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Modeling the pH in the tidal fresh Potomac River under conditions of varying hydrology and loads

Author

Listed:
  • Cerco, Carl F.
  • Threadgill, Tammy
  • Noel, Mark R.
  • Hinz, Scott

Abstract

The pH of the freshwater portion of the Potomac River estuary attains 9–10.5, driven by photosynthesis during cyanobacteria blooms. Processes which contribute to elevated pH are examined by adding a mass-balance model of the carbonate cycle to an existing eutrophication model. Four new variables are added to the model suite: alkalinity, total inorganic carbon, total calcium, and calcium carbonate. The pH is computed from these four quantities via equilibrium kinetics. The model is employed in a continuous simulation of the years 1994–2000. Emphasis in examination of model results is placed on the tidal fresh portion of the system where elevated pH is an environmental concern. Model sensitivity analysis indicates hydrology has the greatest influence on pH. During low-flow periods, residence time is lengthy allowing ample time for algal production to occur. The production stimulates net uptake of TIC, and results in enhanced pH.

Suggested Citation

  • Cerco, Carl F. & Threadgill, Tammy & Noel, Mark R. & Hinz, Scott, 2013. "Modeling the pH in the tidal fresh Potomac River under conditions of varying hydrology and loads," Ecological Modelling, Elsevier, vol. 257(C), pages 101-112.
    • Handle: RePEc:eee:ecomod:v:257:y:2013:i:c:p:101-112
    DOI: 10.1016/j.ecolmodel.2013.02.011
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    References listed on IDEAS

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    1. Cerco, Carl F. & Noel, Mark R., 2010. "Monitoring, modeling, and management impacts of bivalve filter feeders in the oligohaline and tidal fresh regions of the Chesapeake Bay system," Ecological Modelling, Elsevier, vol. 221(7), pages 1054-1064.
    2. Ken Caldeira & Michael E. Wickett, 2003. "Anthropogenic carbon and ocean pH," Nature, Nature, vol. 425(6956), pages 365-365, September.
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