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Design of an optimal process for enhanced production of bioethanol and biodiesel from algae oil via glycerol fermentation

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  • Martín, Mariano
  • Grossmann, Ignacio E.

Abstract

In this paper, we optimize a process that integrates the use of glycerol to produce ethanol via fermentation within the simultaneous production of biodiesel and bioethanol from algae. The process consists of growing the algae, determining the optimal fraction of oil vs. starch, followed by oil extraction, starch liquefaction and saccharification, to sugars, oil transesterification, for which we consider two transesterification technologies (enzymes and alkali) and the fermentation of sugars and glycerol. The advantage of this process is that the dehydration technologies are common for the products of the glucose and glycerol fermentation. Simultaneous optimization and heat integration is performed using Duran and Grossmann’s model. The fermentation of glycerol to ethanol increases the production of bioethanol by at least 50%. The energy and water consumptions are competitive with other processes that either sell the glycerol or use it to obtain methanol. However, the price for the biofuels is only competitive if glycerol cannot be sold to the market.

Suggested Citation

  • Martín, Mariano & Grossmann, Ignacio E., 2014. "Design of an optimal process for enhanced production of bioethanol and biodiesel from algae oil via glycerol fermentation," Applied Energy, Elsevier, vol. 135(C), pages 108-114.
    • Handle: RePEc:eee:appene:v:135:y:2014:i:c:p:108-114
    DOI: 10.1016/j.apenergy.2014.08.054
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    References listed on IDEAS

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    1. Cerón-García, M.C. & Macías-Sánchez, M.D. & Sánchez-Mirón, A. & García-Camacho, F. & Molina-Grima, E., 2013. "A process for biodiesel production involving the heterotrophic fermentation of Chlorella protothecoides with glycerol as the carbon source," Applied Energy, Elsevier, vol. 103(C), pages 341-349.
    2. Rawat, I. & Ranjith Kumar, R. & Mutanda, T. & Bux, F., 2013. "Biodiesel from microalgae: A critical evaluation from laboratory to large scale production," Applied Energy, Elsevier, vol. 103(C), pages 444-467.
    3. Demirbas, M. Fatih, 2011. "Biofuels from algae for sustainable development," Applied Energy, Elsevier, vol. 88(10), pages 3473-3480.
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    Citations

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    Cited by:

    1. Fantozzi, F. & Frassoldati, A. & Bartocci, P. & Cinti, G. & Quagliarini, F. & Bidini, G. & Ranzi, E.M., 2016. "An experimental and kinetic modeling study of glycerol pyrolysis," Applied Energy, Elsevier, vol. 184(C), pages 68-76.
    2. Wu, Wei & Wang, Po-Han & Lee, Duu-Jong & Chang, Jo-Shu, 2017. "Global optimization of microalgae-to-biodiesel chains with integrated cogasification combined cycle systems based on greenhouse gas emissions reductions," Applied Energy, Elsevier, vol. 197(C), pages 63-82.
    3. Wang, Yi-Tong & Fang, Zhen & Yang, Xing-Xia, 2017. "Biodiesel production from high acid value oils with a highly active and stable bifunctional magnetic acid," Applied Energy, Elsevier, vol. 204(C), pages 702-714.
    4. Abdulkhani, Ali & Alizadeh, Peyman & Hedjazi, Sahab & Hamzeh, Yahya, 2017. "Potential of Soya as a raw material for a whole crop biorefinery," Renewable and Sustainable Energy Reviews, Elsevier, vol. 75(C), pages 1269-1280.
    5. Martín, Mariano, 2016. "RePSIM metric for design of sustainable renewable based fuel and power production processes," Energy, Elsevier, vol. 114(C), pages 833-845.

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