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Low severity dilute-acid hydrolysis of sweet sorghum bagasse

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  • Banerji, Aditi
  • Balakrishnan, M.
  • Kishore, V.V.N.

Abstract

Sweet sorghum is emerging as a promising energy crop in India, with potential for ethanol production both from the extracted juice and the bagasse residue. This work investigates the release of fermentable total sugars (TS) and formation of total degradation compounds (TDC) by dilute sulphuric acid hydrolysis of sweet sorghum bagasse from the genotype SSV 84. Hydrolysis was conducted at moderate temperatures (100°C and 121°C). The effect of pretreatment severity (measured by the combined severity factor, CS), particle size and substrate loading on the hydrolysate composition was examined. The kinetics of xylose, acetic acid and furfural formation was also studied. The maximum theoretical yield is 29.9g C5 sugars/100g bagasse on dry weight basis. Under the conditions of this study, 10% substrate loading in the CS range of 1.64–1.93 was optimal with C5 yield >22.3g/100g bagasse and efficiency (TS/TDC ratio) >8. Bagasse particle size reduction also resulted in a higher efficiency. SEM and FT-IR analysis of the solid residue confirmed disruption of the biomass structure and removal of functional groups associated with hemicelluloses and lignin. This study demonstrates that acid hydrolysis at moderate temperature has an advantage in terms of high sugars concentration vis-a-vis low degradation compounds formation.

Suggested Citation

  • Banerji, Aditi & Balakrishnan, M. & Kishore, V.V.N., 2013. "Low severity dilute-acid hydrolysis of sweet sorghum bagasse," Applied Energy, Elsevier, vol. 104(C), pages 197-206.
    • Handle: RePEc:eee:appene:v:104:y:2013:i:c:p:197-206
    DOI: 10.1016/j.apenergy.2012.11.012
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    1. Yu, Qiang & Zhuang, Xinshu & Yuan, Zhenhong & Wang, Wen & Qi, Wei & Wang, Qiong & Tan, Xuesong, 2011. "Step-change flow rate liquid hot water pretreatment of sweet sorghum bagasse for enhancement of total sugars recovery," Applied Energy, Elsevier, vol. 88(7), pages 2472-2479, July.
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    3. Rohowsky, Bernd & Häßler, Thomas & Gladis, Arne & Remmele, Edgar & Schieder, Doris & Faulstich, Martin, 2013. "Feasibility of simultaneous saccharification and juice co-fermentation on hydrothermal pretreated sweet sorghum bagasse for ethanol production," Applied Energy, Elsevier, vol. 102(C), pages 211-219.
    4. Vancov, T. & McIntosh, S., 2012. "Mild acid pretreatment and enzyme saccharification of Sorghum bicolor straw," Applied Energy, Elsevier, vol. 92(C), pages 421-428.
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    2. Mesa, Leyanis & Martínez, Yenisleidy & Barrio, Edenny & González, Erenio, 2017. "Desirability function for optimization of Dilute Acid pretreatment of sugarcane straw for ethanol production and preliminary economic analysis based in three fermentation configurations," Applied Energy, Elsevier, vol. 198(C), pages 299-311.
    3. Zhang, Changwei & Wen, Hao & Chen, Changjing & Cai, Di & Fu, Chaohui & Li, Ping & Qin, Peiyong & Tan, Tianwei, 2019. "Simultaneous saccharification and juice co-fermentation for high-titer ethanol production using sweet sorghum stalk," Renewable Energy, Elsevier, vol. 134(C), pages 44-53.
    4. Chen, Dongyu & Gao, Dongxiao & Capareda, Sergio C. & E, Shuang & Jia, Fengrui & Wang, Ying, 2020. "Influences of hydrochloric acid washing on the thermal decomposition behavior and thermodynamic parameters of sweet sorghum stalk," Renewable Energy, Elsevier, vol. 148(C), pages 1244-1255.
    5. Zhou, Ziyuan & Liu, Dehua & Zhao, Xuebing, 2021. "Conversion of lignocellulose to biofuels and chemicals via sugar platform: An updated review on chemistry and mechanisms of acid hydrolysis of lignocellulose," Renewable and Sustainable Energy Reviews, Elsevier, vol. 146(C).
    6. Zoulikha, Maache-Rezzoug & Thierry, Maugard & Jean-Michel Qiuyu, Zhao & Nouviaire, Armelle & Sid-Ahmed, Rezzoug, 2015. "Combined steam-explosion toward vacuum and dilute-acid spraying of wheat straw. Impact of severity factor on enzymatic hydrolysis," Renewable Energy, Elsevier, vol. 78(C), pages 516-526.

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