keey & Wan Mahari, Wan Adibah & Ong, Hwai Chyuan & Chen, Wei-Hsin & Peng, Wanxi & Park, Young-Kwon & Sonne, Christian & Kong, Sieng Huat & Tabatabaei, 2021. "Progress in the torrefaction technology for upgrading oil palm wastes to energy-dense biochar: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).
    17. El may, Yassine & Jeguirim, Mejdi & Dorge, Sophie & Trouvé, Gwenaelle & Said, Rachid, 2012. "Study on the thermal behavior of different date palm residues: Characterization and devolatilization kinetics under inert and oxidative atmospheres," Energy, Elsevier, vol. 44(1), pages 702-709.
    18. Stachowicz, Paweł & Stolarski, Mariusz J., 2024. "Pellets from mixtures of short rotation coppice with forest-derived biomass: Production costs and energy intensity," Renewable Energy, Elsevier, vol. 225(C).
    19. Batidzirai, B. & Mignot, A.P.R. & Schakel, W.B. & Junginger, H.M. & Faaij, A.P.C., 2013. "Biomass torrefaction technology: Techno-economic status and future prospects," Energy, Elsevier, vol. 62(C), pages 196-214.
    20. Abdulyekeen, Kabir Abogunde & Daud, Wan Mohd Ashri Wan & Patah, Muhamad Fazly Abdul, 2024. "Torrefaction of wood and garden wastes from municipal solid waste to enhanced solid fuel using helical screw rotation-induced fluidised bed reactor: Effect of particle size, helical screw speed and te," Energy, Elsevier, vol. 293(C).

    More about this item

    Keywords

    KMnO4; Ba(NO3)2; Lignin; Combustion kinetics; Oxidizer;
    All these keywords.

    JEL classification:

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:293:y:2024:i:c:s0360544224004791. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.