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A comprehensive experimental procedure for CO2 coal gasification: Is there really a maximum reaction rate?

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  • Gomez, Arturo
  • Silbermann, Rico
  • Mahinpey, Nader

Abstract

A novel procedure to perform carbon dioxide (CO2) gasification studies was tested with two different Alberta coals and compared to the most common procedures using thermogravimetric analysis (TGA). The designed experiments indicate that maximum reaction rates reported in the literature were probably a consequence of the increasing CO2 concentration in the gas mixture when the inert gas was switched to CO2. It has been proven that, independent of feedstocks, the time to observe this maximum reaction rate was constant, indicating the reported maximum reaction rate depends only on the gas dispersion when the gasifying agent is fed and not on the surface properties of the char.

Suggested Citation

  • Gomez, Arturo & Silbermann, Rico & Mahinpey, Nader, 2014. "A comprehensive experimental procedure for CO2 coal gasification: Is there really a maximum reaction rate?," Applied Energy, Elsevier, vol. 124(C), pages 73-81.
    • Handle: RePEc:eee:appene:v:124:y:2014:i:c:p:73-81
    DOI: 10.1016/j.apenergy.2014.02.077
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    References listed on IDEAS

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    1. Irfan, Muhammad F. & Usman, Muhammad R. & Kusakabe, K., 2011. "Coal gasification in CO2 atmosphere and its kinetics since 1948: A brief review," Energy, Elsevier, vol. 36(1), pages 12-40.
    2. Tremel, Alexander & Haselsteiner, Thomas & Kunze, Christian & Spliethoff, Hartmut, 2012. "Experimental investigation of high temperature and high pressure coal gasification," Applied Energy, Elsevier, vol. 92(C), pages 279-285.
    3. Ahmed, I.I. & Gupta, A.K., 2011. "Kinetics of woodchips char gasification with steam and carbon dioxide," Applied Energy, Elsevier, vol. 88(5), pages 1613-1619, May.
    4. Nipattummakul, Nimit & Ahmed, Islam & Kerdsuwan, Somrat & Gupta, Ashwani K., 2010. "High temperature steam gasification of wastewater sludge," Applied Energy, Elsevier, vol. 87(12), pages 3729-3734, December.
    5. Prabowo, Bayu & Umeki, Kentaro & Yan, Mi & Nakamura, Masato R. & Castaldi, Marco J. & Yoshikawa, Kunio, 2014. "CO2–steam mixture for direct and indirect gasification of rice straw in a downdraft gasifier: Laboratory-scale experiments and performance prediction," Applied Energy, Elsevier, vol. 113(C), pages 670-679.
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    Cited by:

    1. Li, Yu & Fan, Weidong, 2016. "Effect of char gasification on NOx formation process in the deep air-staged combustion in a 20kW down flame furnace," Applied Energy, Elsevier, vol. 164(C), pages 258-267.
    2. Gomez, Arturo & Mahinpey, Nader, 2015. "A new model to estimate CO2 coal gasification kinetics based only on parent coal characterization properties," Applied Energy, Elsevier, vol. 137(C), pages 126-133.
    3. Jayakumar, Abhimanyu & Gomez, Arturo & Mahinpey, Nader, 2016. "Post-combustion CO2 capture using solid K2CO3: Discovering the carbonation reaction mechanism," Applied Energy, Elsevier, vol. 179(C), pages 531-543.
    4. Lee, Jechan & Yang, Xiao & Cho, Seong-Heon & Kim, Jae-Kon & Lee, Sang Soo & Tsang, Daniel C.W. & Ok, Yong Sik & Kwon, Eilhann E., 2017. "Pyrolysis process of agricultural waste using CO2 for waste management, energy recovery, and biochar fabrication," Applied Energy, Elsevier, vol. 185(P1), pages 214-222.

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