IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v158y2018icp111-120.html
   My bibliography  Save this article

Process intensification of the transesterification of palm oil to biodiesel in a batch agitated vessel provided with mesh screen extended baffles

Author

Listed:
  • Metawea, Rodaina
  • Zewail, Taghreed
  • El-Ashtoukhy, El-Sayed
  • El Gheriany, Iman
  • Hamad, Hesham

Abstract

One of the major challenges in the production of biodiesel is the immiscibility of oil and methanol. The extent of dispersion between the two phases controls the mass and heat transfer rates and consequently the rate of the transesterification reaction. In this study, we report a novel design of a batch agitated vessel used for the production of biodiesel from palm oil. The new reactor is provided with static stainless steel mesh screen baffles to promote dispersion between the two immiscible reactants. The effect of the key parameters was investigated. The reaction yield was expressed in terms of FAME (fatty acid methyl ester) concentration. The optimum transesterification reaction conditions that yielded the highest biodiesel yield (97%) were as follows: methanol to oil molar ratio of 6:1, a reaction temperature of 60 °C, a one percent (wt.%) NaOH solution, a mesh screen size of 12″ and an agitation speed of 250 rpm. In order to test whether the produced biodiesel can replace diesel oil in combustion engines we evaluated the biodiesel quality, the engine performance and the emission characteristics of a B20 (20% biodiesel and 80% petroleum diesel) blend. A reduction in carbon monoxide and a marginal increase in nitrogen oxides emissions was observed.

