IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v235y2019icp1183-1191.html
   My bibliography  Save this article

Production of CO from CO2 over mixed-metal oxides derived from layered-double-hydroxides

Author

Listed:
  • Hussein, A.M.A.
  • Burra, K.G.
  • Bassioni, G.
  • Hammouda, R.M.
  • Gupta, A.K.

Abstract

Carbon monoxide generation from the splitting of CO2 is of greater importance now than ever before due to continuous increase in CO2 levels in the atmosphere and concerns on the sustainability of energy and environment. This paper examines the conversion of CO2 to CO via thermochemical redox looping of metal oxides. Oxides of Mg/Fe and Mg/Al/Fe prepared from layered double hydroxide (LDH) were explored to aid in the conversion of CO2 to CO. The prepared metal oxides from LDH offered superior stability of porous metal structure and sustained redox capability at moderate to high temperatures required for conversion. The formations of these metal oxides from LDH were analyzed using thermogravimetric analysis (TGA). The results showed 635 µmol CO/g of Mg/Fe oxides as compared 557 µmol CO/g from Mg/Al/Fe. Continuous operation resulted in some sintering effects with deteriorated redox performance. The redox capability of Mg/Fe oxide over multi-cycle operations was lower as compared to Mg/Al/Fe oxides, which showed significant thermal stability while maintaining high CO yield and redox capability over extended redox cycles. The specific LDH derived metal oxides produced CO three times higher than those reported previously in the literature using Zr-doped ceria and other perovskites per unit mass of the oxygen carriers. While the surface area was reduced in Mg/Al/Fe the yield after the first cycle remained unchanged; both the surface area and yield decreased in Mg/Fe oxides. Mixed-metal oxide prepared from co-precipitation provided highly porous Mg/Al/Fe oxide compared to Mg/Fe or Mg/Al. High porosity enhanced the surface oxidation of Mg/Al/Fe that contributed to more than 85% oxidation from fast surface reactions. After two cycles, the redox rates changed little with further increase in the number of cycles to reveal surface area stability of Mg/Al/Fe. Multiple cycle operation suggested superior redox kinetics of Mg/Al/Fe than Mg/Fe. These LDH derived mixed metal (Mg/Al/Fe) oxide provided high and sustained CO production rates compared to those reported in the current literature used other materials so that the examined materials have good potential to serve as oxygen carrier for CO2 splitting to CO.

