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Effect of reaction parameters on the quality of captured sulfur in Claus process

Author

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  • Selim, H.
  • Gupta, A.K.
  • Al Shoaibi, A.

Abstract

Quality of sulfur deposits collected from hydrogen sulfide combustion has been examined. Experimental conditions representing selected practical systems have been investigated. Combustion of hydrogen sulfide was allowed to occur under the different conditions with sulfur deposits collected for analysis. Experimental conditions represented effect of equivalence ratio of rich (Claus) conditions and stoichiometric conditions; effect of contaminants, other than H2S, in the acid gas stream; combustion of H2S with hydrocarbon fuels (methane and propane). Sulfur deposits from H2S combustion under various conditions were captured and analyzed using X-ray powder diffraction and laser induced breakdown spectroscopy (LIBS) diagnostics. X-ray powder diffraction was used to determine the type of deposited sulfur allotrope, while LIBS was used to identify the elemental analysis of deposited sulfur.

Suggested Citation

  • Selim, H. & Gupta, A.K. & Al Shoaibi, A., 2013. "Effect of reaction parameters on the quality of captured sulfur in Claus process," Applied Energy, Elsevier, vol. 104(C), pages 772-776.
  • Handle: RePEc:eee:appene:v:104:y:2013:i:c:p:772-776
    DOI: 10.1016/j.apenergy.2012.12.015
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    References listed on IDEAS

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    1. Selim, H. & Al Shoaibi, A. & Gupta, A.K., 2011. "Effect of H2S in methane/air flames on sulfur chemistry and products speciation," Applied Energy, Elsevier, vol. 88(8), pages 2593-2600, August.
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    Cited by:

    1. Ibrahim, S. & Al Shoaibi, A. & Gupta, A.K., 2015. "Effect of benzene on product evolution in a H2S/O2 flame under Claus condition," Applied Energy, Elsevier, vol. 145(C), pages 21-26.
    2. Li, Yang & Guo, Qinghua & Yu, Xinlei & Dai, Zhenghua & Wang, Yifei & Yu, Guangsuo & Wang, Fuchen, 2017. "Effect of O2 enrichment on acid gas oxidation and formation of COS and CS2 in a rich diffusion flame," Applied Energy, Elsevier, vol. 206(C), pages 947-958.
    3. Meratizaman, Mousa & Monadizadeh, Sina & Tohidi Sardasht, Mohammad & Amidpour, Majid, 2015. "Techno economic and environmental assessment of using gasification process in order to mitigate the emission in the available steam power cycle," Energy, Elsevier, vol. 83(C), pages 1-14.

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