IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v199y2020ics0360544220305442.html
   My bibliography  Save this article

Full carbon upcycling of landfill gas into methanol by integrating CO2 hydrogenation and methane reforming: Process development and techno-economic analysis

Author

Listed:
  • Lee, Junyoung
  • Kim, Sunghoon
  • Kim, Yong Tae
  • Kwak, Geunjae
  • Kim, Jiyong

Abstract

This study proposes an innovative methanol production process from landfill gas (LFG) through direct CO2 hydrogenation and methane (CH4) reforming. The integration of two methanol production routes from CO2 and CH4 enables the full upcycling of carbon sources in the LFG into methanol, as compared to conventional processes that utilize only CH4 as a carbon source. The optimal process configurations and operating conditions of two LFG-to-methanol processes (L2M), stand-alone (L2M-SA) and with hydrogen supply (L2M−HS), are proposed by developing rigorous process models with the aid of sequential quadratic programming optimization. The capability of the processes is analyzed using four evaluation metrics: carbon and energy efficiencies, net CO2 emission, and unit production cost (UPC). It was observed that the carbon and energy efficiencies of both the L2M processes could reach up to 92% and 69%, respectively. The methanol UPC is estimated in the range of 392–440 USD/ton, which is competitive against other renewable and conventional methanol production options. In addition, the CO2 emission (0.83 and 1.29 kg of CO2 per kg of MeOH of the L2M−HS and -SA, respectively) implies that the full upcycling of LFG to methanol is not only economically viable but also an environmentally clean strategy.

