IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v164y2018icp35-45.html
   My bibliography  Save this article

Optimal efficient biodiesel synthesis from used oil employing low-cost ram bone supported Cr catalyst: Engine performance and exhaust assessment

Author

Listed:
  • Pradhan, Piasy
  • Chakraborty, Rajat

Abstract

This article reports the preparation of cost-effective bio-hydroxyapatite (ram bone derived) supported mesoporous Cr heterogeneous catalysts and its performance in biodiesel production from used frying mustard oil (UFMO). The optimal catalyst (98.45 m2/g BET area; pore volume 0.0586 cc/g; modal pore diameter 19.3 nm and 0.78 mmol NH3/g catalyst acid-site concentration) demonstrated remarkable efficacy in sustainable synthesis of biodiesel from UFMO achieving maximum FAME content (96.85%) at optimal (predicted through D-optimal method) conditions: 4 wt% catalyst concentration, 8.0 methanol/UFMO molar ratio and 200 °C calcination temperature for catalyst preparation. Biodiesel production through concurrent transesterification-esterification (CTE) of UFMO could be augmented from 40.22% (conductive heating system) to 96.85% FAME yield using energy-proficient infrared radiation. Promising engine operation was recorded in terms of lower exhaust temperature at various blends of petrodiesel-product biodiesel in comparison with unaided petro-diesel. Assessment of exhaust emissions implied a significantly low CO (0.05%) and hydrocarbon (HC) emissions (<0.00002) for product biodiesel conforming to Euro-VI emission standards. Thus, the article demonstrates an inexpensive and efficient avenue for utilisation of waste resources to generate and utilise clean and renewable energy.