Suggested Citation

  • Metawea, Rodaina & Zewail, Taghreed & El-Ashtoukhy, El-Sayed & El Gheriany, Iman & Hamad, Hesham, 2018. "Process intensification of the transesterification of palm oil to biodiesel in a batch agitated vessel provided with mesh screen extended baffles," Energy, Elsevier, vol. 158(C), pages 111-120.
    • Handle: RePEc:eee:energy:v:158:y:2018:i:c:p:111-120
    DOI: 10.1016/j.energy.2018.06.007
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544218310600
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2018.06.007?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Ndayishimiye, Pascal & Tazerout, Mohand, 2011. "Use of palm oil-based biofuel in the internal combustion engines: Performance and emissions characteristics," Energy, Elsevier, vol. 36(3), pages 1790-1796.
    2. Szabados, György & Bereczky, Ákos, 2018. "Experimental investigation of physicochemical properties of diesel, biodiesel and TBK-biodiesel fuels and combustion and emission analysis in CI internal combustion engine," Renewable Energy, Elsevier, vol. 121(C), pages 568-578.
    3. Tran, Dang-Thuan & Chang, Jo-Shu & Lee, Duu-Jong, 2017. "Recent insights into continuous-flow biodiesel production via catalytic and non-catalytic transesterification processes," Applied Energy, Elsevier, vol. 185(P1), pages 376-409.
    4. Sharon, H. & Karuppasamy, K. & Soban Kumar, D.R. & Sundaresan, A., 2012. "A test on DI diesel engine fueled with methyl esters of used palm oil," Renewable Energy, Elsevier, vol. 47(C), pages 160-166.
    5. Cui, Yi & Liang, Yanna, 2014. "Direct transesterification of wet Cryptococcus curvatus cells to biodiesel through use of microwave irradiation," Applied Energy, Elsevier, vol. 119(C), pages 438-444.
    6. Alptekin, Ertan & Canakci, Mustafa, 2008. "Determination of the density and the viscosities of biodiesel–diesel fuel blends," Renewable Energy, Elsevier, vol. 33(12), pages 2623-2630.
    7. Issariyakul, Titipong & Dalai, Ajay K., 2014. "Biodiesel from vegetable oils," Renewable and Sustainable Energy Reviews, Elsevier, vol. 31(C), pages 446-471.
    8. Li, Bowen & Li, Yanfei & Liu, Haoye & Liu, Fang & Wang, Zhi & Wang, Jianxin, 2017. "Combustion and emission characteristics of diesel engine fueled with biodiesel/PODE blends," Applied Energy, Elsevier, vol. 206(C), pages 425-431.
    9. Budžaki, Sandra & Miljić, Goran & Tišma, Marina & Sundaram, Smitha & Hessel, Volker, 2017. "Is there a future for enzymatic biodiesel industrial production in microreactors?," Applied Energy, Elsevier, vol. 201(C), pages 124-134.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Abukhadra, Mostafa R. & Salam, Mohamed Abdel & Ibrahim, Sherouk M., 2019. "Insight into the catalytic conversion of palm oil into biodiesel using Na+/K+ trapped muscovite/phillipsite composite as a novel catalyst: Effect of ultrasonic irradiation and mechanism," Renewable and Sustainable Energy Reviews, Elsevier, vol. 115(C).
    2. Wongwuttanasatian, Tanakorn & Jookjantra, Kittichai, 2020. "Effect of dual-frequency pulsed ultrasonic excitation and catalyst size for biodiesel production," Renewable Energy, Elsevier, vol. 152(C), pages 1220-1226.
    3. Vargas, Edgar M. & Ospina, Lizeth & Neves, Márcia C. & Tarelho, Luís A.C. & Nunes, Maria I., 2021. "Optimization of FAME production from blends of waste cooking oil and refined palm oil using biomass fly ash as a catalyst," Renewable Energy, Elsevier, vol. 163(C), pages 1637-1647.
    4. Gourich, Wail & Chan, Eng-Seng & Ng, Wei Zhe & Obon, Aaron Anthony & Maran, Kireshwen & Ong, Yi Hui & Lee, Chin Loong & Tan, Jully & Song, Cher Pin, 2022. "Life cycle benefits of enzymatic biodiesel co-produced in palm oil mills from sludge palm oil as renewable fuel for rural electrification," Applied Energy, Elsevier, vol. 325(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Arbab, M.I. & Masjuki, H.H. & Varman, M. & Kalam, M.A. & Imtenan, S. & Sajjad, H., 2013. "Fuel properties, engine performance and emission characteristic of common biodiesels as a renewable and sustainable source of fuel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 22(C), pages 133-147.
    2. Sanjid, A. & Masjuki, H.H. & Kalam, M.A. & Rahman, S.M. Ashrafur & Abedin, M.J. & Palash, S.M., 2013. "Impact of palm, mustard, waste cooking oil and Calophyllum inophyllum biofuels on performance and emission of CI engine," Renewable and Sustainable Energy Reviews, Elsevier, vol. 27(C), pages 664-682.
    3. Varun, & Singh, Paramvir & Tiwari, Samaresh Kumar & Singh, Rituparn & Kumar, Naresh, 2017. "Modification in combustion chamber geometry of CI engines for suitability of biodiesel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1016-1033.