Suggested Citation

  • Lee, Junyoung & Kim, Sunghoon & Kim, Yong Tae & Kwak, Geunjae & Kim, Jiyong, 2020. "Full carbon upcycling of landfill gas into methanol by integrating CO2 hydrogenation and methane reforming: Process development and techno-economic analysis," Energy, Elsevier, vol. 199(C).
    • Handle: RePEc:eee:energy:v:199:y:2020:i:c:s0360544220305442
    DOI: 10.1016/j.energy.2020.117437
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544220305442
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2020.117437?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Yi, Qun & Gong, Min-Hui & Huang, Yi & Feng, Jie & Hao, Yan-Hong & Zhang, Ji-Long & Li, Wen-Ying, 2016. "Process development of coke oven gas to methanol integrated with CO2 recycle for satisfactory techno-economic performance," Energy, Elsevier, vol. 112(C), pages 618-628.
    2. Man, Yi & Yang, Siyu & Zhang, Jun & Qian, Yu, 2014. "Conceptual design of coke-oven gas assisted coal to olefins process for high energy efficiency and low CO2 emission," Applied Energy, Elsevier, vol. 133(C), pages 197-205.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Xie, Xuanlan & Li, Chang & Lu, Zhiheng & Wang, Yishuang & Yang, Wenqiang & Chen, Mingqiang & Li, Wenzhi, 2024. "Noble metal modified copper-exchanged mordenite zeolite (Cu-ex-MOR) catalysts for catalyzing the methane efficient gas-phase synthesis methanol," Energy, Elsevier, vol. 300(C).
    2. Do, Thai Ngan & Hur, Young Gul & Chung, Hegwon & Kim, Jiyong, 2023. "Potentials and benefit assessment of green fuels from residue gas via gas-to-liquid," Renewable and Sustainable Energy Reviews, Elsevier, vol. 182(C).
    3. Kwon, Yuree & An, Jinjoo, 2024. "Comparative life cycle assessment of landfill gas utilization in South Korea with parametric uncertainties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 198(C).
    4. Park, Min-Ju & Kim, Hak-Min & Gu, Yun-Jeong & Jeong, Dae-Woon, 2023. "Optimization of biogas-reforming conditions considering carbon formation, hydrogen production, and energy efficiencies," Energy, Elsevier, vol. 265(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yang, Qingchun & Yang, Qing & Xu, Simin & Zhang, Dawei & Liu, Chengling & Zhou, Huairong, 2021. "Optimal design, exergy and economic analyses of coal-to-ethylene glycol process coupling different shale gas reforming technologies," Energy, Elsevier, vol. 228(C).
    2. Chen, Jianjun & Yang, Siyu & Qian, Yu, 2019. "A novel path for carbon-rich resource utilization with lower emission and higher efficiency: An integrated process of coal gasification and coking to methanol production," Energy, Elsevier, vol. 177(C), pages 304-318.
    3. Shin, Sunkyu & Lee, Jeong-Keun & Lee, In-Beum, 2020. "Development and techno-economic study of methanol production from coke-oven gas blended with Linz Donawitz gas," Energy, Elsevier, vol. 200(C).
    4. Yi, Qun & Wu, Guo-sheng & Gong, Min-hui & Huang, Yi & Feng, Jie & Hao, Yan-hong & Li, Wen-ying, 2017. "A feasibility study for CO2 recycle assistance with coke oven gas to synthetic natural gas," Applied Energy, Elsevier, vol. 193(C), pages 149-161.
    5. Ma, Qian & Chang, Yuan & Yuan, Bo & Song, Zhaozheng & Xue, Jinjun & Jiang, Qingzhe, 2022. "Utilizing carbon dioxide from refinery flue gas for methanol production: System design and assessment," Energy, Elsevier, vol. 249(C).
    6. Zhou, Huairong & Li, Hongwei & Duan, Runhao & Yang, Qingchun, 2020. "An integrated scheme of coal-assisted oil shale efficient pyrolysis and high-value conversion of pyrolysis oil," Energy, Elsevier, vol. 196(C).
    7. Yaser Khojasteh Salkuyeh & Thomas A. Adams II, 2015. "Co-Production of Olefins, Fuels, and Electricity from Conventional Pipeline Gas and Shale Gas with Near-Zero CO 2 Emissions. Part I: Process Development and Technical Performance," Energies, MDPI, vol. 8(5), pages 1-23, April.
    8. Yi, Qun & Gong, Min-Hui & Huang, Yi & Feng, Jie & Hao, Yan-Hong & Zhang, Ji-Long & Li, Wen-Ying, 2016. "Process development of coke oven gas to methanol integrated with CO2 recycle for satisfactory techno-economic performance," Energy, Elsevier, vol. 112(C), pages 618-628.
    9. Park, Hoyoung & Byun, Jaewon & Han, Jeehoon, 2021. "Economically feasible thermochemical process for methanol production from kenaf," Energy, Elsevier, vol. 230(C).
    10. Huang, Yi & Yi, Qun & Wei, Guo-qiang & Kang, Jing-xian & Li, Wen-ying & Feng, Jie & Xie, Ke-chang, 2018. "Energy use, greenhouse gases emission and cost effectiveness of an integrated high– and low–temperature Fisher–Tropsch synthesis plant from a lifecycle viewpoint," Applied Energy, Elsevier, vol. 228(C), pages 1009-1019.
    11. Michael Bampaou & Kyriakos Panopoulos & Panos Seferlis & Amaia Sasiain & Stephane Haag & Philipp Wolf-Zoellner & Markus Lehner & Leokadia Rog & Przemyslaw Rompalski & Sebastian Kolb & Nina Kieberger &, 2022. "Economic Evaluation of Renewable Hydrogen Integration into Steelworks for the Production of Methanol and Methane," Energies, MDPI, vol. 15(13), pages 1-26, June.
    12. Xiang, Dong & Jin, Tong & Lei, Xinru & Liu, Shuai & Jiang, Yong & Dong, Zhongbing & Tao, Quanbao & Cao, Yan, 2018. "The high efficient synthesis of natural gas from a joint-feedstock of coke-oven gas and pulverized coke via a chemical looping combustion scheme," Applied Energy, Elsevier, vol. 212(C), pages 944-954.
    13. Uribe-Soto, Wilmar & Portha, Jean-François & Commenge, Jean-Marc & Falk, Laurent, 2017. "A review of thermochemical processes and technologies to use steelworks off-gases," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 809-823.
    14. Qin, Shiyue & Chang, Shiyan, 2017. "Modeling, thermodynamic and techno-economic analysis of coke production process with waste heat recovery," Energy, Elsevier, vol. 141(C), pages 435-450.
    15. Liu, Shuoshi & Yang, Lu & Chen, Bokun & Yang, Siyu & Qian, Yu, 2021. "Comprehensive energy analysis and integration of coal-based MTO process," Energy, Elsevier, vol. 214(C).
    16. Lee, Boreum & Kim, Hyunwoo & Lee, Hyunjun & Byun, Manhee & Won, Wangyun & Lim, Hankwon, 2020. "Technical and economic feasibility under uncertainty for methane dry reforming of coke oven gas as simultaneous H2 production and CO2 utilization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 133(C).
    17. Bampaou, M. & Haag, S. & Kyriakides, A.-S. & Panopoulos, K.D. & Seferlis, P., 2023. "Optimizing methanol synthesis combining steelworks off-gases and renewable hydrogen," Renewable and Sustainable Energy Reviews, Elsevier, vol. 171(C).
    18. Lei, Yang & Chen, Yuming & Chen, Jinghai & Liu, Xinyan & Wu, Xiaoqin & Chen, Yuqiu, 2023. "A novel modeling strategy for the prediction on the concentration of H2 and CH4 in raw coke oven gas," Energy, Elsevier, vol. 273(C).
    19. Zhan, Honglei & Zhao, Kun & Xiao, Lizhi, 2015. "Spectral characterization of the key parameters and elements in coal using terahertz spectroscopy," Energy, Elsevier, vol. 93(P1), pages 1140-1145.
    20. Yang, Qingchun & Xu, Simin & Zhang, Jinliang & Liu, Chenglin & Zhang, Dawei & Zhou, Huairong & Mei, Shumei & Gao, Minglin & Liu, Hongyan, 2021. "Thermodynamic and techno-economic analyses of a novel integrated process of coal gasification and methane tri-reforming to ethylene glycol with low carbon emission and high efficiency," Energy, Elsevier, vol. 229(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:199:y:2020:i:c:s0360544220305442. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.