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Improving the supercooling degree of titanium dioxide nanofluids with sodium dodecylsulfate

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  • Jia, Lisi
  • Peng, Lan
  • Chen, Ying
  • Mo, Songping
  • Li, Xing

Abstract

The solidification processes of titanium (TiO2) nanofluids and deionized water (DW) were measured by differential scanning calorimetry to explore the effect of sodium dodecylsulfate (SDS) surfactants on the supercooling degree of TiO2 nanofluids. The supercooling degrees of TiO2 nanofluids without surfactants were approximately 11.5% lower than that of DW, and the values did not change significantly with nanoparticle concentration. However, the addition of SDS surfactants could reduce the supercooling degree of TiO2 nanofluids. With increasing surfactant-to-nanoparticle mass ratio and SDS concentration, the reduction in the supercooling degrees of TiO2 nanofluids increased to a maximum value of approximately 30.6%. These phenomena indicated that the surfactants served an important function in enhancing heterogeneous nucleation in TiO2 nanofluids. The theoretical analysis of heterogeneous nucleation associated with surfactants revealed that the surfactants reduced the free energy change required for nucleation in TiO2 nanofluids by changing the contact angle of nanoparticles. The supercooling degree of TiO2 nanofluids was found to be closely related to the adsorption density of SDS, that is, large adsorption densities resulted in low supercooling degrees. When the saturation adsorption density of SDS on TiO2 nanoparticles was reached, the reduction in the supercooling degree of TiO2 nanofluids caused by surfactants was at its maximum.

Suggested Citation

  • Jia, Lisi & Peng, Lan & Chen, Ying & Mo, Songping & Li, Xing, 2014. "Improving the supercooling degree of titanium dioxide nanofluids with sodium dodecylsulfate," Applied Energy, Elsevier, vol. 124(C), pages 248-255.
    • Handle: RePEc:eee:appene:v:124:y:2014:i:c:p:248-255
    DOI: 10.1016/j.apenergy.2014.03.019
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    1. Oró, E. & de Gracia, A. & Castell, A. & Farid, M.M. & Cabeza, L.F., 2012. "Review on phase change materials (PCMs) for cold thermal energy storage applications," Applied Energy, Elsevier, vol. 99(C), pages 513-533.
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    1. Suganthi, K.S. & Leela Vinodhan, V. & Rajan, K.S., 2014. "Heat transfer performance and transport properties of ZnO–ethylene glycol and ZnO–ethylene glycol–water nanofluid coolants," Applied Energy, Elsevier, vol. 135(C), pages 548-559.
    2. Bhattad, Atul & Sarkar, Jahar & Ghosh, Pradyumna, 2018. "Improving the performance of refrigeration systems by using nanofluids: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3656-3669.
    3. Fan, Li-Wu & Yao, Xiao-Li & Wang, Xiao & Wu, Yu-Yue & Liu, Xue-Ling & Xu, Xu & Yu, Zi-Tao, 2015. "Non-isothermal crystallization of aqueous nanofluids with high aspect-ratio carbon nano-additives for cold thermal energy storage," Applied Energy, Elsevier, vol. 138(C), pages 193-201.
    4. Leong, K.Y. & Ku Ahmad, K.Z. & Ong, Hwai Chyuan & Ghazali, M.J. & Baharum, Azizah, 2017. "Synthesis and thermal conductivity characteristic of hybrid nanofluids – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 75(C), pages 868-878.
    5. Zahir, Md. Hasan & Mohamed, Shamseldin A. & Saidur, R. & Al-Sulaiman, Fahad A., 2019. "Supercooling of phase-change materials and the techniques used to mitigate the phenomenon," Applied Energy, Elsevier, vol. 240(C), pages 793-817.
    6. Hussien, Ahmed A. & Abdullah, Mohd Z. & Al-Nimr, Moh’d A., 2016. "Single-phase heat transfer enhancement in micro/minichannels using nanofluids: Theory and applications," Applied Energy, Elsevier, vol. 164(C), pages 733-755.

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