    4. Hashemzadeh Gargari, M. & Sadrameli, S.M., 2018. "Investigating continuous biodiesel production from linseed oil in the presence of a Co-solvent and a heterogeneous based catalyst in a packed bed reactor," Energy, Elsevier, vol. 148(C), pages 888-895.
    5. Palash, S.M. & Kalam, M.A. & Masjuki, H.H. & Masum, B.M. & Rizwanul Fattah, I.M. & Mofijur, M., 2013. "Impacts of biodiesel combustion on NOx emissions and their reduction approaches," Renewable and Sustainable Energy Reviews, Elsevier, vol. 23(C), pages 473-490.
    6. Sidhu, Manpreet Singh & Roy, Murari Mohon & Wang, Wilson, 2018. "Glycerine emulsions of diesel-biodiesel blends and their performance and emissions in a diesel engine," Applied Energy, Elsevier, vol. 230(C), pages 148-159.
    7. Onumaegbu, C. & Alaswad, A. & Rodriguez, C. & Olabi, A., 2019. "Modelling and optimization of wet microalgae Scenedesmus quadricauda lipid extraction using microwave pre-treatment method and response surface methodology," Renewable Energy, Elsevier, vol. 132(C), pages 1323-1331.
    8. Tamošiūnas, Andrius & Gimžauskaitė, Dovilė & Uscila, Rolandas & Aikas, Mindaugas, 2019. "Thermal arc plasma gasification of waste glycerol to syngas," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    9. Živković, Snežana B. & Veljković, Milan V. & Banković-Ilić, Ivana B. & Krstić, Ivan M. & Konstantinović, Sandra S. & Ilić, Slavica B. & Avramović, Jelena M. & Stamenković, Olivera S. & Veljković, Vlad, 2017. "Technological, technical, economic, environmental, social, human health risk, toxicological and policy considerations of biodiesel production and use," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 222-247.
    10. Eiadtrong, Suppakit & Maliwan, Kittinan & Prateepchaikul, Gumpon & Kattiyawan, Taweesak & Thephsorn, Pongsakorns & Leevijit, Theerayut, 2019. "Preparation, important fuel properties, and comparative use of un-preheated palm fatty acid distillate-diesel blends in a single cylinder diesel engine," Renewable Energy, Elsevier, vol. 134(C), pages 1089-1098.
    11. Tamilselvan, P. & Nallusamy, N. & Rajkumar, S., 2017. "A comprehensive review on performance, combustion and emission characteristics of biodiesel fuelled diesel engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1134-1159.
    12. Budžaki, Sandra & Miljić, Goran & Tišma, Marina & Sundaram, Smitha & Hessel, Volker, 2017. "Is there a future for enzymatic biodiesel industrial production in microreactors?," Applied Energy, Elsevier, vol. 201(C), pages 124-134.
    13. Ali, Obed M. & Mamat, Rizalman & Abdullah, Nik R. & Abdullah, Abdul Adam, 2016. "Analysis of blended fuel properties and engine performance with palm biodiesel–diesel blended fuel," Renewable Energy, Elsevier, vol. 86(C), pages 59-67.
    14. Li, Yu & Li, Hailin & Guo, Hongsheng & Wang, Hu & Yao, Mingfa, 2018. "A numerical study on the chemical kinetics process during auto-ignition of n-heptane in a direct injection compression ignition engine," Applied Energy, Elsevier, vol. 212(C), pages 909-918.
    15. Md Modassir Khan & Arun Kumar Kadian & Rabindra Prasad Sharma & S M Mozammil Hasnain & Ahmed Mohamed & Adham E. Ragab & Ali Zare & Shatrudhan Pandey, 2023. "Emission Reduction and Performance Enhancement of CI Engine Propelled by Neem Biodiesel-Neem Oil-Decanol-Diesel Blends at High Injection Pressure," Sustainability, MDPI, vol. 15(11), pages 1-18, June.
    16. Holmatov, B. & Hoekstra, A.Y. & Krol, M.S., 2019. "Land, water and carbon footprints of circular bioenergy production systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 111(C), pages 224-235.
    17. Suiuay, Chokchai & Laloon, Kittipong & Katekaew, Somporn & Senawong, Kritsadang & Noisuwan, Phakamat & Sudajan, Somposh, 2020. "Effect of gasoline-like fuel obtained from hard-resin of Yang (Dipterocarpus alatus) on single cylinder gasoline engine performance and exhaust emissions," Renewable Energy, Elsevier, vol. 153(C), pages 634-645.
    18. E, Jiaqiang & Pham, MinhHieu & Deng, Yuanwang & Nguyen, Tuannghia & Duy, VinhNguyen & Le, DucHieu & Zuo, Wei & Peng, Qingguo & Zhang, Zhiqing, 2018. "Effects of injection timing and injection pressure on performance and exhaust emissions of a common rail diesel engine fueled by various concentrations of fish-oil biodiesel blends," Energy, Elsevier, vol. 149(C), pages 979-989.
    19. Zhang, Ping & Zhuo, La & Li, Meng & Liu, Yilin & Wu, Pute, 2023. "Assessment of advanced bioethanol potential under water and land resource constraints in China," Renewable Energy, Elsevier, vol. 212(C), pages 359-371.
    20. Mohammad Anwar & Mohammad G. Rasul & Nanjappa Ashwath & Md Mofijur Rahman, 2018. "Optimisation of Second-Generation Biodiesel Production from Australian Native Stone Fruit Oil Using Response Surface Method," Energies, MDPI, vol. 11(10), pages 1-18, September.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:158:y:2018:i:c:p:111-120. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.