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Ultra high temperature latent heat energy storage and thermophotovoltaic energy conversion

Author

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  • Datas, Alejandro
  • Ramos, Alba
  • Martí, Antonio
  • del Cañizo, Carlos
  • Luque, Antonio

Abstract

A conceptual energy storage system design that utilizes ultra high temperature phase change materials is presented. In this system, the energy is stored in the form of latent heat and converted to electricity upon demand by TPV (thermophotovoltaic) cells. Silicon is considered in this study as PCM (phase change material) due to its extremely high latent heat (1800 J/g or 500 Wh/kg), melting point (1410 °C), thermal conductivity (∼25 W/mK), low cost (less than $2/kg or $4/kWh) and abundance on earth. The proposed system enables an enormous thermal energy storage density of ∼1 MWh/m3, which is 10–20 times higher than that of lead-acid batteries, 2–6 times than that of Li-ion batteries and 5–10 times than that of the current state of the art LHTES systems utilized in CSP (concentrated solar power) applications. The discharge efficiency of the system is ultimately determined by the TPV converter, which theoretically can exceed 50%. However, realistic discharge efficiencies utilizing single junction TPV cells are in the range of 20–45%, depending on the semiconductor bandgap and quality, and the photon recycling efficiency. This concept has the potential to achieve output electric energy densities in the range of 200–450 kWhe/m3, which is comparable to the best performing state of the art Lithium-ion batteries.

Suggested Citation

  • Datas, Alejandro & Ramos, Alba & Martí, Antonio & del Cañizo, Carlos & Luque, Antonio, 2016. "Ultra high temperature latent heat energy storage and thermophotovoltaic energy conversion," Energy, Elsevier, vol. 107(C), pages 542-549.
    • Handle: RePEc:eee:energy:v:107:y:2016:i:c:p:542-549
    DOI: 10.1016/j.energy.2016.04.048
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    Cited by:

    1. Datas, A. & Ramos, A. & del Cañizo, C., 2019. "Techno-economic analysis of solar PV power-to-heat-to-power storage and trigeneration in the residential sector," Applied Energy, Elsevier, vol. 256(C).
    2. Fadaei, Niloufar & Kasaeian, Alibakhsh & Akbarzadeh, Aliakbar & Hashemabadi, Seyed Hassan, 2018. "Experimental investigation of solar chimney with phase change material (PCM)," Renewable Energy, Elsevier, vol. 123(C), pages 26-35.
    3. Liang, Tao & Hu, Cong & Fu, Tong & Su, Shanhe & Chen, Jincan, 2022. "The maximum efficiency enhancement of a solar-driven graphene-anode thermionic converter realizing total photon reflection," Energy, Elsevier, vol. 239(PA).
    4. Sakai, Hiroki & Sheng, Nan & Kurniawan, Ade & Akiyama, Tomohiro & Nomura, Takahiro, 2020. "Fabrication of heat storage pellets composed of microencapsulated phase change material for high-temperature applications," Applied Energy, Elsevier, vol. 265(C).
    5. Zeneli, M. & Malgarinos, I. & Nikolopoulos, A. & Nikolopoulos, N. & Grammelis, P. & Karellas, S. & Kakaras, E., 2019. "Numerical simulation of a silicon-based latent heat thermal energy storage system operating at ultra-high temperatures," Applied Energy, Elsevier, vol. 242(C), pages 837-853.
    6. Amy, Caleb & Pishahang, Mehdi & Kelsall, Colin & LaPotin, Alina & Brankovic, Sonja & Yee, Shannon & Henry, Asegun, 2022. "Thermal energy grid storage: Liquid containment and pumping above 2000 °C," Applied Energy, Elsevier, vol. 308(C).
    7. Fangqi Chen & Xiaojie Liu & Yanpei Tian & Jon Goldsby & Yi Zheng, 2022. "Refractory All-Ceramic Thermal Emitter for High-Temperature Near-Field Thermophotovoltaics," Energies, MDPI, vol. 15(5), pages 1-9, March.

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