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Experimental assessment of toxic phorbol ester in oil, biodiesel and seed cake of Jatropha curcas and use of biodiesel in diesel engine

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  • Prasad, Lalit
  • Pradhan, Subhalaxmi
  • Das, L.M.
  • Naik, S.N.

Abstract

The present study deals with estimation of toxic phorbol esters in Jatropha curcas oil, cake and biodiesel and performance emission of different blends of biodiesel in diesel engine. The jatropha seed was collected from Chattishgarh, India and oil content of the seed kernel was 56.5%, determined by soxhlet apparatus. The oil was subjected to biodiesel preparation by twin step method of acid esterification followed by alkali transesterification. The total conversion of jatropha oil methyl ester (JOME) after reaction was 96.05% from proton nuclear magnetic resonance (1H NMR) studies. The phorbol esters content of oil, cake and biodiesel was determined by high performance liquid chromatography (HPLC, Waters). The phorbol esters content of the oil was more (2.26±0.01mg/g) than the cake (0.6±0.01mg/g) but no phorbol esters peak was detected in biodiesel. The performance and emission study of the fuel blends (JB2, JB5 and JB10) with conventional diesel were tested for their use as substitute fuel for a single cylinder direct injection diesel engine at constant speed (1500rpm). The emissions such as CO, HC and smoke opacity decreased whereas NOx and BSCF increased with biodiesel blends.

Suggested Citation

  • Prasad, Lalit & Pradhan, Subhalaxmi & Das, L.M. & Naik, S.N., 2012. "Experimental assessment of toxic phorbol ester in oil, biodiesel and seed cake of Jatropha curcas and use of biodiesel in diesel engine," Applied Energy, Elsevier, vol. 93(C), pages 245-250.
    • Handle: RePEc:eee:appene:v:93:y:2012:i:c:p:245-250
    DOI: 10.1016/j.apenergy.2011.11.076
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    References listed on IDEAS

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    1. Atadashi, I.M. & Aroua, M.K. & Aziz, A. Abdul, 2010. "High quality biodiesel and its diesel engine application: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(7), pages 1999-2008, September.
    2. Wang, Rui & Song, Baoan & Zhou, Wanwei & Zhang, Yuping & Hu, Deyu & Bhadury, Pinaki S. & Yang, Song, 2011. "A facile and feasible method to evaluate and control the quality of Jatropha curcus L. seed oil for biodiesel feedstock: Gas chromatographic fingerprint," Applied Energy, Elsevier, vol. 88(6), pages 2064-2070, June.
    3. Agarwal, Avinash Kumar & Rajamanoharan, K., 2009. "Experimental investigations of performance and emissions of Karanja oil and its blends in a single cylinder agricultural diesel engine," Applied Energy, Elsevier, vol. 86(1), pages 106-112, January.
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    2. Gupta, Aditi & Kumar, Ashwani & Sharma, Satyawati & Vijay, V.K., 2013. "Comparative evaluation of raw and detoxified mahua seed cake for biogas production," Applied Energy, Elsevier, vol. 102(C), pages 1514-1521.
    3. Rahman, S.M. Ashrafur & Masjuki, H.H. & Kalam, M.A. & Sanjid, A. & Abedin, M.J., 2014. "Assessment of emission and performance of compression ignition engine with varying injection timing," Renewable and Sustainable Energy Reviews, Elsevier, vol. 35(C), pages 221-230.
    4. Alexander García-Mariaca & Jorge Villalba & Uriel Carreño & Didier Aldana, 2023. "Performance and Emissions of a CI-ICE Fuelled with Jatropha Biodiesel Blends and Economic and Environment Assessment for Power Generation in Non-Interconnected Areas," Energies, MDPI, vol. 16(16), pages 1-16, August.

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