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Synergistic effect of biomass potassium content and oxidative atmosphere: Impact on torrefaction severity and released condensables

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  • Macedo, Lucélia A.
  • Silveira, Edgar A.
  • Rousset, Patrick
  • Valette, Jérémy
  • Commandré, Jean-Michel

Abstract

This study investigates the synergistic behavior between oxidative atmosphere and potassium catalytic effects on woody (Amapaí) and non-woody (Miscanthus) biomass. Inert and oxygen-lean torrefaction was conducted at 275 °C for demineralized and K-loaded samples in fixed-bed and thermo-gravimetric equipment. Torrefaction improvement was assessed by torrefaction severity index (TSI), Catalytic Enhancement Area (CEA), Catalytic index (CI), and conversion rate (CR). Gas chromatography-mass spectrometry analyzed the impact on condensable compounds. The K% anticipated the biomass oxidation and the oxidative medium improved the catalytic effect. CEA and CI provided a reliable performance index (R2 > 0.90) to assess the synergistic effect. Condensable compound yields variation with increasing K% was similar for both atmospheres but the K-impact on the compounds production was intensified under oxidative conditions. The furfuryl alcohol yield increased by a factor of 30 for Amapaí comparing higher K% and demineralized samples, whereas a factor of 3 was observed for inert conditions. For Miscanthus, the factors of increasing production were 22 and 5 for oxidative and inert atmosphere. Under oxygen-lean, syringaldehyde and vanillin yields decreased with higher K%, whereas inert treatment revealed insignificant effects. The results indicate that torrefaction duration and targeted condensates production could be improved according to the K% and atmosphere.

Suggested Citation

  • Macedo, Lucélia A. & Silveira, Edgar A. & Rousset, Patrick & Valette, Jérémy & Commandré, Jean-Michel, 2022. "Synergistic effect of biomass potassium content and oxidative atmosphere: Impact on torrefaction severity and released condensables," Energy, Elsevier, vol. 254(PC).
    • Handle: RePEc:eee:energy:v:254:y:2022:i:pc:s0360544222013755
    DOI: 10.1016/j.energy.2022.124472
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    1. A. Silveira, Edgar & Santanna Chaves, Bruno & Macedo, Lucélia & Ghesti, Grace F. & Evaristo, Rafael B.W. & Cruz Lamas, Giulia & Luz, Sandra M. & Protásio, Thiago de Paula & Rousset, Patrick, 2023. "A hybrid optimization approach towards energy recovery from torrefied waste blends," Renewable Energy, Elsevier, vol. 212(C), pages 151-165.

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