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Low temperature optimization of biodiesel production from algal oil using CaO and CaO/Al2O3 as catalyst by the application of response surface methodology

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  • Narula, Vishal
  • Khan, Mohd. Fazil
  • Negi, Ankit
  • Kalra, Shashvat
  • Thakur, Aman
  • Jain, Siddharth

Abstract

With the swelling of climatic and environmental hazards, Biodiesel is playing the most potential and significant role as the sustainable source of energy. As a substitute for diesel, biodiesel has been getting the attention of researchers/scientists of all over the world. The R & D have indicated sustainability of biodiesel production from non-edible oil sources such as Jatropha and algal oil. The objective of the present study was to optimize the process parameters for the transesterification of algal oil using CaO and 80% wt. CaO.Al2O3 as catalysts. A low temperature transesterification process was selected. A biodiesel yield of 88.89% was achieved with methanol/oil volumetric ratio (3.2:10) using 80% wt. CaO.Al2O3 as catalyst (1.56% w/w) in 125 min time at 50 °C temperature using Response Surface Methodology. It was observed that catalyst concentration, reaction time and methanol/oil volumetric ratio had a significant effect on yield. Also, this model involving heterogeneous catalyst can be used in the industry for efficient biodiesel production from algal oil, thereby saving time and cost of the process in optimizing the process parameters.

Suggested Citation

  • Narula, Vishal & Khan, Mohd. Fazil & Negi, Ankit & Kalra, Shashvat & Thakur, Aman & Jain, Siddharth, 2017. "Low temperature optimization of biodiesel production from algal oil using CaO and CaO/Al2O3 as catalyst by the application of response surface methodology," Energy, Elsevier, vol. 140(P1), pages 879-884.
    • Handle: RePEc:eee:energy:v:140:y:2017:i:p1:p:879-884
    DOI: 10.1016/j.energy.2017.09.028
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    References listed on IDEAS

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    1. Rizwan, Muhammad & Lee, Jay H. & Gani, Rafiqul, 2015. "Optimal design of microalgae-based biorefinery: Economics, opportunities and challenges," Applied Energy, Elsevier, vol. 150(C), pages 69-79.
    2. Narula, Vishal & Thakur, Aman & Uniyal, Ankit & Kalra, Shashvat & Jain, Siddharth, 2017. "Process parameter optimization of low temperature transesterification of algae-Jatropha Curcas oil blend," Energy, Elsevier, vol. 119(C), pages 983-988.
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    Cited by:

    1. Abukhadra, Mostafa R. & Salam, Mohamed Abdel & Ibrahim, Sherouk M., 2019. "Insight into the catalytic conversion of palm oil into biodiesel using Na+/K+ trapped muscovite/phillipsite composite as a novel catalyst: Effect of ultrasonic irradiation and mechanism," Renewable and Sustainable Energy Reviews, Elsevier, vol. 115(C).
    2. Ahmad, Shamshad & Chaudhary, Shalini & Pathak, Vinayak V. & Kothari, Richa & Tyagi, V.V., 2020. "Optimization of direct transesterification of Chlorella pyrenoidosa catalyzed by waste egg shell based heterogenous nano – CaO catalyst," Renewable Energy, Elsevier, vol. 160(C), pages 86-97.
    3. P. Sujin & P. M. Diaz & Ajith J. Kings & L. R. Monisha Miriam, 2023. "Sustainable biodiesel production from Ceiba penandra, Mahua longifolia, and Azadirachta indica using CaO-TiO2 nano catalyst," Energy & Environment, , vol. 34(3), pages 640-662, May.
    4. Alvarez Serafini, Mariana S. & Reinoso, Deborath M. & Tonetto, Gabriela M., 2018. "Response surface study and kinetic modelling of biodiesel synthesis catalyzed by zinc stearate," Energy, Elsevier, vol. 164(C), pages 264-274.
    5. Chukwuma Onumaegbu & Abed Alaswad & Cristina Rodriguez & Abdul G. Olabi, 2018. "Optimization of Pre-Treatment Process Parameters to Generate Biodiesel from Microalga," Energies, MDPI, vol. 11(4), pages 1-16, March.
    6. Violeta Makareviciene & Egle Sendzikiene, 2022. "Application of Microalgae Biomass for Biodiesel Fuel Production," Energies, MDPI, vol. 15(11), pages 1-33, June.

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