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Driving force of the better performance of metal-doped carbonaceous anodes in microbial fuel cells

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  • Mateo, Sara
  • Cañizares, Pablo
  • Rodrigo, Manuel Andrés
  • Fernandez-Morales, Francisco Jesus

Abstract

A comparison between different metal-doped carbonaceous anodes for air-breathing microbial fuel cells (MFCs) has been carried out in this work. In order to do that, the surface of carbon paper anodes were modified with Pt, Au and Ni. The current generated was higher when using these metal-doped anodes, exerting up to 7.4 A m−2 more than when using non-doped ones. Polarization curves results in a great performance of the Ni reaching 2.92 W m−2 at the steady state, followed by 0.99 W m−2 of the Au and 0.52 W m−2 of the Pt. Additionally, from the mathematical fitting of a model to the experimental data of a polarization curve, it was observed that the mechanism that explains the better performance of the metal doped anodes was the reduction of the mass transfer limitations. In this sense, the addition of metal on the anodes increase the threshold current density causing mass transfer limitations, reducing also the significance of the mass transfer limitations when the cells are operated under conditions in which the process is diffusion controlled.

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  • Mateo, Sara & Cañizares, Pablo & Rodrigo, Manuel Andrés & Fernandez-Morales, Francisco Jesus, 2018. "Driving force of the better performance of metal-doped carbonaceous anodes in microbial fuel cells," Applied Energy, Elsevier, vol. 225(C), pages 52-59.
  • Handle: RePEc:eee:appene:v:225:y:2018:i:c:p:52-59
    DOI: 10.1016/j.apenergy.2018.05.016
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    References listed on IDEAS

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    Cited by:

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    2. Modestra, J. Annie & Reddy, C. Nagendranatha & Krishna, K. Vamshi & Min, Booki & Mohan, S. Venkata, 2020. "Regulated surface potential impacts bioelectrogenic activity, interfacial electron transfer and microbial dynamics in microbial fuel cell," Renewable Energy, Elsevier, vol. 149(C), pages 424-434.
    3. Gajda, Iwona & Greenman, John & Ieropoulos, Ioannis, 2020. "Microbial Fuel Cell stack performance enhancement through carbon veil anode modification with activated carbon powder," Applied Energy, Elsevier, vol. 262(C).
    4. Massaglia, Giulia & Margaria, Valentina & Sacco, Adriano & Tommasi, Tonia & Pentassuglia, Simona & Ahmed, Daniyal & Mo, Roberto & Pirri, Candido Fabrizio & Quaglio, Marzia, 2018. "In situ continuous current production from marine floating microbial fuel cells," Applied Energy, Elsevier, vol. 230(C), pages 78-85.
    5. Szymon Potrykus & Sara Mateo & Janusz Nieznański & Francisco Jesús Fernández-Morales, 2020. "The Influent Effects of Flow Rate Profile on the Performance of Microbial Fuel Cells Model," Energies, MDPI, vol. 13(18), pages 1-15, September.
    6. Mateo, S. & Cantone, A. & Cañizares, P. & Fernández-Morales, F.J. & Scialdone, O. & Rodrigo, M.A., 2018. "On the staking of miniaturized air-breathing microbial fuel cells," Applied Energy, Elsevier, vol. 232(C), pages 1-8.
    7. Liu, Shu-Hui & Lai, Yu-Chuan & Lin, Chi-Wen, 2019. "Enhancement of power generation by microbial fuel cells in treating toluene-contaminated groundwater: Developments of composite anodes with various compositions," Applied Energy, Elsevier, vol. 233, pages 922-929.

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