Thermal storage process of phase change materials under high humidity and laminar natural convection condition: Prediction model and sensitivity analysis

The application of phase change materials (PCMs) in renewable energy storage and building temperature regulation is considered an effective method to reduce the use of fossil fuels and carbon emissions. However, issues concerning the utilization of PCMs in high-humidity environments remain to be addressed to fill the gap in real-world applications. This paper establishes a simplified novel two-zone model, comprehensively considering the natural convection on the surface of the PCP in high-humidity environments, as well as the formation, movement, and evaporation of water films on the surface. Subsequently, numerical solutions and experimental validation are conducted, and the influence of high-humidity environments on the heat and moisture transfer is elucidated. The results indicate that a high-humidity environment can significantly suppress the sensible heat transfer with a ratio range of latent heat to sensible heat typically around 1–4. Furthermore, the increase in the height of PCP leads to an increase in the proportion of sensible heat transfer. On the contrary, increasing the thermal conductivity of the PCM can amplify the latent heat transfer. The results can help further study the thermal storage and the dehumidification potential of phase change units in application on a large scale under high humidity conditions.