Suggested Citation

  • Pradhan, Piasy & Chakraborty, Rajat, 2018. "Optimal efficient biodiesel synthesis from used oil employing low-cost ram bone supported Cr catalyst: Engine performance and exhaust assessment," Energy, Elsevier, vol. 164(C), pages 35-45.
    • Handle: RePEc:eee:energy:v:164:y:2018:i:c:p:35-45
    DOI: 10.1016/j.energy.2018.08.181
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544218317171
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2018.08.181?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Chakraborty, R. & Sahu, H., 2014. "Intensification of biodiesel production from waste goat tallow using infrared radiation: Process evaluation through response surface methodology and artificial neural network," Applied Energy, Elsevier, vol. 114(C), pages 827-836.
    2. Lin, Yuan-Chung & Hsu, Kuo-Hsiang & Chen, Chung-Bang, 2011. "Experimental investigation of the performance and emissions of a heavy-duty diesel engine fueled with waste cooking oil biodiesel/ultra-low sulfur diesel blends," Energy, Elsevier, vol. 36(1), pages 241-248.
    3. Chen, Kang-Shin & Lin, Yuan-Chung & Hsu, Kuo-Hsiang & Wang, Hsin-Kai, 2012. "Improving biodiesel yields from waste cooking oil by using sodium methoxide and a microwave heating system," Energy, Elsevier, vol. 38(1), pages 151-156.
    4. Prasad, Lalit & Pradhan, Subhalaxmi & Das, L.M. & Naik, S.N., 2012. "Experimental assessment of toxic phorbol ester in oil, biodiesel and seed cake of Jatropha curcas and use of biodiesel in diesel engine," Applied Energy, Elsevier, vol. 93(C), pages 245-250.
    5. Ghobadian, B. & Rahimi, H. & Nikbakht, A.M. & Najafi, G. & Yusaf, T.F., 2009. "Diesel engine performance and exhaust emission analysis using waste cooking biodiesel fuel with an artificial neural network," Renewable Energy, Elsevier, vol. 34(4), pages 976-982.
    6. Ma, Yingqun & Wang, Qunhui & Zheng, Lu & Gao, Zhen & Wang, Qiang & Ma, Yuhui, 2016. "Mixed methanol/ethanol on transesterification of waste cooking oil using Mg/Al hydrotalcite catalyst," Energy, Elsevier, vol. 107(C), pages 523-531.
    7. Chattopadhyay, Soham & Sen, Ramkrishna, 2013. "Fuel properties, engine performance and environmental benefits of biodiesel produced by a green process," Applied Energy, Elsevier, vol. 105(C), pages 319-326.
    8. Dorado, M.P. & Cruz, F. & Palomar, J.M. & López, F.J., 2006. "An approach to the economics of two vegetable oil-based biofuels in Spain," Renewable Energy, Elsevier, vol. 31(8), pages 1231-1237.
    9. Galadima, Ahmad & Muraza, Oki, 2014. "Biodiesel production from algae by using heterogeneous catalysts: A critical review," Energy, Elsevier, vol. 78(C), pages 72-83.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Pessoa Junior, Wanison A.G. & Takeno, Mitsuo L. & Nobre, Francisco X. & Barros, Silma de S. & Sá, Ingrity S.C. & Silva, Edson P. & Manzato, Lizandro & Iglauer, Stefan & de Freitas, Flávio A., 2020. "Application of water treatment sludge as a low-cost and eco-friendly catalyst in the biodiesel production via fatty acids esterification: Process optimization," Energy, Elsevier, vol. 213(C).
    2. Mulkan, Andi & Mohd Zulkifli, Nurin Wahidah & Husin, Husni & Ahmadi, & Dahlan, Irvan, 2024. "Performance and emissions assessment under full load operation of an unmodified diesel engine running on biodiesel-based waste cooking oil synthesized using JPW solid catalyst," Renewable Energy, Elsevier, vol. 224(C).
    3. Samanta, Ritika & Chakraborty, Rajat, 2023. "Methyl levulinate synthesis from rice husk employing e-waste derived silica supported nano CuO–CdSO4 photocatalyst: Assessment of production environmental impacts, engine performance and emissions," Renewable Energy, Elsevier, vol. 210(C), pages 842-858.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Iftikhar Ahmad & Adil Sana & Manabu Kano & Izzat Iqbal Cheema & Brenno C. Menezes & Junaid Shahzad & Zahid Ullah & Muzammil Khan & Asad Habib, 2021. "Machine Learning Applications in Biofuels’ Life Cycle: Soil, Feedstock, Production, Consumption, and Emissions," Energies, MDPI, vol. 14(16), pages 1-27, August.
    2. Laureano Costarrosa & David Eduardo Leiva-Candia & Antonio José Cubero-Atienza & Juan José Ruiz & M. Pilar Dorado, 2018. "Optimization of the Transesterification of Waste Cooking Oil with Mg-Al Hydrotalcite Using Response Surface Methodology," Energies, MDPI, vol. 11(2), pages 1-9, January.
    3. E, Jiaqiang & Pham, Minhhieu & Zhao, D. & Deng, Yuanwang & Le, DucHieu & Zuo, Wei & Zhu, Hao & Liu, Teng & Peng, Qingguo & Zhang, Zhiqing, 2017. "Effect of different technologies on combustion and emissions of the diesel engine fueled with biodiesel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 620-647.
