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Integrated hydrogen liquefaction processes with LNG production by two-stage helium reverse Brayton cycles taking industrial by-products as feedstock gas

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  • Xu, Jingxuan
  • Lin, Wensheng

Abstract

Hydrogen-rich industrial by-products, such as coke oven gas (COG) and synthetic ammonia exhaust tail gas, are often simply utilized as fuel gas, or even not utilized at all in many cases. An innovative and efficient utilization method is proposed and investigated in this paper. Aiming to coproduce liquid hydrogen and liquefied natural gas (LNG), three helium reverse Brayton cycles are constructed, optimized, analyzed and compared. The LN-He-1 process is constructed with reference to conventional industrial hydrogen liquefaction processes, but with different feedstock gas. The LN-He-2 and N–He processes, which are an improvement on the basis of LN-He-1. A combination of distillation and flash is utilized to reduce the separation load. Analysis of load variation, power consumption, exergy, heat transfer and turbomachinery efficiencies are carried out. For different feedstock gas compositions, the specific power consumptions of LN-He-1, LN-He-2 and N–He processes are within 26.45–54.78 kWh/kmol (feedstock gas), 26.32–53.78 kWh/kmol (feedstock gas) and 21.94–50.42 kWh/kmol (feedstock gas), respectively. The exergy efficiencies are between 13.0% and 66.5%.

Suggested Citation

  • Xu, Jingxuan & Lin, Wensheng, 2021. "Integrated hydrogen liquefaction processes with LNG production by two-stage helium reverse Brayton cycles taking industrial by-products as feedstock gas," Energy, Elsevier, vol. 227(C).
    • Handle: RePEc:eee:energy:v:227:y:2021:i:c:s0360544221006927
    DOI: 10.1016/j.energy.2021.120443
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    References listed on IDEAS

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    5. Bi, Yujing & Ju, Yonglin, 2022. "Design and analysis of an efficient hydrogen liquefaction process based on helium reverse Brayton cycle integrating with steam methane reforming and liquefied natural gas cold energy utilization," Energy, Elsevier, vol. 252(C).
    6. Julian David Hunt & Behnam Zakeri & Andreas Nascimento & Fei Guo & Marcos Aurélio Vasconcelos de Freitas & Cristiano Vitorino Silva & Bas van Ruijven, 2023. "Ammonia Airship Cooling: An Option for Renewable Cooling in the Tropics," Energies, MDPI, vol. 17(1), pages 1-16, December.
    7. Shamsi, Mohammad & Rooeentan, Saeed & karami, Behtash & Elyasi Gomari, Kamal & Naseri, Masoud & Bonyadi, Mohammad, 2023. "Design and thermodynamic analysis of a novel structure utilizing coke oven gas for LNG and power cogeneration," Energy, Elsevier, vol. 277(C).
    8. Qiu, Guoyi & Zhu, Shaolong & Wang, Kai & Wang, Weibo & Hu, Junhui & Hu, Yun & Zhi, Xiaoqin & Qiu, Limin, 2023. "Numerical study on the dynamic process of reciprocating liquid hydrogen pumps for hydrogen refueling stations," Energy, Elsevier, vol. 281(C).
    9. Zhang, Rui & Cao, Xuewen & Zhang, Xingwang & Yang, Jian & Bian, Jiang, 2024. "Co-benefits of the liquid hydrogen economy and LNG economy: Advances in LNG integrating LH2 production processes," Energy, Elsevier, vol. 301(C).

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