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Hydroxyl-Stretching Region in the Raman Broad Scans on Minerals of the Vivianite Group (Vivianite, Baricite, Bobierrite, Annabergite, Erythrite)

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  • Amelia Carolina Sparavigna

Abstract

Vivianite is a hydrated iron phosphate mineral (Fe3(PO4)2•8H2O), crystallized in a monoclinic system. It is the endmember of a mineral series known as the vivianite group, where minerals have the general formula A3(XO4)2•8H2O, A is a divalent metal cation and X is phosphorus P or arsenic As. Today, vivianite is attracting interest as a promising material for recovering phosphorous from wastewaters. In fact, the presence in wastewater sludges of soluble iron and phosphorus can lead to vivianite formation. As a crystal, it is a naturally occurring Van der Walls material. It can be easily characterized by means of Raman and infrared spectroscopies. Here we will consider the Raman spectroscopy, precisely that related to the hydroxyl-stretching region. We will propose the deconvolutions in q-Gaussian functions of spectra from RRUFF database, comparing the obtained results with those available from literature. Besides vivianite, we will consider also baricite, bobierrite, annabergite and erythrite, other members of the vivianite group. About the hydroxyl-stretching region and the use of q-Gaussians, we take the chance to continue a discussion regarding the Raman spectroscopy of water, discussion that we started in March 2024.

Suggested Citation

  • Amelia Carolina Sparavigna, 2024. "Hydroxyl-Stretching Region in the Raman Broad Scans on Minerals of the Vivianite Group (Vivianite, Baricite, Bobierrite, Annabergite, Erythrite)," International Journal of Sciences, Office ijSciences, vol. 13(08), pages 23-36, August.
    • Handle: RePEc:adm:journl:v:13:y:2024:i:8:p:23-36
    DOI: 10.18483/ijSci.2787
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    References listed on IDEAS

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    1. Yuan Liu & Jie Jin & Jiawei Li & Ziwei Zou & Renchan Lei & Jintao Sun & Jinxia Xia, 2022. "Enhanced Phosphorus Recovery as Vivianite from Anaerobically Digested Sewage Sludge with Magnetic Biochar Addition," Sustainability, MDPI, vol. 14(14), pages 1-14, July.
    2. R. Hanel & S. Thurner & C. Tsallis, 2009. "Limit distributions of scale-invariant probabilistic models of correlated random variables with the q-Gaussian as an explicit example," The European Physical Journal B: Condensed Matter and Complex Systems, Springer;EDP Sciences, vol. 72(2), pages 263-268, November.
    3. Amelia Carolina Sparavigna, 2023. "SERS Spectral Bands of L-Cysteine, Cysteamine and Homocysteine Fitted by Tsallis q-Gaussian Functions," International Journal of Sciences, Office ijSciences, vol. 12(09), pages 14-24, September.
    4. Amelia Carolina Sparavigna, 2024. "Kubo Lineshape and its Fitted q-Gaussian Tsallis Function," International Journal of Sciences, Office ijSciences, vol. 13(01), pages 1-9, January.
    5. Amelia Carolina Sparavigna, 2023. "Multifunctional Porosity in Biochar," International Journal of Sciences, Office ijSciences, vol. 12(07), pages 41-54, July.
    6. Amelia Carolina Sparavigna, 2023. "q-Gaussian Tsallis Line Shapes and Raman Spectral Bands," International Journal of Sciences, Office ijSciences, vol. 12(03), pages 27-40, March.
    7. Amelia Carolina Sparavigna, 2024. "Water, q-Gaussians and Raman Spectroscopy," International Journal of Sciences, Office ijSciences, vol. 13(03), pages 17-25, March.
    8. Amelia Carolina Sparavigna, 2024. "Applying q-Gaussians to the OH-stretching Raman bands of Water and Ice," International Journal of Sciences, Office ijSciences, vol. 13(04), pages 1-10, April.
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