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Catalytic co-pyrolysis of woody biomass with waste plastics: Effects of HZSM-5 and pyrolysis temperature on producing high-value pyrolytic products and reducing wax formation

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  • Jin, Xuanjun
  • Lee, Jae Hoon
  • Choi, Joon Weon

Abstract

In this study, using an analytical pyrolysis-GC/MS system, pine sawdust was pyrolyzed with polyethylene (PE) and polyethylene terephthalate (PET) in the presence of HZSM-5 to investigate the effect of plastic. Pyrolysis was performed at 500 °C, 600 °C, and 700 °C after 3.0 mg feedstock loading. Chemical compounds were identified and classified into six groups: Monomeric Aromatic Hydrocarbon (MAH), Polycyclic Aromatic Hydrocarbon (PAH), Phenols, Furfurals, Alkenes, and Alkanes. Results showed that pine and PE co-pyrolysis significantly decreased oxygen content from 23.4% (pine only) to 0.3% (pine + PE/HZSM-5), which increased products’ HHV from 25.9 MJ/kg to 34.4 MJ/kg. It also revealed that the pine and PE ratio did not heavily influence the petrochemical concentration (aromatic hydrocarbons + alkenes (C ≤ 15) + alkanes (C ≤ 13)). However, a higher plastic ratio led to a higher wax production, which is the reason for poor condensation performance in condenser bio-oil capture. A pinewood sawdust to PE ratio of 3:1 showed the most higher-level petrochemicals and least amount of wax formation. Pine and PET co-pyrolysis produced significantly less wax and similar aromatic hydrocarbons to pine and PE co-pyrolysis. It also made as many acids as PET depolymerization and is a problem for pyrolysis oil use.

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  • Jin, Xuanjun & Lee, Jae Hoon & Choi, Joon Weon, 2022. "Catalytic co-pyrolysis of woody biomass with waste plastics: Effects of HZSM-5 and pyrolysis temperature on producing high-value pyrolytic products and reducing wax formation," Energy, Elsevier, vol. 239(PA).
    • Handle: RePEc:eee:energy:v:239:y:2022:i:pa:s0360544221019873
    DOI: 10.1016/j.energy.2021.121739
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    References listed on IDEAS

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    1. Long, Huiling & Li, Xiaobing & Wang, Hong & Jia, Jingdun, 2013. "Biomass resources and their bioenergy potential estimation: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 26(C), pages 344-352.
    2. Chattopadhyay, Jayeeta & Pathak, T.S. & Srivastava, R. & Singh, A.C., 2016. "Catalytic co-pyrolysis of paper biomass and plastic mixtures (HDPE (high density polyethylene), PP (polypropylene) and PET (polyethylene terephthalate)) and product analysis," Energy, Elsevier, vol. 103(C), pages 513-521.
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    4. Zhu, Liang & Cai, Wei & Li, Jie & Chen, Dengyu & Ma, Zhongqing, 2024. "Highly selective production of light aromatics from co-catalytic fast pyrolysis of pre-deoxygenated biomass and hydrogen-rich polyethylene using a dual-catalyst system," Energy, Elsevier, vol. 296(C).
    5. Fujin Mo & Habib Ullah & Noor Zada & Asfandyar Shahab, 2023. "A Review on Catalytic Co-Pyrolysis of Biomass and Plastics Waste as a Thermochemical Conversion to Produce Valuable Products," Energies, MDPI, vol. 16(14), pages 1-28, July.
    6. Chen, Chunxiang & Zhao, Jian & Wei, Yixue & Huang, Xiaodong & Lu, Wei & Fan, Dianzhao & Bi, Yingxin & Qiu, Hongfu, 2023. "Influence of graphite/alumina on co-pyrolysis of Chlorella vulgaris and polypropylene for producing bio-oil," Energy, Elsevier, vol. 265(C).

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