IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v166y2019icp541-551.html
   My bibliography  Save this article

Hydrogen-rich syngas production by reforming of ethanol blended with aqueous urea using a thermodynamic analysis

Author

Listed:
  • Wu, Horng-Wen
  • Lin, Ke-Wei

Abstract

This study presents a new concept of the aqueous urea solution (AUS) to replace pure water and uses a thermodynamic analysis to compare the characteristics of steam and autothermal reforming of ethanol with/without AUS. The results show that hydrogen-rich syngas production under steam reforming of ethanol (SRE) with the blended AUS is higher than that under the pure steam. Under autothermal reforming of ethanol (ATRE), syngas yield increases with an increase in urea, and the thermal neutral temperature (TNT) can be adjusted through the amount of AUS because of the endothermic role of urea in the overall reaction. The best operating condition of ATRE is the H2O/EtOH equal to 5 and the O2/EtOH equal to 1.2 at 800 °C, and the reforming efficiency of ethanol with the AUS reaches 93.17% much higher than that without the AUS. The present results are also verified by an experiment and indicate that the use of AUS as a reactant to replace pure steam in ethanol reforming can increase both syngas yield.

Suggested Citation

  • Wu, Horng-Wen & Lin, Ke-Wei, 2019. "Hydrogen-rich syngas production by reforming of ethanol blended with aqueous urea using a thermodynamic analysis," Energy, Elsevier, vol. 166(C), pages 541-551.
    • Handle: RePEc:eee:energy:v:166:y:2019:i:c:p:541-551
    DOI: 10.1016/j.energy.2018.10.122
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544218321121
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2018.10.122?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Lee, Jun Sung & Han, Gi Bo & Kang, Misook, 2012. "Low temperature steam reforming of ethanol for carbon monoxide-free hydrogen production over mesoporous Sn-incorporated SBA-15 catalysts," Energy, Elsevier, vol. 44(1), pages 248-256.
    2. Baruah, Renika & Dixit, Marm & Basarkar, Pratik & Parikh, Dhrupad & Bhargav, Atul, 2015. "Advances in ethanol autothermal reforming," Renewable and Sustainable Energy Reviews, Elsevier, vol. 51(C), pages 1345-1353.
    3. Tippawan, Phanicha & Im-orb, Karittha & Arpornwichanop, Amornchai, 2017. "Efficient heat allocation in the two-step ethanol steam reforming and solid oxide fuel cell integrated process," Energy, Elsevier, vol. 133(C), pages 545-556.
    4. Alrazen, Hayder A. & Abu Talib, A.R. & Adnan, R. & Ahmad, K.A., 2016. "A review of the effect of hydrogen addition on the performance and emissions of the compression – Ignition engine," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 785-796.
    5. Zabed, H. & Sahu, J.N. & Suely, A. & Boyce, A.N. & Faruq, G., 2017. "Bioethanol production from renewable sources: Current perspectives and technological progress," Renewable and Sustainable Energy Reviews, Elsevier, vol. 71(C), pages 475-501.
    6. de Ávila, C.N. & Hori, C.E. & de Assis, A.J., 2011. "Thermodynamic assessment of hydrogen production and cobalt oxidation susceptibility under ethanol reforming conditions," Energy, Elsevier, vol. 36(7), pages 4385-4395.
    7. Mazloomi, Kaveh & Gomes, Chandima, 2012. "Hydrogen as an energy carrier: Prospects and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 3024-3033.
    8. Oliveira, V.B. & Pereira, J.P. & Pinto, A.M.F.R., 2017. "Modeling of passive direct ethanol fuel cells," Energy, Elsevier, vol. 133(C), pages 652-665.
    9. Manochio, C. & Andrade, B.R. & Rodriguez, R.P. & Moraes, B.S., 2017. "Ethanol from biomass: A comparative overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 743-755.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Xin, Yanbin & Sun, Bing & Zhu, Xiaomei & Yan, Zhiyu & Sun, Xiaohang, 2021. "Hydrogen-rich syngas production by liquid phase pulsed electrodeless discharge," Energy, Elsevier, vol. 214(C).
    2. Siang, T.J. & Jalil, A.A. & Abdulrasheed, A.A. & Hambali, H.U. & Nabgan, Walid, 2020. "Thermodynamic equilibrium study of altering methane partial oxidation for Fischer–Tropsch synfuel production," Energy, Elsevier, vol. 198(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Nariê Rinke Dias de Souza & Bruno Colling Klein & Mateus Ferreira Chagas & Otavio Cavalett & Antonio Bonomi, 2021. "Towards Comparable Carbon Credits: Harmonization of LCA Models of Cellulosic Biofuels," Sustainability, MDPI, vol. 13(18), pages 1-17, September.
    2. Rita H. R. Branco & Mariana S. T. Amândio & Luísa S. Serafim & Ana M. R. B. Xavier, 2020. "Ethanol Production from Hydrolyzed Kraft Pulp by Mono- and Co-Cultures of Yeasts: The Challenge of C6 and C5 Sugars Consumption," Energies, MDPI, vol. 13(3), pages 1-15, February.
