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Catalyzed pyrolysis of SRC poplar biomass. Alkaline carbonates and zeolites catalysts

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  • Soares Dias, Ana Paula
  • Rego, Filipe
  • Fonseca, Frederico
  • Casquilho, Miguel
  • Rosa, Fátima
  • Rodrigues, Abel

Abstract

Poplar biomass of nine different genotypes, from short rotation coppice, was pyrolyzed in a fixed bed reactor using several solid catalysts. Pine bark was used as reference for uncatalyzed pyrolysis. Pyrolysis tests were performed for temperatures in the range 425–500 °C, selected from the thermal degradation profiles obtained by thermogravimetry under N2 flow. All the analyzed poplar genotypes showed similar pyrolysis behavior, with the highest bio-oil yield (53% average value) being obtained for the highest tested temperature (500 °C). In analogous conditions, the pine bark resulted in higher bio-char yields than poplar biomass, due to its larger lignin content.

Suggested Citation

  • Soares Dias, Ana Paula & Rego, Filipe & Fonseca, Frederico & Casquilho, Miguel & Rosa, Fátima & Rodrigues, Abel, 2019. "Catalyzed pyrolysis of SRC poplar biomass. Alkaline carbonates and zeolites catalysts," Energy, Elsevier, vol. 183(C), pages 1114-1122.
    • Handle: RePEc:eee:energy:v:183:y:2019:i:c:p:1114-1122
    DOI: 10.1016/j.energy.2019.07.009
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    Cited by:

    1. Rego, Filipe & Soares Dias, Ana P. & Casquilho, Miguel & Rosa, Fátima C. & Rodrigues, Abel, 2020. "Pyrolysis kinetics of short rotation coppice poplar biomass," Energy, Elsevier, vol. 207(C).
    2. Rijo, Bruna & Soares Dias, Ana Paula & Ramos, Marta & Ameixa, Marcelo, 2022. "Valorization of forest waste biomass by catalyzed pyrolysis," Energy, Elsevier, vol. 243(C).
    3. Fonseca, Frederico G. & Soares Dias, Ana P., 2021. "Almond shells: Catalytic fixed-bed pyrolysis and volatilization kinetics," Renewable Energy, Elsevier, vol. 180(C), pages 1380-1390.
    4. Mariana Abreu & Luís Silva & Belina Ribeiro & Alice Ferreira & Luís Alves & Susana M. Paixão & Luísa Gouveia & Patrícia Moura & Florbela Carvalheiro & Luís C. Duarte & Ana Luisa Fernando & Alberto Rei, 2022. "Low Indirect Land Use Change (ILUC) Energy Crops to Bioenergy and Biofuels—A Review," Energies, MDPI, vol. 15(12), pages 1-68, June.
    5. Rijo, Bruna & Soares Dias, Ana Paula & Ramos, Marta & de Jesus, Nicole & Puna, Jaime, 2021. "Catalyzed pyrolysis of coffee and tea wastes," Energy, Elsevier, vol. 235(C).

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