Suggested Citation

  • Hussein, A.M.A. & Burra, K.G. & Bassioni, G. & Hammouda, R.M. & Gupta, A.K., 2019. "Production of CO from CO2 over mixed-metal oxides derived from layered-double-hydroxides," Applied Energy, Elsevier, vol. 235(C), pages 1183-1191.
  • Handle: RePEc:eee:appene:v:235:y:2019:i:c:p:1183-1191
    DOI: 10.1016/j.apenergy.2018.11.040
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261918317483
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.apenergy.2018.11.040?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Rosen, Marc A., 2010. "Advances in hydrogen production by thermochemical water decomposition: A review," Energy, Elsevier, vol. 35(2), pages 1068-1076.
    2. Graves, Christopher & Ebbesen, Sune D. & Mogensen, Mogens & Lackner, Klaus S., 2011. "Sustainable hydrocarbon fuels by recycling CO2 and H2O with renewable or nuclear energy," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 1-23, January.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Antonio Fabozzi & Francesca Cerciello & Osvalda Senneca, 2024. "Reduction of Iron Oxides for CO 2 Capture Materials," Energies, MDPI, vol. 17(7), pages 1-22, April.
    2. Wang, Fuhuan & Xie, Heping & Liu, Tao & Wu, Yifan & Chen, Bin, 2020. "Highly dispersed CuFe-nitrogen active sites electrode for synergistic electrochemical CO2 reduction at low overpotential," Applied Energy, Elsevier, vol. 269(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Sadeghi, Shayan & Ghandehariun, Samane, 2022. "A standalone solar thermochemical water splitting hydrogen plant with high-temperature molten salt: Thermodynamic and economic analyses and multi-objective optimization," Energy, Elsevier, vol. 240(C).
    2. Géremi Gilson Dranka & Paula Ferreira, 2020. "Electric Vehicles and Biofuels Synergies in the Brazilian Energy System," Energies, MDPI, vol. 13(17), pages 1-22, August.
    3. Pellegrino, Sandro & Lanzini, Andrea & Leone, Pierluigi, 2017. "Greening the gas network – The need for modelling the distributed injection of alternative fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 266-286.
    4. Bergthorson, Jeffrey M. & Thomson, Murray J., 2015. "A review of the combustion and emissions properties of advanced transportation biofuels and their impact on existing and future engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1393-1417.
    5. Becker, W.L. & Braun, R.J. & Penev, M. & Melaina, M., 2012. "Production of Fischer–Tropsch liquid fuels from high temperature solid oxide co-electrolysis units," Energy, Elsevier, vol. 47(1), pages 99-115.
    6. Abanades, Stéphane & André, Laurie, 2018. "Design and demonstration of a high temperature solar-heated rotary tube reactor for continuous particles calcination," Applied Energy, Elsevier, vol. 212(C), pages 1310-1320.
    7. Ganesh, Ibram, 2016. "Electrochemical conversion of carbon dioxide into renewable fuel chemicals – The role of nanomaterials and the commercialization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 59(C), pages 1269-1297.
    8. Mathiesen, B.V. & Lund, H. & Connolly, D. & Wenzel, H. & Østergaard, P.A. & Möller, B. & Nielsen, S. & Ridjan, I. & Karnøe, P. & Sperling, K. & Hvelplund, F.K., 2015. "Smart Energy Systems for coherent 100% renewable energy and transport solutions," Applied Energy, Elsevier, vol. 145(C), pages 139-154.
    9. Connolly, D. & Lund, H. & Mathiesen, B.V., 2016. "Smart Energy Europe: The technical and economic impact of one potential 100% renewable energy scenario for the European Union," Renewable and Sustainable Energy Reviews, Elsevier, vol. 60(C), pages 1634-1653.
    10. Lin, Kuang C. & Lin, Yuan-Chung & Hsiao, Yi-Hsing, 2014. "Microwave plasma studies of Spirulina algae pyrolysis with relevance to hydrogen production," Energy, Elsevier, vol. 64(C), pages 567-574.
    11. Nzihou, Ange & Flamant, Gilles & Stanmore, Brian, 2012. "Synthetic fuels from biomass using concentrated solar energy – A review," Energy, Elsevier, vol. 42(1), pages 121-131.
    12. Brynolf, Selma & Taljegard, Maria & Grahn, Maria & Hansson, Julia, 2018. "Electrofuels for the transport sector: A review of production costs," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P2), pages 1887-1905.
    13. Drechsler, Carsten & Agar, David W., 2020. "Intensified integrated direct air capture - power-to-gas process based on H2O and CO2 from ambient air," Applied Energy, Elsevier, vol. 273(C).
    14. Cinti, Giovanni & Baldinelli, Arianna & Di Michele, Alessandro & Desideri, Umberto, 2016. "Integration of Solid Oxide Electrolyzer and Fischer-Tropsch: A sustainable pathway for synthetic fuel," Applied Energy, Elsevier, vol. 162(C), pages 308-320.
    15. Reznicek, Evan P. & Braun, Robert J., 2020. "Reversible solid oxide cell systems for integration with natural gas pipeline and carbon capture infrastructure for grid energy management," Applied Energy, Elsevier, vol. 259(C).
    16. Santos, D.M.F. & Šljukić, B. & Sequeira, C.A.C. & Macciò, D. & Saccone, A. & Figueiredo, J.L., 2013. "Electrocatalytic approach for the efficiency increase of electrolytic hydrogen production: Proof-of-concept using platinum--dysprosium alloys," Energy, Elsevier, vol. 50(C), pages 486-492.
    17. Preininger, Michael & Stoeckl, Bernhard & Subotić, Vanja & Mittmann, Frank & Hochenauer, Christoph, 2019. "Performance of a ten-layer reversible Solid Oxide Cell stack (rSOC) under transient operation for autonomous application," Applied Energy, Elsevier, vol. 254(C).
    18. Antenucci, Andrea & Sansavini, Giovanni, 2019. "Extensive CO2 recycling in power systems via Power-to-Gas and network storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 100(C), pages 33-43.
    19. Pickard, William F., 2013. "Transporting the terajoules: Efficient energy distribution in a post-carbon world," Energy Policy, Elsevier, vol. 62(C), pages 51-61.
    20. Zheng Luo & Yinghan Li & Fengbo Guo & Kaizhi Zhang & Kankan Liu & Wanli Jia & Yuxia Zhao & Yan Sun, 2020. "Carbon Dioxide Conversion with High-Performance Photocatalysis into Methanol on NiSe 2 /WSe 2," Energies, MDPI, vol. 13(17), pages 1-11, August.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:235:y:2019:i:c:p:1183-1191. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.