    3. Jain, Sanyam & Kumar, Shushil, 2024. "A comprehensive review of bioethanol production from diverse feedstocks: Current advancements and economic perspectives," Energy, Elsevier, vol. 296(C).
    4. Burton, N.A. & Padilla, R.V. & Rose, A. & Habibullah, H., 2021. "Increasing the efficiency of hydrogen production from solar powered water electrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    5. Lee, Boreum & Park, Junhyung & Lee, Hyunjun & Byun, Manhee & Yoon, Chang Won & Lim, Hankwon, 2019. "Assessment of the economic potential: COx-free hydrogen production from renewables via ammonia decomposition for small-sized H2 refueling stations," Renewable and Sustainable Energy Reviews, Elsevier, vol. 113(C), pages 1-1.
    6. Navas-Anguita, Zaira & García-Gusano, Diego & Iribarren, Diego, 2019. "A review of techno-economic data for road transportation fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 112(C), pages 11-26.
    7. Dixon, Christopher & Reynolds, Steve & Rodley, David, 2016. "Micro/small wind turbine power control for electrolysis applications," Renewable Energy, Elsevier, vol. 87(P1), pages 182-192.
    8. Fukunaga, Akihiko & Kato, Asami & Hara, Yuki & Matsumoto, Takaya, 2023. "Dehydrogenation of methylcyclohexane using solid oxide fuel cell – A smart energy conversion," Applied Energy, Elsevier, vol. 348(C).
    9. Hosseini, Mir Ghasem & Mahmoodi, Raana & Daneshvari-Esfahlan, Vahid, 2018. "Ni@Pd core-shell nanostructure supported on multi-walled carbon nanotubes as efficient anode nanocatalysts for direct methanol fuel cells with membrane electrode assembly prepared by catalyst coated m," Energy, Elsevier, vol. 161(C), pages 1074-1084.
    10. Serrano, J. & Jiménez-Espadafor, F.J. & López, A., 2019. "Analysis of the effect of the hydrogen as main fuel on the performance of a modified compression ignition engine with water injection," Energy, Elsevier, vol. 173(C), pages 911-925.
    11. Andrade Díaz, Christhel & Albers, Ariane & Zamora-Ledezma, Ezequiel & Hamelin, Lorie, 2024. "The interplay between bioeconomy and the maintenance of long-term soil organic carbon stock in agricultural soils: A systematic review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PA).
    12. Sahu, Omprakash, 2021. "Appropriateness of rose (Rosa hybrida) for bioethanol conversion with enzymatic hydrolysis: Sustainable development on green fuel production," Energy, Elsevier, vol. 232(C).
    13. Michail Cheliotis & Evangelos Boulougouris & Nikoletta L Trivyza & Gerasimos Theotokatos & George Livanos & George Mantalos & Athanasios Stubos & Emmanuel Stamatakis & Alexandros Venetsanos, 2021. "Review on the Safe Use of Ammonia Fuel Cells in the Maritime Industry," Energies, MDPI, vol. 14(11), pages 1-20, May.
    14. Muhammad Aziz, 2021. "Liquid Hydrogen: A Review on Liquefaction, Storage, Transportation, and Safety," Energies, MDPI, vol. 14(18), pages 1-29, September.
    15. Lin, Boqiang & Xu, Bin, 2018. "How to promote the growth of new energy industry at different stages?," Energy Policy, Elsevier, vol. 118(C), pages 390-403.
    16. Bechara, Rami & Gomez, Adrien & Saint-Antonin, Valérie & Schweitzer, Jean-Marc & Maréchal, François & Ensinas, Adriano, 2018. "Review of design works for the conversion of sugarcane to first and second-generation ethanol and electricity," Renewable and Sustainable Energy Reviews, Elsevier, vol. 91(C), pages 152-164.
    17. Ye, Yang & Yue, Yi & Lu, Jianfeng & Ding, Jing & Wang, Weilong & Yan, Jinyue, 2021. "Enhanced hydrogen storage of a LaNi5 based reactor by using phase change materials," Renewable Energy, Elsevier, vol. 180(C), pages 734-743.
    18. Ghadge, Abhijeet & van der Werf, Sjoerd & Er Kara, Merve & Goswami, Mohit & Kumar, Pankaj & Bourlakis, Michael, 2020. "Modelling the impact of climate change risk on bioethanol supply chains," Technological Forecasting and Social Change, Elsevier, vol. 160(C).
    19. Ye, Yang & Ding, Jing & Wang, Weilong & Yan, Jinyue, 2021. "The storage performance of metal hydride hydrogen storage tanks with reaction heat recovery by phase change materials," Applied Energy, Elsevier, vol. 299(C).
    20. Rimkus, Alfredas & Matijošius, Jonas & Bogdevičius, Marijonas & Bereczky, Ákos & Török, Ádám, 2018. "An investigation of the efficiency of using O2 and H2 (hydrooxile gas -HHO) gas additives in a ci engine operating on diesel fuel and biodiesel," Energy, Elsevier, vol. 152(C), pages 640-651.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:166:y:2019:i:c:p:541-551. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.