IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v106y2016icp221-230.html
   My bibliography  Save this article

Effect of N-isopropylacrylamide on the preparation and properties of microencapsulated phase change materials

Author

Listed:
  • Li, Dan
  • Wang, Jianping
  • Wang, Yanan
  • Li, Wei
  • Wang, Xuechen
  • Shi, Haifeng
  • Zhang, Xingxiang

Abstract

NIPAm (N-isopropylacrylamide), a thermosensitive monomer, was introduced into a system for synthesis of MicroPCMs (microencapsulated phase change materials) through free radical emulsion polymerization with n-oct (n-octadecane) as the core and cross-linked PMMA (poly (methyl methacrylate)) as the shell. The effect of NIPAm on the formation mechanism, surface morphologies, crystallization properties, and thermal stabilities of the MicroPCMs were studied using FTIR (Fourier transform infrared spectroscopy), SEM (scanning electron microscopy), DSC (differential scanning calorimetry), and TGA (thermogravimetric analysis), respectively. The results indicate that addition of NIPAm causes a significant increase in the enthalpy of the heterogeneous nucleation (approximately 2–4 times more than without NIPAm). The diameter distribution of microcapsules becomes narrower (the PDI (polydispersity index) has a minimum of 0.073) and the encapsulation ratio and encapsulation efficiency increase. On the contrary, the microcapsules that have some irregular holes were obtained by adding NIPAm prepolymer.