    4. Ong, Hwai Chyuan & Masjuki, H.H. & Mahlia, T.M.I. & Silitonga, A.S. & Chong, W.T. & Yusaf, Talal, 2014. "Engine performance and emissions using Jatropha curcas, Ceiba pentandra and Calophyllum inophyllum biodiesel in a CI diesel engine," Energy, Elsevier, vol. 69(C), pages 427-445.
    5. Rahman, S.M. Ashrafur & Masjuki, H.H. & Kalam, M.A. & Sanjid, A. & Abedin, M.J., 2014. "Assessment of emission and performance of compression ignition engine with varying injection timing," Renewable and Sustainable Energy Reviews, Elsevier, vol. 35(C), pages 221-230.
    6. Gad, M.S. & Panchal, Hitesh & Ağbulut, Ümit, 2022. "Waste to Energy: An experimental comparison of burning the waste-derived bio-oils produced by transesterification and pyrolysis methods," Energy, Elsevier, vol. 242(C).
    7. Ma, Yingqun & Wang, Qunhui & Sun, Xiaohong & Wu, Chuanfu & Gao, Zhen, 2017. "Kinetics studies of biodiesel production from waste cooking oil using FeCl3-modified resin as heterogeneous catalyst," Renewable Energy, Elsevier, vol. 107(C), pages 522-530.
    8. Bhuiya, M.M.K. & Rasul, M.G. & Khan, M.M.K. & Ashwath, N. & Azad, A.K. & Hazrat, M.A., 2016. "Prospects of 2nd generation biodiesel as a sustainable fuel – Part 2: Properties, performance and emission characteristics," Renewable and Sustainable Energy Reviews, Elsevier, vol. 55(C), pages 1129-1146.
    9. Kumar, Niraj & Varun, & Chauhan, Sant Ram, 2013. "Performance and emission characteristics of biodiesel from different origins: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 633-658.
    10. Tamilselvan, P. & Nallusamy, N. & Rajkumar, S., 2017. "A comprehensive review on performance, combustion and emission characteristics of biodiesel fuelled diesel engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1134-1159.
    11. Subrata Bhowmik & Rajsekhar Panua & Subrata K Ghosh & Abhishek Paul & Durbadal Debroy, 2018. "Prediction of performance and exhaust emissions of diesel engine fuelled with adulterated diesel: An artificial neural network assisted fuzzy-based topology optimization," Energy & Environment, , vol. 29(8), pages 1413-1437, December.
    12. Behçet, Rasim & Yumrutaş, Recep & Oktay, Hasan, 2014. "Effects of fuels produced from fish and cooking oils on performance and emissions of a diesel engine," Energy, Elsevier, vol. 71(C), pages 645-655.
    13. Tan, Pi-qiang & Ruan, Shuai-shuai & Hu, Zhi-yuan & Lou, Di-ming & Li, Hu, 2014. "Particle number emissions from a light-duty diesel engine with biodiesel fuels under transient-state operating conditions," Applied Energy, Elsevier, vol. 113(C), pages 22-31.
    14. Jemni, Mohamed Ali & Kantchev, Gueorgui & Abid, Mohamed Salah, 2011. "Influence of intake manifold design on in-cylinder flow and engine performances in a bus diesel engine converted to LPG gas fuelled, using CFD analyses and experimental investigations," Energy, Elsevier, vol. 36(5), pages 2701-2715.
    15. Mansir, Nasar & Teo, Siow Hwa & Rashid, Umer & Saiman, Mohd Izham & Tan, Yen Ping & Alsultan, G. Abdulkareem & Taufiq-Yap, Yun Hin, 2018. "Modified waste egg shell derived bifunctional catalyst for biodiesel production from high FFA waste cooking oil. A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3645-3655.
    16. Gupta, Anilkumar R. & Rathod, Virendra K., 2018. "Calcium diglyceroxide catalyzed biodiesel production from waste cooking oil in the presence of microwave: Optimization and kinetic studies," Renewable Energy, Elsevier, vol. 121(C), pages 757-767.
    17. Mohammed Kamil & Fatima M. Almarashda, 2023. "Economic Viability and Engine Performance Evaluation of Biodiesel Derived from Desert Palm Date Seeds," Energies, MDPI, vol. 16(3), pages 1-22, February.
    18. Muhammad Usman & Haris Hussain & Fahid Riaz & Muneeb Irshad & Rehmat Bashir & Muhammad Haris Shah & Adeel Ahmad Zafar & Usman Bashir & M. A. Kalam & M. A. Mujtaba & Manzoore Elahi M. Soudagar, 2021. "Artificial Neural Network Led Optimization of Oxyhydrogen Hybridized Diesel Operated Engine," Sustainability, MDPI, vol. 13(16), pages 1-24, August.
    19. Marietta Markiewicz & Łukasz Muślewski, 2019. "The Impact of Powering an Engine with Fuels from Renewable Energy Sources including its Software Modification on a Drive Unit Performance Parameters," Sustainability, MDPI, vol. 11(23), pages 1-16, November.
    20. Peng-Lim, Boey & Ganesan, Shangeetha & Maniam, Gaanty Pragas & Khairuddean, Melati, 2012. "Sequential conversion of high free fatty acid oils into biodiesel using a new catalyst system," Energy, Elsevier, vol. 46(1), pages 132-139.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:164:y:2018:i:c:p:35-45. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.