Suggested Citation

  • Li, Dan & Wang, Jianping & Wang, Yanan & Li, Wei & Wang, Xuechen & Shi, Haifeng & Zhang, Xingxiang, 2016. "Effect of N-isopropylacrylamide on the preparation and properties of microencapsulated phase change materials," Energy, Elsevier, vol. 106(C), pages 221-230.
    • Handle: RePEc:eee:energy:v:106:y:2016:i:c:p:221-230
    DOI: 10.1016/j.energy.2016.03.035
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544216302791
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2016.03.035?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Kuznik, Frédéric & David, Damien & Johannes, Kevyn & Roux, Jean-Jacques, 2011. "A review on phase change materials integrated in building walls," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 379-391, January.
    2. SarI, Ahmet & Alkan, Cemil & Karaipekli, Ali, 2010. "Preparation, characterization and thermal properties of PMMA/n-heptadecane microcapsules as novel solid-liquid microPCM for thermal energy storage," Applied Energy, Elsevier, vol. 87(5), pages 1529-1534, May.
    3. Salunkhe, Pramod B. & Shembekar, Prashant S., 2012. "A review on effect of phase change material encapsulation on the thermal performance of a system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(8), pages 5603-5616.
    4. Wang, Lijiu & Meng, Duo, 2010. "Fatty acid eutectic/polymethyl methacrylate composite as form-stable phase change material for thermal energy storage," Applied Energy, Elsevier, vol. 87(8), pages 2660-2665, August.
    5. Cai, Yibing & Wei, Qufu & Huang, Fenglin & Lin, Shiliang & Chen, Fang & Gao, Weidong, 2009. "Thermal stability, latent heat and flame retardant properties of the thermal energy storage phase change materials based on paraffin/high density polyethylene composites," Renewable Energy, Elsevier, vol. 34(10), pages 2117-2123.
    6. Tang, Xiaofen & Li, Wei & Zhang, Xingxiang & Shi, Haifeng, 2014. "Fabrication and characterization of microencapsulated phase change material with low supercooling for thermal energy storage," Energy, Elsevier, vol. 68(C), pages 160-166.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Cao, Rui-rui & Li, Xuan & Chen, Sai & Yuan, Hao-ran & Zhang, Xing-xiang, 2017. "Fabrication and characterization of novel shape-stabilized synergistic phase change materials based on PHDA/GO composites," Energy, Elsevier, vol. 138(C), pages 157-166.
    2. Zhang, Li & Yang, Wenbin & Jiang, Zhuoni & He, Fangfang & Zhang, Kai & Fan, Jinghui & Wu, Juying, 2017. "Graphene oxide-modified microencapsulated phase change materials with high encapsulation capacity and enhanced leakage-prevention performance," Applied Energy, Elsevier, vol. 197(C), pages 354-363.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Giro-Paloma, Jessica & Barreneche, Camila & Martínez, Mònica & Šumiga, Boštjan & Cabeza, Luisa F. & Fernández, A. Inés, 2015. "Comparison of phase change slurries: Physicochemical and thermal properties," Energy, Elsevier, vol. 87(C), pages 223-227.
    2. Giro-Paloma, Jessica & Martínez, Mònica & Cabeza, Luisa F. & Fernández, A. Inés, 2016. "Types, methods, techniques, and applications for microencapsulated phase change materials (MPCM): A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 1059-1075.
    3. Wang, Yi & Xia, Tian Dong & Feng, Hui Xia & Zhang, Han, 2011. "Stearic acid/polymethylmethacrylate composite as form-stable phase change materials for latent heat thermal energy storage," Renewable Energy, Elsevier, vol. 36(6), pages 1814-1820.
    4. He, Fang & Wang, Xiaodong & Wu, Dezhen, 2014. "New approach for sol–gel synthesis of microencapsulated n-octadecane phase change material with silica wall using sodium silicate precursor," Energy, Elsevier, vol. 67(C), pages 223-233.
    5. Jamekhorshid, A. & Sadrameli, S.M. & Farid, M., 2014. "A review of microencapsulation methods of phase change materials (PCMs) as a thermal energy storage (TES) medium," Renewable and Sustainable Energy Reviews, Elsevier, vol. 31(C), pages 531-542.
    6. Amaral, C. & Vicente, R. & Marques, P.A.A.P. & Barros-Timmons, A., 2017. "Phase change materials and carbon nanostructures for thermal energy storage: A literature review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1212-1228.
    7. Kenisarin, Murat M. & Kenisarina, Kamola M., 2012. "Form-stable phase change materials for thermal energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(4), pages 1999-2040.
    8. Meysam Nazari & Mohamed Jebrane & Nasko Terziev, 2020. "Bio-Based Phase Change Materials Incorporated in Lignocellulose Matrix for Energy Storage in Buildings—A Review," Energies, MDPI, vol. 13(12), pages 1-25, June.
    9. Alva, Guruprasad & Huang, Xiang & Liu, Lingkun & Fang, Guiyin, 2017. "Synthesis and characterization of microencapsulated myristic acid–palmitic acid eutectic mixture as phase change material for thermal energy storage," Applied Energy, Elsevier, vol. 203(C), pages 677-685.
    10. Umair, Malik Muhammad & Zhang, Yuang & Iqbal, Kashif & Zhang, Shufen & Tang, Bingtao, 2019. "Novel strategies and supporting materials applied to shape-stabilize organic phase change materials for thermal energy storage–A review," Applied Energy, Elsevier, vol. 235(C), pages 846-873.
    11. Giro-Paloma, Jessica & Barreneche, Camila & Martínez, Mònica & Šumiga, Boštjan & Fernández, Ana Inés & Cabeza, Luisa F., 2016. "Mechanical response evaluation of microcapsules from different slurries," Renewable Energy, Elsevier, vol. 85(C), pages 732-739.
    12. Lashgari, Somayeh & Arabi, Hassan & Mahdavian, Ali Reza & Ambrogi, Veronica, 2017. "Thermal and morphological studies on novel PCM microcapsules containing n-hexadecane as the core in a flexible shell," Applied Energy, Elsevier, vol. 190(C), pages 612-622.
    13. Rathod, Manish K. & Banerjee, Jyotirmay, 2013. "Thermal stability of phase change materials used in latent heat energy storage systems: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 246-258.
    14. Jinghua Yu & Kangxin Leng & Feifei Wang & Hong Ye & Yongqiang Luo, 2020. "Simulation Study on Dynamic Thermal Performance of a New Ventilated Roof with Form-Stable PCM in Southern China," Sustainability, MDPI, vol. 12(22), pages 1-21, November.
    15. Liu, Yang & Zheng, Ruowei & Li, Ji, 2022. "High latent heat phase change materials (PCMs) with low melting temperature for thermal management and storage of electronic devices and power batteries: Critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    16. Chai, Luxiao & Wang, Xiaodong & Wu, Dezhen, 2015. "Development of bifunctional microencapsulated phase change materials with crystalline titanium dioxide shell for latent-heat storage and photocatalytic effectiveness," Applied Energy, Elsevier, vol. 138(C), pages 661-674.
    17. Gao, Wei & Liu, Feifan & Yu, Cheng & Chen, Yongping & Liu, Xiangdong, 2023. "Microfluidic method–based encapsulated phase change materials: Fundamentals, progress, and prospects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 171(C).
    18. Konuklu, Yeliz & Paksoy, Halime O. & Unal, Murat, 2015. "Nanoencapsulation of n-alkanes with poly(styrene-co-ethylacrylate) shells for thermal energy storage," Applied Energy, Elsevier, vol. 150(C), pages 335-340.
    19. Mu, Mulan & Basheer, P.A.M. & Sha, Wei & Bai, Yun & McNally, Tony, 2016. "Shape stabilised phase change materials based on a high melt viscosity HDPE and paraffin waxes," Applied Energy, Elsevier, vol. 162(C), pages 68-82.
    20. Kahwaji, Samer & Johnson, Michel B. & Kheirabadi, Ali C. & Groulx, Dominic & White, Mary Anne, 2016. "Stable, low-cost phase change material for building applications: The eutectic mixture of decanoic acid and tetradecanoic acid," Applied Energy, Elsevier, vol. 168(C), pages 457-464.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:106:y:2016:i:c:p:221-230. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.